Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
110 (1999), S. 11517-11522
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We analyze, by means of a random phase approximation (RPA) calculation, the conditions under which a mixture of oppositely weakly charged polyelectrolytes can microsegregate in the neighborhood of a charged surface creating a layered structure. A number of stable layers can be formed if the surface is sufficiently strongly charged even at temperatures at which the bulk of the mixture is homogeneous. The wave-length of the induced concentration fluctuation is proportional to 1/f1/2 near the microphase transition, where f is the charge density of the polyelectrolytes. © 1999 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.479093
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