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  • 1
    Electronic Resource
    Electronic Resource
    Determination of rate of heteroexchange in the system molecular oxygen-solid oxide (1969)
    Springer
    International applied mechanics 5 (1969), S. 313-319 
    Details
    ISSN: 1573-8582
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00896228
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  • 2
    Electronic Resource
    Electronic Resource
    Reactivity of oxygen on the surface of complex oxides (1969)
    Springer
    International applied mechanics 5 (1969), S. 344-350 
    Details
    ISSN: 1573-8582
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00896233
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  • 3
    Electronic Resource
    Electronic Resource
    Kinetics of exchange and species of oxygen on the surface of oxide catalysts (1974)
    Springer
    Reaction kinetics and catalysis letters 1 (1974), S. 315-319 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract На основании кинетических закономерностей изотопного обмена установлено, что гетерообмен O2 на поверхности окислов осуществляется по двум различным механизмам: 1) за счет обратимой адсорбции с образованием двух атомных форм с различной прочностью связи и 2) через трехатомный комплекс из молекулы и поверхностного атома кислорода. Наяду с этим, может протекать гомообмен молекулярного кислорода по ассоциативному механизму.
    Notes: Abstract On the basis of the kinetic law of isotope exchange, it has been established that the heteroexchange of O2 occurs via two different mechanisms: 1/reversible adsorption resulting in the formation of two atomic species with different bonding strengths, and 2/formation of a triatomic complex from the oxygen molecule and an oxygen atom on the surface. Simultaneously, the homoexchange of molecular oxygen may take place by an associative mechanism.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02070900
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  • 4
    Electronic Resource
    Electronic Resource
    Isotope exchange of molecular nitrogen on barium nitride (1981)
    Springer
    Reaction kinetics and catalysis letters 16 (1981), S. 247-251 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract По активности в изотопном обмене азота нитрид бария на 2–3 порядка превосходит Fe и Ru. Энергия активации обмена в области 373–673 К составляет 40 кДж/моль.
    Notes: Abstract The activity of barium nitride in the isotope exchange of nitrogen is 2–3 orders of magnitude higher than that of Fe and Ru. In the temperature range from 373 to 673 K the activation energy of exchange is 40 kJ/mol.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02065467
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  • 5
    Electronic Resource
    Electronic Resource
    Kinetic, conductivity and ESR studies of superconducting Y−Ba−Cu−O ceramics with controlled oxygen content (1989)
    Springer
    Reaction kinetics and catalysis letters 39 (1989), S. 411-417 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Измерена энергия активации Ea выхода кислорода из керамики YBa2Cu3O7-δ для значений δ от 0 до 0,2. Показано, что в интервале δ от 0,006 до 0,15–0,18 кислород достаточно однороден и характеризуется Ea=(36±3) ккал/моль. Изучены температурные зависимости низкополевого сигнала ЭПР этих керамик на частоте 9,3 КГц вблизи Tc.
    Notes: Abstract The activation energy Ea of oxygen evolution from the YBa2Cu3O7−/gs ceramics has been measured for σ ranging from 0 to 0.2. In the σ range from 0.15 to 0.18 oxygen is fairly homogeneous and its evolution is characterized by Ea=(36±3) kcal/mol. Temperature dependence of a low-field ESR signal of the ceramics have been studied at a frequency of 9.3 KHz nearby TC.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02071361
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  • 6
    Electronic Resource
    Electronic Resource
    Silylation effect on the catalytic properties of FeZSM-11 in benzene oxidation to phenol (1994)
    Springer
    Reaction kinetics and catalysis letters 52 (1994), S. 275-283 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The outer surface of FeZSM-11 zeolite was selectively silylated without affecting the inner system of its channels. SiO2 deposition suppressed both the acidity and catalytic activity of the outer surface in mesitylene isomerization. Neither zeolite activity, nor its stability in N2O benzene oxidation to phenol have changed upon silylation. This fact gives evidence that the latter reaction proceeds primarily within the zeolite channels.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02067799
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  • 7
    Electronic Resource
    Electronic Resource
    Catalytic properties of nitrides in ammonia synthesis (1985)
    Springer
    Reaction kinetics and catalysis letters 29 (1985), S. 267-274 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract При давлении до 100 бар исследован синтез аммиака на нитридах CeN, UN1, 70 и железном катализаторе CA-1. Кинетика реакции описывается уравнением Темкина-Пыжова. Энергия активации для всех образцов близка и составляет около 200 кДж/моль. Удельная каталитическая активность нитридов уступает железному катализаторы: 3–4 раза для урана и в 10 раз для церия.
    Notes: Abstract Ammonia synthesis on nitrides CeN, UN1.70 and iron catalyst CA-1 has been examined at pressures of up to 100 bar. Reaction kinetics is described by the Temkin-Pyzhev equation. Activation energy for all samples is similar and equals about 200 kJ/mol. Specific catalytic activity of nitrides is lower than that of the iron catalyst by a factor of 3–4 for uranium and 10 for cerium.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02067978
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  • 8
    Electronic Resource
    Electronic Resource
    Rate of14N2 desorption from the surfaces of nitrides in the presence and absence of15N2 in the gas phase (1985)
    Springer
    Reaction kinetics and catalysis letters 29 (1985), S. 433-441 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Проведены измерения скоростей десорбции азота14N2 с поверхности нитридов в присутствии и отсутствии молекул15N2 в газовой фазе. Показано, что независимо от теплоты адсорбции и атомности поверхностных частиц адсорбция молекул15N2 не влияет на скорость десорбции14N2.
    Notes: Abstract The rates of14N2 desorption from the surfaces of nitrides have been measured in the presence and absence of15N2 in the gas phase. Whatever the adsorption heat and the form of surface species, the adsorption of15N2 molecules does not affect the rate of14N2 desorption.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02068538
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  • 9
    Electronic Resource
    Electronic Resource
    Low-temperature oxidation of hydrogen on platinum (1978)
    Springer
    Reaction kinetics and catalysis letters 9 (1978), S. 239-244 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Исследовано взаимодействие кислорода, адсорбированного на платине, с водородом в области низких температур, Показано, что молекулярная форма поверхностного кислорода способна принимать участие во взаимодействии с водородом. В области 170–350°К измерена стационарная скорость реакции окисления водорода, энергия активации которой равна 3 ккал/моль.
    Notes: Abstract The interaction of oxygen adsorbed on platinum with hydrogen at low temperatures has been studied. The molecular surface oxygen is shown to be involved in the reaction with hydrogen. The steady-state rate of hydrogen oxidation has been measured at 170–350 K. The activation energy is 3 kcal/mol.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02068931
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  • 10
    Electronic Resource
    Electronic Resource
    Isotope exchange of nitrogen on magnesium, calcium and lanthanum nitrides (1980)
    Springer
    Reaction kinetics and catalysis letters 15 (1980), S. 263-268 
    Details
    ISSN: 1588-2837
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Abstract Установлено что нитрид кальция обладает высокой каталитической активностью в изотопном обмене азота. Показано отсутствие зависимости каталитической активности нитридов от теплоты их образования. Исследовано влияние H2 и O2 на изотопный обмен азота.
    Notes: Abstract It has been found that calcium nitride possesses a high catalytic activity in the isotope exchange of nitrogen. The catalytic activity of nitrides is shown to be independent of the heat of their formation. The effect of H2 and O2 on the isotope exchange of nitrogen is studied.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02062443
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