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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 110 (1999), S. 11517-11522 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We analyze, by means of a random phase approximation (RPA) calculation, the conditions under which a mixture of oppositely weakly charged polyelectrolytes can microsegregate in the neighborhood of a charged surface creating a layered structure. A number of stable layers can be formed if the surface is sufficiently strongly charged even at temperatures at which the bulk of the mixture is homogeneous. The wave-length of the induced concentration fluctuation is proportional to 1/f1/2 near the microphase transition, where f is the charge density of the polyelectrolytes. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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