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  • Electronic Resource  (32)
  • 1985-1989  (32)
  • 1988  (22)
  • 1987  (10)
Material
  • Electronic Resource  (32)
Years
  • 1985-1989  (32)
Year
  • 1
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Extensive networks of metastable ions link the major peaks in the electron impact mass spectra of two crown ethers containing 2,6-pyrido units. High-resolution mass measurements and the metastable peaks allow the elucidation of the fragmentation pathways. The spectra are influenced more by the presence of aromatic substituents than by the 2,6-pyrido units.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 20 (1987), S. 138-142 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 5513-5515 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A number of Nd15 Fe79−x Mgx B6 magnets with x up to 0.41 and pseudoternary Nd2(Fe1−yMgy)14B compounds with y up to 0.081 have been prepared by conventional powder metallurgy processes. Magnetic measurements indicate that for the magnet alloys i Hc increases as x increases up to 0.25 without a loss in Br, hence the (BH)max values are slightly enhanced. The maximum increase in i Hc is about 15% for x=0.25. Extensive Mg-rich precipitates inside the Nd-rich phase have been observed by electron probe microanalysis (EPMA). Higher Mg intensity at grain boundaries is also detected by EPMA. The reasons for the i Hc increase might be the grain boundary cleaning ability of Mg dopant. For the pseudoternary compounds, the anisotropy field HA is found to increase only slightly due to Mg doping while TC remains practically unchanged.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 61 (1987), S. 4398-4400 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic graphite intercalation compounds (GIC's) allow a controlled separation of atomically abrupt magnetic layers by variation of the stage of the sample. Thus very small J'/J values (∼10−4) and quasi-two-dimensional behavior can be achieved where J' and J are, respectively, the interplanar and intraplanar exchange constants. The applicability of a 2D XY model is established by a comparison of the high-temperature susceptibility with the high-temperature series expansions for the various 2D and 3D models. Low-temperature studies provide values for magnetic interactions pertinent to the most interesting intermediate temperature range, where a 2D XY bound vortex phase may occur.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 2739-2741 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic and crystallographic measurements have been made on new pseudoternary compounds Nd2(Fe1−xCux)14B in order to study the systematic variation of magnetic properties with Cu substitution. X-ray powder diffraction data indicate that the tetragonal Nd2Fe14B-type phase exists only for x≤0.05. Partial replacement of Fe by nonmagnetic Cu significantly decreases the saturation magnetization value with little change in ferromagnetic Curie temperature TC. Low-temperature spin orientation temperature (Tsr) decreases from 135 K for x=0.00 to 130 K for x=0.03, and 122 K for x=0.05, and the tilt angle of the easy magnetization direction from the tetragonal c axis decreases accordingly.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 62 (1987), S. 1189-1194 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The microstructure of the nickel silicide, Ni5Si2, which forms during solid-state reactions using self-supporting Ni-Si lateral-diffusion couples, has been studied using high-resolution electron microscopy (HREM) and selected-area electron diffraction. Two different structures for Ni5Si2 have been identified, one of which is consistent with the crystal structure which has been reported to have an actual composition of Ni31Si12. There is evidence for the existence of a third structure. Variations in the distribution of these structures and the presence of planar defects may account for the reported composition range of Ni5Si2 in the Ni-Si phase diagram. The observed HREM images are compared with computer simulated images.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 5546-5548 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Magnetic and crystallographic measurements have been made on the rare-earth iron boride systems (R1−xScx)2Fe14B (R=Y, Nd, Dy, Er, Lu). Powder x-ray diffraction data indicate that a Nd2Fe14B-type single phase persists up to x=0.2 with lattice parameters decreasing slightly due to the smaller metallic radius of the Sc3+ ions. The variation of magnetic moments per formula unit with nonmagnetic Sc substitution depends on the smaller Sc size and the nature of the magnetic alignment of the rare-earth sublattice (nonmagnetic in Y and Lu, ferromagnetic axial in Nd, ferromagnetic planar in Er, and antiferromagnetic axial in Dy) with respect to the iron sublattice. The Curie temperature TC decreases monotonically with progressive addition of Sc atoms.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 89 (1988), S. 545-550 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Thermodynamics of protein solubilization in water-in-oil microemulsions is analyzed in terms of the shell-and-core model for reverse micelles. The electrostatic contribution to the free energy of transfer of the protein from the aqueous solution to the microemulsion is determined via the solution of the nonlinear Poisson–Boltzmann equation for the protein/reverse micelle complex, for the protein-free micelle, and for the cell model of aqueous protein solution in equilibrium with the microemulsion. The electrolyte effect on the protein solubility in the microemulsion is studied. A good agreement between the predictions of the model and the known salting out effect of cytochrome-c in sodium di-2-ethylhexylsulfosuccinate AOT-water-in-isooctane microemulsion is observed.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 1758-1761 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A technique has been adapted to measure the relative change in the acoustic velocity of materials at frequencies up to 500 MHz with a maximum sensitivity of one part in 107. This technique is applied to the measurement of the temperature coefficient of the longitudinal-acoustic velocity of fused quartz over the temperature range 28–47 °C. The longitudinal velocity is observed to increase linearly over this temperature range. The temperature coefficient of the fractional longitudinal velocity increase of fused quartz is determined to be (1.075±0.025)×10−4 °C−1. This number is in agreement with the results of previous investigators and is the most accurate measurement available at room temperature.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 64 (1988), S. 6690-6698 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The stress relaxation behavior during thermal cycling of metal/quartz and metal/polyimide/quartz layered structures has been investigated using a cantilever bending beam technique. The metals chosen for this study include Cu and Cr, two materials with contrasting mechanical and interfacial bonding properties. A finite element analysis, as well as an analytical calculation, has been carried out to deduce the stress distribution in the layered structures. Results indicate that the extent of stress relaxation strongly depends on the intrinsic mechanical property of the metal film with significantly higher stresses residing in the Cr film than in the Cu film. The interfacial polyimide layer has been found to serve as an effective buffering layer to reduce the residual stress in metal films. Observations from transmission electron microscopy suggest that the stress is partially released through the deformation of the polyimide near the metal/polyimide interface.
    Type of Medium: Electronic Resource
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