ISSN:
0009-2940
Keywords:
Aldehydes
;
Ketones
;
Titanium complexes
;
Niobium complexes
;
Tantalum complexes
;
Phosphonium chlorides
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Transition Metal-Activated Organic Compounds, XXXVII[1]. - A Novel Reaction of Aldehydes and Ketones: Synthesis and Spectroscopic Investigation of α1-Phosphonioalkoxy Transition Metal ComplexesHerrn Professor Ulrich Schöllkopf zum 65. Geburtstag gewidmet.By treatment of aldehydes and ketones with one mole equivalent of a Lewis acid (TiCl4, NbCl5, TaCl5) and one mole equivalent of PPh3, or in one case of Ph2PCH2CH2PPh2, the aldehyde derivates [R1CH(P+Ph2R2)-OMCln]Cl- (4-8; M=Ti, Nb, Ta; R2=Ph or CH2CH2PPh2) and the ketone derivatives [R1R2C(P+Ph3)-ONbCl4]Cl- (9-10) were prepared. Complexes 4-10 were isolated as air-and water-sensitive solids. According to the NMR spectra some of the obtained aldehyde derivatives 4-8 exist in solution as a mixture of isomers or oligomers, whereas the ketone derivatives 9 and 10 form in solution an equilibrium with the free ketone and the complex NbCl5 · PPh3. The chloride ion of 4-10 is perhaps coordinated to the metal.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260224
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