ISSN:
0040-5744
Keywords:
Key words: AM1
;
Wolff Rearrangement
;
β-Oxy-α-Diazo carbonyl compounds
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract. The study of several thermal processes involved in the β-oxy-α-diazo carbonyl compounds chemistry at the AM1 semiempirical level is reported. Principally, our study focussed on competitive Wolff and 1,2-hydride rearrangement reactions involving nitrogen elimination that a particular type of β-oxy-α-diazo carbonyl compounds (see scheme 1) can undergo under certain conditions. The AM1 results provide a reasonable description of the energy-related and structural aspects involved in the elementary processes considered.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00190152
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