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  • Inorganic Chemistry  (7)
  • Added nitrogen interaction  (3)
  • Aqua ammonia  (2)
  • Urea N
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  • 1
    Digitale Medien
    Digitale Medien
    Mineralization of soil organic nitrogen solubilized by aqua ammonia fertilizer (1996)
    Springer
    Biology and fertility of soils 23 (1996), S. 93-98 
    Details
    ISSN: 1432-0789
    Schlagwort(e): Added nitrogen interaction ; Alkaline-hydrolysing fertilizer ; Aqua ammonia ; Gross N immobilization ; Gross N mineralization ; 15N ; Soluble organic N availability
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Organic N solubilized by NH3(aq) was extracted from 15N-labelled or unlabelled soil, concentrated and added to non-extracted soil, which was incubated under aerobic conditions at 27±1°C. Gross N mineralization, gross N immobilization, and nitrification in soils with or without addition of unlabelled soluble organic N were estimated by models based on the dilution of the NH 4 + or NO inf3 sup- pools, which were labelled with 15N at the beginning of incubation. Mineralization of labelled organic N was measured by the appearance of label in the mineral N pool. Although gross N mineralization and gross N immobilization were increased in two soils between day 0 and day 7 following addition of unlabelled organic N solubilized by NH3(aq), there was no increase in net N mineralization. Solubilization of 15N-labelled organic N increased and the 15N enrichment of the soluble organic N decereased as the concentration of NH3(aq) added increased. A constant proportion of approximately one-quarter of the labelled organic N added at different rates to non-extracted soil was recovered in the mineral N pool after an incubation period of 14 days, and the availability ratios calculated from net N mineralization data were 1.1:1 and 2.1:1 for 111 and 186 mg added organic-N kg-1 soil, respectively, indicating that the mineralization of organic N was increased by solubilization.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00335824
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  • 2
    Digitale Medien
    Digitale Medien
    Amelioration of water stress effects on wetland rice by urea-N, plant growth regulators, and foliar spray of a diazotrophic bacterium Klebsiella sp. (1996)
    Springer
    Biology and fertility of soils 23 (1996), S. 454-458 
    Details
    ISSN: 1432-0789
    Schlagwort(e): Key words Water stress effects ; Urea N ; Diazotrophic bacteria ; Plant growth regulators ; Wetland rice ; Oryza sativa L. ; Klebsiella sp. strain ; CO2 exchange ; Na content
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Some of the measures suggested for amelioration of drought effects include application of N fertilizer and plant growth regulators (PGRs). Since N2-fixing bacteria produce plant growth substances (PGRs), the effect of foliar application of an active strain of Klebsiella sp. (KUPOS) on IR-50 rice was examined using three foliar sprays applied at 10-day intervals. Irrigation once every 3 days was essential for plant growth. Application of KUPOS and 40 kg N ha–1 improved grain yield of acutely water stressed plants from 330 kgha–1 to more than 1300 kgha–1 along with an improvement in several growth variables and yield determinants. Indole acetic acid, kinetin and GA3, in a mixture of 10–4 M of each, were less effective than KUPOS in alleviating stress effects. The adverse effects of water stress on respiration and photosynthesis as indicated by CO2 exchange were also alleviated by these treatments. While uptake of K, Mg, Ca, Fe and Mo was increased, Na content decreased, accompanied by an increase in proline content. The order of effectiveness of the treatments was 40 kg N ha–1 〉KUPOS〉PGRs.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00335922
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  • 3
    Digitale Medien
    Digitale Medien
    Amelioration of water stress effects on wetland rice by urea-N, plant growth regulators, and foliar spray of a diazotrophic bacterium Klebsiella sp. (1996)
    Springer
    Biology and fertility of soils 23 (1996), S. 454-458 
    Details
    ISSN: 1432-0789
    Schlagwort(e): Water stress effects ; Urea N ; Diazotrophic bacteria ; Plant growth regulators ; Wetland rice ; Oryza sativa L. ; Klebsiella sp. strain ; CO2 exchange ; Na content
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Some of the measures suggested for amelioration of drought effects include application of N fertilizer and plant growth regulators (PGRs). Since N2-fixing bacteria produce plant growth substances (PGRs), the effect of foliar application of an active strain of Klebsiella sp. (KUPOS) on IR-50 rice was examined using three foliar sprays applied at 10-day intervals. Irrigation once every 3 days was essential for plant growth. Application of KUPOS and 40 kg N ha-1 improved grain yield of acutely water stressed plants from 330 kg ha-1 to more than 1300 kg ha-1 along with an improvement in several growth variables and yield determinants. Indole acetic acid, kinetin and GA3, in a mixture of 10-4 M of each, were less effective than KUPOS in alleviating stress effects. The adverse effects of water stress on respiration and photosynthesis as indicated by CO2 exchange were also alleviated by these treatments. While uptake of K, Mg, Ca, Fe and Mo was increased, Na content decreased, accompanied by an increase in proline content. The order of effectiveness of the treatments was 40 kg N ha-1 〉KUPOS〉PGRs.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00335922
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  • 4
    Digitale Medien
    Digitale Medien
    Biological interactions between soil nitrogen and alkaline-hydrolysing nitrogen fertilizers (1995)
    Springer
    Biology and fertility of soils 20 (1995), S. 41-48 
    Details
    ISSN: 1432-0789
    Schlagwort(e): Added nitrogen interaction ; Ammonia fixation ; 15N ; Immobilization ; Fertilizer-induced solubilization
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Added N interactions were measured in four soil incubated with 15N-labelled urea or diammonium phosphate. The use of biologically active, γ-irradiated, or reinoculated γ-irradiated samples allowed us to separate added N interactions due to chemical and biological processes, and to distinguish real interactions from apparent effects. Real biologically mediated added N interactions were observed in one soil for both fertilizer sources and in three soils amended with urea. These real interactions increased with the N fertilizer rate, but did not differ significantly between N sources. Fertilizer-induced unlabelled organic N in soil extracts declined during incubation in both sterile and non-sterile samples, but the temporal decline was higher in biologically active soil. Changes in fertilizer-induced unlabelled organic N in the extracts of three soils attributed to biological processes were similar to the measured real biologically mediated added N interactions. The results are consistent with the hypothesis that real biologically mediated added N interactions arise from the mineralization of soil organic N solubilized by alkaline-hydrolysing N fertilizers.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00307839
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  • 5
    Digitale Medien
    Digitale Medien
    Mineralization of soil organic nitrogen solubilized by aqua ammonia fertilizer (1996)
    Springer
    Biology and fertility of soils 23 (1996), S. 93-98 
    Details
    ISSN: 1432-0789
    Schlagwort(e): Key words Added nitrogen interaction ; Alkaline-hydrolysing fertilizer ; Aqua ammonia ; Gross N immobilization ; Gross N mineralization ; 15N ; Soluble organic N availability
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Geologie und Paläontologie , Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Organic N solubilized by NH3(aq) was extracted from 15N-labelled or unlabelled soil, concentrated and added to non-extracted soil, which was incubated under aerobic conditions at 27±1°C. Gross N mineralization, gross N immobilization, and nitrification in soils with or without addition of unlabelled soluble organic N were estimated by models based on the dilution of the NH4 + or NO3 – pools, which were labelled with 15N at the beginning of incubation. Mineralization of labelled organic N was measured by the appearance of label in the mineral N pool. Although gross N mineralization and gross N immobilization were increased in two soils between day 0 and day 7 following addition of unlabelled organic N solubilized by NH3(aq), there was no increase in net N mineralization. Solubilization of 15N-labelled organic N increased and the 15N enrichment of the soluble organic N decereased as the concentration of NH3(aq) added increased. A constant proportion of approximately one-quarter of the labelled organic N added at different rates to non-extracted soil was recovered in the mineral N pool after an incubation period of 14 days, and the availability ratios calculated from net N mineralization data were 1.1:1 and 2.1:1 for 111 and 186 mg added organic-N kg–1 soil, respectively, indicating that the mineralization of organic N was increased by solubilization.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00335824
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  • 6
    Digitale Medien
    Digitale Medien
    Chemical interactions between soil N and alkaline-hydrolysing N fertilizers (1993)
    Springer
    Nutrient cycling in agroecosystems 36 (1993), S. 239-248 
    Details
    ISSN: 1573-0867
    Schlagwort(e): Added nitrogen interaction ; alkaline hydrolysis ; ammonia fixation ; aqua ammonia ; di-ammonium phosphate ; fertilizer-induced deamination ; urea
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Land- und Forstwirtschaft, Gartenbau, Fischereiwirtschaft, Hauswirtschaft
    Notizen: Abstract Chemical interactions between soil N and alkaline-hydrolysing N fertilizers labelled with15N were studied in the laboratory using twelveγ-irradiated soils. Fertilizer was recovered in the soil organic N fraction via the process of NH3 fixation. NH3 fixation at day 7 varied from 1.8 to 4.6% of the N added as aqua ammonia at 1000 mg kg−1 soil. The amount of NH3 fixed increased with increasing rates of application of NH3(aq) and urea. The rate of NH3 fixation decreased with time, with more than 55% of the total NH3 fixation in 28 days occurring in the first week following application of 2000 mg urea-N kg−1 soil. Soil pH and NH3 fixation varied in response to N source, and increased in the order of di-ammonium phosphate 〈urea 〈 aqua ammonia at equivalent N concentrations. The alkaline hydrolysis of indigenous organic N occurred simultaneously with NH3 fixation, resulting in the release of unlabelled ammonium (deamination) and a real added nitrogen interaction in all but two of the soils studied. The release of NH 4 + initially increased up to a pH of 7.5, was inhibited between pH 8.5 and 9.0, but increased thereafter. The balance (Nbal) between NH3 fixation and deamination was either positive or negative, depending on the pH of the fertilized soil, which was directly related to N source and concentration for a given soil.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00748702
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  • 7
    Digitale Medien
    Digitale Medien
    Acetylacetone complexes of tetravalent molybdenum (1989)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 570 (1989), S. 159-166 
    Details
    ISSN: 0044-2313
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Acetylacetonat-Komplexe des vierwertigen MolybdänsEinige neue Komplexe des vierwertigen Molybdäns mit Acetylaceton werden dargestellt, wobei sich zwei Reihen von Komplexen mit unterschiedlichen koordinativen Bindungen für Acetylaceton ergeben. Alle Verbindungen werden durch Elementaranalyse, spektroskopische Daten, magnetische und Leitfähigkeits-Messungen charakterisiert.
    Notizen: Some new complexes of tetravalent molybdenum containing acetylacetone have been synthesized by the reaction of acetylacetone with hydrated molybdenum(IV) oxide. Two series of complexes having varied coordination linkages for acetylacetone have been isolated under appropriate conditions. All the compounds were characterized through their elemental analyses, spectral data, magnetic moment and conductance measurement.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/zaac.19895700117
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  • 8
    Digitale Medien
    Digitale Medien
    Nitrosyl rhenium complexes: Syntheses, properties, and structures of acetylacetonato derivatives (1987)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 548 (1987), S. 217-224 
    Details
    ISSN: 0044-2313
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Nitrosyl-Rhenium-Komplexe: Darstellung, Eigenschaften und Struktur von Acetylacetonato-DerivatenEinige neue Rhenium-Komplexe, wie [Re(NO)(acac)2(Cl)H2O] und Re(NO)(acac)3(acacH)(H2O)2 wurden durch Umsatz von Re(NO)Cl3 · H2O bzw. Re(NO)(OH)3 · H2O mit Acetylaceton dargestellt. Ferner wird die Darstellung von [Re(NO)(py)(acac)2(Cl) · H2O], [Re(NO)(acac)(OH)(Cl) · H2O], [Re2(NO)2(acacH)3(acac)2 · Cl4], [Re(NO)(acac)2(OH) · H2O] · 2 H2O angegeben. Die Komplexe werden durch Elementaranalyse, spektroskopische, magnetische und Leitfähigkeitsdaten charakterisiert.
    Notizen: Some new complexes of rhenium containing monocoordinating acetylacetone viz. [Re(NO)(acac)2(Cl)H2O], Re(NO)(acac)3(acacH)(H2O)2 have been synthesized by reacting acetylacetone with either Re(NO)Cl3 · H2O or Re(NO)(OH)3 · H2O. The preparation of [Re(NO)(py)(acac)2(Cl) · H2O], [Re(NO)(acac)(OH)(Cl) · H2O], [Re2(NO)2(acacH)3(acac)2 · Cl4], [Re(NO)(acac)2(OH) · H2O] · 2 H2O have also been described. These complexes were characterized through their elemental analyses, u.v., vis, i.r., 1Hn.m.r., magnetic, and conductance data.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/zaac.19875480524
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  • 9
    Digitale Medien
    Digitale Medien
    Cyanogen Complexes of Rhenium. IV (1965)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 340 (1965), S. 82-85 
    Details
    ISSN: 0044-2313
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Durch Umsetzung von Aquopenta-cyanorhenaten(II) mit Alkalicyaniden wurden die hexacyanoferrat(II)-analogen Salze K4[ReII(CN)6] · 3 H2O und Na4[ReII(CN)6] · 5 H2O gewonnen, die diamagnetisch und aus deren wäßrigen Lösungen die entsprechenden schwerlöslichen Cu(II)- und Co(II)-Salze auszufällen sind.
    Notizen: Preparation of K4ReII(CN)6 · 3 H2O and Na4ReII(CN)6 · 5 H2O analogous to hexacyanoferrates(II) are described. They have been prepared by the treatment of corresponding aquopentacyano-rhenates(II) with alkali cyanides. The insoluble copper and cobalt salts have also been prepared. The hexacyanorhenates(II) are diamagnetic at room temperature.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/zaac.19653400110
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  • 10
    Digitale Medien
    Digitale Medien
    Preparation of some nickel(II) and copper(II) complexes of the SCHIFF-Base derived from Acetophenone and Ethylenediamine (1972)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 389 (1972), S. 215-219 
    Details
    ISSN: 0044-2313
    Schlagwort(e): Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Beschreibung / Inhaltsverzeichnis: Es wird über Herstellung und Eigenschaften von NiII- und CuII-Komplexen mit der SCHIFFschen Base „BAPE“ aus Acetophenon und Äthylendiamin sowie über gemischte BAPE/Acetylaceton-Komplexe berichtet (Formeln I-V s. Abstract). BAPE wirkt dabei als zweizähniger Neutralligand. Die Komplexe wurden durch Elementaranalyse, Elektronenspektrum sowie durch magnetische und Leitfähigkeitsmessungen charakterisiert. Für MII(BAPE)Cl2 wird pseudotetraedrische, für [MII(BAPE)(acac)(H2O)2] ClO4 tetragonale Struktur abgeleitet (MII = Ni, Cu). Der Komplex [Ni(BAPE)(acac)]ClO4 erwies sich als quadratisch-planar.
    Notizen: Preparation and properties of the following NiII and CuII complexes of the Schiff base derived from acetophenone and ethylenediamine (BAPE) and also of the mixed NiII and CuII chelates with BAPE and acetylacetone (acac-H) are described: In each case the Schiff base, BAPE, acts as a neutral bidentate ligand. The complexes are characterised by electronic spectra, magnetic susceptibilities, conductivities and elemental analyses. Pseudotetrahedral structure is proposed for M(BAPE)C12, while tetragonal structure for [M(BAPE)(acac)(H2O)2]ClO4 (M = Ni and Cu). The complex [Ni(BAPE) (acac)]ClO4 has been found to be square planar.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/zaac.19723890213
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