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  • 1990-1994  (3)
  • 1980-1984  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 124 (1993), S. 355-366 
    ISSN: 1434-4475
    Keywords: Vanadyl(IV) saccharinate ; IR spectra ; Electronic spectra ; Magnetic and thermal behaviour
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The synthesis of a new vanadyl(IV)/saccharin complex is reported. Its bonding characteristics differ considerably from all known divalent metal-saccharinates. In this complex a VO(OH)+ moiety is coordinated to a saccharin molecule through its carbonyl oxygen and to a saccharinate ion through its deprotonated nitrogen. Two water molecules complete the coordination sphere. X-ray powder diagrams, infrared- and electronic absorption-spectra were recorded and analyzed for the characterization of the compound and its coordination properties. Besides, the magnetic susceptibility and the thermal behaviour were also investigated.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 465 (1980), S. 153-158 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Spectroscopic Investigation of the Oxodiperoxooxalatomolybdate(VI)AnionThe infrared and electronic spectra of K2[MoO(O2)2C2O4] are recorded and interpreted. The characteristics of the metal-oxygen and metal-peroxide bonds are discussed and some comparisons with related species are made.
    Notes: Die Infrarot- und Elektronenabsorptionsspektren von K2[MoO(O2)2C2O4] wurden aufgenommen und gedeutet. Die Eigenschaften der Metall-sauerstoff- und Metall-Peroxid-Bindungen wurden analysiert und in Zusammenhang mit verwandten Spezies diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 486 (1982), S. 215-220 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Spectroscopic and Magnetic Properties of CuPO4H · H2O and Cu4H(PO4)3 · 3 H2OThe i.r., electronic (reflectance) and e.s.r. spectra and the magnetic susceptibilities of the title compounds are measured and discussed. It is demonstrated that the CuII ions show a similar coordination behaviour in both compounds.
    Notes: Es wurden die IR-, Elektronen(Reflexion)- und ESR-Spektren sowie die magnetischen Suszeptibilitäten der Titelverbindungen gemessen und diskutiert. Es wird gezeigt, daß in beiden Verbindungen die CuII-Ionen ähnliche Koordinationsverhältnisse aufweisen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 515 (1984), S. 207-212 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Hydrolytic and Thermal Behaviour of Sn3PO4F3The behaviour of Sn3PO4F3 in aqueous solutions, has been investigated under different experimental conditions. It is shown that the compound possesses a high hydrolytic stability. The thermal behaviour has been analyzed by means of TG/DTA measurements and the decomposition products have been characterized by X-ray diffraction and 119Sn-Mössbauer spectroscopy. A detailed study of the SnF2/H3PO4 system, allows the formulation of new preparative procedures for Sn3PO4F3 and monoclinic Sn3(PO4)2.
    Notes: Es wurde das Verhalten von Sn3PO4F3 in wäßrigen Lösungen unter verschiedenen experimentellen Bedingungen untersucht. Dabei wurde festgestellt, daß diese Phase eine sehr hohe hydrolytische Stabilität besitzt. Das thermische Verhalten wurde mittels TG/DTA-Messungen untersucht und die Zersetzungsprodukte röntgenographisch und durch 119Sn-Mößbauer-Spektroskopie charakterisiert. Eine eingehende Untersuchung des SnF2/H3PO4-Systems erlaubte weiterhin, neue Darstellungsmethoden für Sn3PO4F3 und monoklines Sn3(PO4)2 auszuarbeiten.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 23 (1992), S. 15-20 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The Raman spectrum of solid [Fe(Sac)2 (H2O4)] · 2H2O was recorded and assigned. Some comparisons with the spectra of the related copper(II) and nickel(II) complexes were also made. The excitation profiles of the vibrational modes that show pre-resonance on excitation with laser lines within the electronic bands are reported. On this basis, and with the aid of a semi-empirical extended Hückel MO calculation, the assignment of the metal - ligand vibrations and the interpretation of the electronic spectrum could be reinforced.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 24 (1993), S. 627-631 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Information on the vibrational and electronic properties of the [VO(biuret)(SO4)] · 3H2O complex was improved in order to gain a deeper insight into the characteristics of the metal-ligand bonds. Normal Raman and pre-resonance Raman studies were performed, which allowed a better characterization of the metal-ligand modes and a thorough analysis of the electronic spectrum. The results were also compared with theoretical semi-empirical molecular orbital calculations.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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