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  • 1990-1994  (6)
  • 27.60.+j  (2)
  • Analytical Chemistry and Spectroscopy  (2)
  • 14.60  (1)
  • 21.10  (1)
Material
Years
Year
Keywords
  • 1
    ISSN: 1432-0649
    Keywords: 07.77 ; 07.80 ; 32.80 F ; 14.60
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We report here on the development of a high-temperature laser ion source useful for trace analysis and other applications. It consists of a high temperature ionization chamber, three tunable dye lasers pumped by copper vapor lasers for stepwise resonant ionization and a Mattauch-Herzog mass spectrometer for the analysis of photo-ions. The principle of the laser ion source and its theoretical efficiency are discussed, where the efficiency of a laser ion source is the ratio of photo-ions extracted out to the number of atoms introduced into the cavity. Experimentally, an efficiency of 2×10−3 has been achieved for technetium. The scheme of gated detection is described which is used for suppressing isobaric background of molybdenum. The possible improvements are briefly mentioned for achieving isotopic analysis of 108 atoms of 97,98Tc in the presence of 1015 atoms of molybdenum, as separated chemically from molybdenum ore. Such an analysis of technetium isotopes produced in molybdenite ore by a (v,e −) reaction, is expected to yield information about the solar neutrino flux.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-601X
    Keywords: 21.10 ; 21.60 ; 27.70 ; 27.80 ; 35.10.F
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The hyperfine structure splitting and the isotope shift in the λ=266 nm transition of Pt isotopes within the mass range 183 ≦A≦ 198 have been determined by Resonance Ionization Mass Spectroscopy (RIMS) in combination with Pulsed-Laser Induced Desorption (PLID). The Pt isotopes were obtained at the on-line isotope separator ISOLDE-3/CERN as daugthers of the primarily produced Hg isotopes. Magnetic moments, quadrupole moments, and changes in the mean-square charge radii are deduced and compared with results of a particle-triaxial rotor model and mean field calculations. Good agreement with experimental data (including nuclear level schemes and transition probabilities) can only be obtained if triaxial shape is admitted. The calculations yield a smooth transition in the shape of odd-A Pt nuclei from a slightly deformed, nearly oblate195Pt via triaxial197-187Pt to a strongly deformed nearly prolate177Pt.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-601X
    Keywords: 21.10.Hw ; 21.10.Ky ; 21.60.Cs ; 23.20.Ck ; 23.20.Lv ; 27.60.+j
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The neutron-deficient nuclei100,101Cd were identified for the first time in — beam following the reactions58Ni +46,48Ti and58Ni +50Cr at 230 MeV and 245 MeV bombarding energy of the58Ni beams. Theγ-decay of the isotopes100,101,102Cd was studied inpγ, ppγ,nγ, nnγ, andnγγ prompt and delayed coincidence spectra. Isomers were found with spin and half life {ie1-01}=8+, T1/2=52(5) ns in100Cd, {ie1-02}=(19/2+), T1/2=4.6(4) ns in101Cd and {ie1-03}=8+, T1/2=56(4) ns in102Cd. In a PAD experiment theg-factor of the {ie1-04}=8+ isomer in100Cd was measured to be g=1.24(6). Using the reaction36Ar +70Ge at 135 MeV energy of the36Ar beam, theg-factor and the quadrupole moment of the {ie1-05}=8+ isomer in102Cd were measured to be g=1.29(3) and Q=87(10) fm2, respectively. The spectroscopic results are discussed within a shell model approach using a100Sn core, which accounts well for the electromagnetic properties of the proton aligned isomers. The structure of the spherical neutron states, dominated by the close lying vd5/2, g7/2 orbitals, and the gradually developing quadrupole collectivity are reproduced by the shell model calculations.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1434-601X
    Keywords: 21.10.Re ; 23.20.Lv ; 27.60.+j
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Excited states of the nuclei127Xe and125Xe have been investigated in the inverse kinematic reactions48 Ca(82 Se,(3.5)n) at 275 MeV beam energy with the OSIRIS multidetector system at the VICKSI-accelerator of the HMI Berlin. The level scheme of127Xe was extended up to a level of tentative spin (51/2−). Two excited bands of 3QP-character were observed. For125Xe these structures were extended towards higher spins. Experimental Routhians of selected bands are presented.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The collision-induced dissociation of positively charged gold clusters (2-23 atoms) stored in a Penning trap has been studied. After collisions with rare gases, excited clusters predominantly decay by emission of one or two atoms. The loss of two atoms occurs most probably through the emission of a dimer rather than by a sequential evaporation. The minimum kinetic energies of clusters required to induce dissociation exhibit a pronounced odd-even effect. Clusters with an even number of delocalized electrons are more stable than those with an odd number.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. 133-136 
    ISSN: 0749-1581
    Keywords: 17β-Substituted 14α-steroids ; 7α-substituted 14α-steroids ; 1H NMR ; 13C NMR ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: γgaucheEffects of 17β- and 7α-substituted 14α-steroids were studied by 1H and 13C NMR spectroscopy. A linear correlation was found between the 1H chemical shift of H-12β and the 13C chemical shift of C-12 for C-17β-substituted steroids and between the chemical shifts of H-14α and C-14 in C-7α-substituted compounds.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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