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Digitale Medien

Eigenvectors of the polyethylene chain with conformational defects calculated semianalytically by Green's function (1991)

Wolf, S. ; Hägele, P. C. ; Schmid, C.

Springer

Colloid & polymer science 269 (1991), S. 364-374

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Details

ISSN: 1435-1536

Schlagwort(e): Polyethylene ; eigenvector ; conformationaldefect ; Green's function ; resonance mode ; fold ; kink

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie , Maschinenbau

Notizen: Abstract Eigenvectors of vibrating polyethylene chains with (200) and (110) folds have been calculated by solving the phonon-scattering problem exactly with the method of Green's function. The results are applied to analyze the resonance modes of the (200) fold (ggtgg: 1353, 1356, 1374 cm−1) and the (110) fold (approximately g′g′ggtg: 820, 1288, 1342, 1348, 1372, 1374 cm−1) in terms of the characteristic vibrations of smaller subunits of the (200) fold (gg, gtg) and the (110) fold (g′g′ggtg, g′g′gg, gtg) which can be identified spectroscopcally.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00654583

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