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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 6 (1995), S. 228-234 
    ISSN: 1573-482X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Second-harmonic generation and spectroscopic absorption measurements were made to study the non-linear optical and stability properties of guest/host polycarbonate thin films in which the guest chromophores were oriented by corona poling. Optimum poling conditions were achieved at temperatures less than the glass-rubber transition temperatures. Stabilized order parameters as high as 0.23 and retention of orientational order as high as 86% were found. Stable, resonance-enhanced, values of the non-linear optical coefficient d 33, for the fundamental of 1.064 Μm, were as high as 31 pm V−1. This value is over four times that predicted by a simple thermodynamic model for isotropic materials. Hydrogen bonding between the guest and polycarbonate is proposed to account for the high d 33 coefficients and long-term stability of the films.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 11 (2000), S. 229-234 
    ISSN: 1573-482X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract We report on the photorefractive properties of a stable polymeric material based on the host polymer, poly(N-vinylcarbazole). Two-beam coupling and four-wave mixing experiments were used to measure the performance of devices constructed by sandwiching the material, composed of host, plasticizer, photo-sensitizer, and non-linear optical chromophore, between transparent electrodes. A steady-state diffraction efficiency of 60% and a two-beam coupling gain of 22 cm−1 in excess of the absorption of 4 cm−1 were observed at the laser's operating wavelength of 670 nm. The devices are easily prepared and have lifetimes in excess of one year with no indication of degradation when stored at ambient temperatures.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 3 (1992), S. 187-190 
    ISSN: 1573-482X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Spectroscopic absorption measurements were used to study the non-linear optical thin-film properties of an azo dye-attached polymer in which the dye chromophores were oriented by corona poling. Details of the polymer synthesis, poling configuration and poling procedure are presented. A rigid oriented gas model was used to describe the poled polymer. The stabilized order parameter of 0.51 found is, to the authors' knowledge, larger than any reported for guest-host or chromophore-attached polymeric systems.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 16 (1997), S. 642-644 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Abstracts are not published in this journal
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 11 (1992), S. 794-796 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Computational Chemistry 12 (1991), S. 880-884 
    ISSN: 0192-8651
    Keywords: Computational Chemistry and Molecular Modeling ; Biochemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Computer Science
    Notes: Vibrational spectra were obtained for the structurally similar compounds 2-methylbutyronitrile and 3-methyl-1-pentyne, and vibrational assignments were made with the aid of normal coordinate calculations. Molecular mechanics calculations were also made, and each compound was shown to exist as a mixture of three conformers, with the most stable conformer being the one with the two methyl groups trans to each other. Results of the calculations are given.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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