ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary 1. The reaction of ferrocene derivatives with aryldiazoniums was studied. 2. On arylating p-tolylferrocene with p-tolyldiazonium, 1,1′-di-(p-tolyl)ferrocene was obtained. 3. On reacting methyl- and ethylferrocene with phenyldiazonium, a mixture of arylation products is formed, from which are obtained heteroannular methylphenylferrocene and ethylphenylferrocene. 4. Dipropionyl-, dibutyryl-, and dibenzoylferrocene react with p-nitrophenyldiazonium with rupture of the ferrocene nucleus, giving low yields of derivatives on a 1,2,3-oxadiazine. 5. On reacting the dimethyl ester of ferrocenedicarboxylic acid with p-nitrophenyldiazonium, both arylation and rupture of the ferrocene nucleus take place. 6. Monoacetylferrocene and the methyl ester of ferrocenemonocarboxylic acid are arylated on reacting with p-nitrophenyldiazonium.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00909405
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