ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Crystal Structure of 2,4,4-Trifluoro-1,3-dithietan-2-ylium HexafluoroarsenateCrystals of [F2CS2CF]⊕ [AsF6]⊖ are orthorhombic, space group Pmmn, with a = 764.9(1), b = 831.7(1), c = 690.3(1) pm. The cation possesses mm symmetry and does not show any short intermolecular interactions. The C—F and C—S bonds to the cationic carbon are significantly shorter than the other C—F and C—S bonds. The anion exhibits twofold disorder.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19851181231
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