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  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 21 (1994), S. 718-723 
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The formation of Schottky barriers at the Sb/n-ZnSe interface has been investigated for a selected number of chemically etched n-ZnSe surfaces. Microscopic properties of the surfaces and interfaces have been observed with SEM, XPS, AES and SIMS, while the conventional I-V technique has been used to determine the macroscopic electrical properties. Both polycrystalline ZnSe wafers and molecular beam epitaxy-grown layers of n-ZnSe on n+-GaAs substrates were used for this investigation. Stoichiometric variations resulting from wet chemical etching of n-ZnSe were investigated using XPS, AES and SIMS techniques. The electrical properties of Sb contacts formed by vacuum evaporation on the etched surfaces were also determined. Possible intermixing at the Sb/n-ZnSe interface was studied using the SIMS imaging technique. The correlation between macroscopic electrical properties and microscopic interactions at the interface will be presented in this paper.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 26 (1998), S. 444-454 
    ISSN: 0142-2421
    Keywords: XPS ; ToF-SIMS ; surface segregation ; coil coatings ; adhesion ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The segregation of minor components - a melamine-formaldehyde resin and a poly(acrylic) flow control agent - in a model epoxy resin coil coating applied to hot-dipped galvanized steel has been investigated by high-resolution XPS and time-of-flight SIMS (ToF-SIMS). It is shown that by using the highest resolution monochromated XPS currently available, the C 1s spectrum can be peak fitted to account for all eleven carbon functionalities present in the three components of the organic coating. A ToF-SIMS analysis of the melamine-formaldehyde resin has been undertaken and a comprehensive ion fragmentation scheme for the positive ion spectrum of this molecule in the range 0-500 Da is proposed. It is shown, by both surface analytical techniques, that when the flow control agent is excluded from the formulation the surface of the paint film is enriched in the melamine-formaldehyde component. On addition of the flow control agent such segregation is only identified by XPS; the ToF-SIMS spectrum resembles that of the flow control agent. This is taken to be an indication of monolayer segregation of this component at the paint/air interface. Such segregation phenomena are shown to be insensitive to substrate surface pretreatment. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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