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  • Electronic Resource  (6)
  • 13C NMR  (2)
  • 21.10.Hw  (2)
  • 32.80.Dz  (2)
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  • Electronic Resource  (6)
Years
  • 1
    ISSN: 1432-0649
    Keywords: 32.30.—r ; 32.80.Rm ; 32.80.Dz ; 35.10.Hn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Resonance ionization mass spectroscopic (RIMS) measurements for trace analysis and spectroscopy of 237Np, the ecologically most important isotope of neptunium, are described. The chemical procedure for the separation of neptunium from aqueous samples as well as the preparation of filaments for RIMS are outlined. Several two- and three-step excitation schemes have been investigated in order to find suitable conditions for the sensitive detection of 237Np. Using a three-step, three-color excitation and ionization scheme an overall detection efficiency of 3×10−8 was obtained, resulting in a detection limit of 4×108 atoms (160 fg) of 237Np. The hyperfine structure splittings of the levels under investigation, which influence the detection limit, were measured. A new method to determine the first ionization potential (IP) was applied to neptunium yielding a value of IP=6.2655(2) eV.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 07.65.Eh ; 32.70.Fw ; 32.80.Dz
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Resonance ionization mass spectroscopy (RIMS) and pulsed-laser induced desorption (PLID) have been combined for ultrasensitive detection and spectroscopy of very small samples of refractive elements. The method has been tested and applied to laser spectroscopy of 5×109 atoms (1.5 pg) of195Au (T 1/2= 183d) implanted at the ISOLDE online mass separator with 60 keV into graphite. A pulsed thermal atomic beam was formed by laser desorption with a 10 ns Nd∶Yag laser pulse. Subsequently the atoms were photoionized in a three-colour, three-step resonant excitation to an autoionizing state. The selectivity was enhanced by a time-of-flight measurement of the photo ions. In resonance, one ion was detected per 105 atoms implanted resulting in a gain in detection efficiency by three orders of magnitude in comparison to the use of a continuous atomic beam. In the course of the experiments several unknown autoionizing states were found, and the lifetime of the 6d 2 D 3/2 state of gold was determined to beτ=10.7(6) ns.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-601X
    Keywords: 21.10.Hw ; 21.60.Cs ; 23.20.Lv ; 25.70.Cd
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract 208Pb has been excited with inelastic heavy ion scattering of 350 MeV64Ni and 420 MeV82Se on a thick208Pb target. Withγ -γ coincidence measurements 2 new decays of the 10+ isomer, namely a 34.5 keVE2-transition to 8 2 + and a 857.7 keVE3 transition to 7− have been found and the wavefunctions of the participating levels deduced. An observed gamma cascade of 295.3, 348.0, 865.4 and 340.2 keV on top of the 10+ isomer is assigned to the particle-hole states with the highest spins 14− 6744.1 keV→13− 6448.9 keV→12+ 6100.9 keV→11+ 5235.6 keV→10+ 4895.4 keV.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1434-601X
    Keywords: 21.10.Hw ; 21.10.Ky ; 21.60.Cs ; 23.20.Ck ; 23.20.Lv ; 27.60.+j
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The neutron-deficient nuclei100,101Cd were identified for the first time in — beam following the reactions58Ni +46,48Ti and58Ni +50Cr at 230 MeV and 245 MeV bombarding energy of the58Ni beams. Theγ-decay of the isotopes100,101,102Cd was studied inpγ, ppγ,nγ, nnγ, andnγγ prompt and delayed coincidence spectra. Isomers were found with spin and half life {ie1-01}=8+, T1/2=52(5) ns in100Cd, {ie1-02}=(19/2+), T1/2=4.6(4) ns in101Cd and {ie1-03}=8+, T1/2=56(4) ns in102Cd. In a PAD experiment theg-factor of the {ie1-04}=8+ isomer in100Cd was measured to be g=1.24(6). Using the reaction36Ar +70Ge at 135 MeV energy of the36Ar beam, theg-factor and the quadrupole moment of the {ie1-05}=8+ isomer in102Cd were measured to be g=1.29(3) and Q=87(10) fm2, respectively. The spectroscopic results are discussed within a shell model approach using a100Sn core, which accounts well for the electromagnetic properties of the proton aligned isomers. The structure of the spherical neutron states, dominated by the close lying vd5/2, g7/2 orbitals, and the gradually developing quadrupole collectivity are reproduced by the shell model calculations.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. 133-136 
    ISSN: 0749-1581
    Keywords: 17β-Substituted 14α-steroids ; 7α-substituted 14α-steroids ; 1H NMR ; 13C NMR ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: γgaucheEffects of 17β- and 7α-substituted 14α-steroids were studied by 1H and 13C NMR spectroscopy. A linear correlation was found between the 1H chemical shift of H-12β and the 13C chemical shift of C-12 for C-17β-substituted steroids and between the chemical shifts of H-14α and C-14 in C-7α-substituted compounds.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 26 (1988), S. 85-88 
    ISSN: 0749-1581
    Keywords: 13C NMR ; 1H NMR ; 12-Substituted-14β-hydroxy steroids ; 14α-Steroids ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: γgauche effects of 12-substituted-14β-hydroxy- and 14α-steroids were studied by 1H and 13C NMR spectroscopy. A linear correlation was found between the 1H chemical shift of 4H-17 and the 13C shift of C-17 for C-12-substituted steroids. This correlation can be explained by steric interactions.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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