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  • 1980-1984  (4)
  • 1975-1979  (5)
  • Chemistry  (9)
  • Polymer and Materials Science  (9)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 3019-3025 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The thermomechanical behavior of particle composites was investigated in their transition region. In particular, the value of the glass-transition temperature Tg, which constitutes an upper limit for the structurally important glassy region, was examined. According to experimental evidence existing in the literature the introduction of a reinforcing filler in a polymeric matrix causes Tg of the latter to increase, unless mechanical imperfections counterbalance the reinforcing effect or even produce a Tg for the composite which is lower than that of the matrix. Based on mechanical theories, valid for the mechanical moduli of viscoelastic particle composites, a model was introduced that explains why the glass transition of composite materials may be reduced in some cases, whereas it may be increased in others. The concept of interphase between inclusions and matrix was used for the development of the model. Interphase is assumed to be a region, which is created between the matrix material and the filler particles, both considered as homogeneous and isotropic, whose thermomechanical properties and volume fraction may be determined from the overall thermomechanical behavior of the composite.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3641-3649 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Retardation spectra, derived from dynamic measurements of extension compliances along three decades on the logarithmic scale of frequencies in standard specimens prepared from a fiber-reinforced composite with their fibers parallel to the longitudinal axis of the specimens, have revealed the structure of the matrix material of the composite. The experimental results were used to prove that the physicochemical rearrangements in the vicinity of the inclusions, consisting of restrained development of the macromolecules and especially their side chains due to the presence of the other phase, concentration of voids and dirt, shrinkage stresses developed during curing and creating microcracks (radial as well as along the interface), are activated by the existence of high stress gradients and eventually stress singularities due to the strong adhesion developed between phases.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 903-910 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A class of amine-cured epoxy resins containing various amounts of polysulfide plasticizer were subjected to dynamic testing during curing at high temperature. Both E modulus and loss factor were determined simultaneously. It was proved that the method allowed for rapid determination of the general pattern of the crosslinking procedure and the necessary curing time and, in general, that dynamic methods are most suitable for the mechanical characterization of polymers under curing at each stage of the curing cycle.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3145-3153 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of moisture absorption on the extent of the boundary interphase in particulate composites is thoroughly studied. It was found that, during the process of moisture absorption there is a variation of the extent of the boundary interphase, closely related to the degradation of the mechanical behavior of the composite, as well as to the percentage amount of moisture absorbed. An explanation of the observed relationship was advanced, based on a theoretical mechanism of absorption. This study complements a previous one, where the observed degradation of the thermomechanical properties of particulate composites due to moisture absorption was shown to be intimately interrelated with the state and extent of the interphase between fillers and matrix.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 689-701 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal expansion coefficients and glass transition temperatures for metal-epoxy composites were determined experimentally. Results were in fair agreement with existing theories when certain fundamental assumptions were fulfilled. The effects of filler content and particle size as well as of adhesion between matrix and filler particles were investigated. The latter, in particular, was found to be of cardinal importance for the properties examined in the present work.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 1417-1430 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A class of plasticized epoxy polymers were subjected to indentation tests over a wide range of temperature and plasticizer percentage. Constant or continuously varying temperature tests were carried out under constant load, and the materials exhibited creep behavior according to the temperature and the amount of plasticizer. Thermal expansion properties were also studied, and glass transition temperature as well as thermal expansion coefficients a1 and a2 were determined for each individual material. Theoretical predictions were found valid under the present conditions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 1725-1734 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A series of cold-setting epoxy polymers, plasticized with different amounts of plasticizer, ranging between 0 and 90% by weight of the amount of the epoxy prepolymer, were studied for their mechanical, optical, and fracture behavior properties. Quantities defining the mechanical properties were considered: the elastic modulus E, Poisson's ratio v, and fracture tensile stress σf. These were accurately measured with electric strain gauges in specimens tested in a 5-ton Instron tester. The optical behavior was characterized by the stress optical coefficients of the materials in both principal directions, α and β, as well as by the coefficient of optical anisotropy, ζ. The values of these quantities were measured by a Fizeau interferometric method. Finally, the optical method of caustics was applied to cracked epoxy polymer specimens to provide a new experimental technique for determining the stress optical properties of these polymers in terms of their mechanical properties. This method was used to check the previous results found by established experimental methods.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 2245-2252 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A class of aluminum-filled epoxy composites were subjected to indentation tests over a wide temperature range. The tests were carried out under constant load and continuously varying temperature. The effect of aluminum content, applied load, and adhesion efficiency between matrix and aluminum particles on the indentation behavior was studied. Measured indentation values were found to lie within limits predicted theoretically.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 2997-3011 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The static and dynamic elastic moduli of particulate composites, consisting of two phases, one of which has isotropic-elastic and the other linear viscoelastic properties, were studied. For this purpose a model defining the approximate equations for determining the elastic modulus of a composite from the properties of the constituent materials was used. Classical theory of elasticity was applied to this simplified model of a composite-unit cell. The following assumptions are made: (i) filler particles are spherical; (ii) fillers are completely dispersed; and (iii) the volume fraction of fillers is sufficiently small, so that any interaction among fillers may be neglected. A class of iron-filled epoxy composites was subjected to tests in order to compare the theoretical values with the experimental results. The elastic modulus calculated by the expression derived in this study seems to corroborate with the experimental results fairly well. Finally, by applying the correspondence principle to this expression, theoretical relationships for the dynamic storage and loss moduli were also derived.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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