Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
83 (1985), S. 1404-1405
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Experiments are described which show that sucrose considerably reduces the freezing potential of very dilute solutions of alkali halides, NH4Cl and (NH4)2CO3 while urea enhances the magnitude of such potentials. Results have been explained on the basis of a hypothetical model based on nonequilibrium structure of ice containing hydrogen bonded structure and free water molecules in which foreign ions are incorporated during freezing and the growth of phase occurs by the acquisition of hydronium and hydroxyl ions which form free water molecules in the nonequilibrium ice phase.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.449406
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