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  • 1
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Precise concentrations of Zr, Y and Nb in the μg/g to ng/g range have been determined in rock samples using multi-ion counting spark-source mass spectrometry (MIC-SSMS). A high resolution method, combined with interference correction on 91Zr and 93Nb for low concentration samples, was applied. An analytical precision of 2–5% for concentrations down to 0.020 μg/g and 10% for lower concentrations was attained. The detection limit is below 0.005 μg/g. By measuring international reference materials, the accuracy of the method was determined to be within about 10% of the recommended values. However, the accuracy of the final concentration is influenced by interference corrections, but the additional error is below 20%. The interference problem is most difficult for Al-rich samples (〉15% Al2O3), as the interfering molecules are 40Ca27Al12C2 + and 27Al3 12C+. The accordance between ICP-MS and MIC-SSMS results is worse for low Nb concentrations in the ng/g range. Here, ICP-MS gives systematically lower values than MIC-SSMS. The reason for this discrepancy is not yet clear, but may be caused by Nb loss during chemical treatment of the samples prior to ICP-MS measurements.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1365-3121
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: The Kostomuksha greenstone belt consists of two lithotectonic terranes, one mafic igneous and the other sedimentary, separated by a major shear zone. The former contains submarine 2.8 Gyr old komatiite-basalt lavas and volcaniclastic lithologies with trace element and isotopic compositions resembling those of recent oceanic flood basalts [ɛNd(T) =+ 2,8, μ.1= 8.73 (Nb/Th)N= 1.5–2.1 (Nb/La)N= 1.0–1.5]. We suggest that the mafic terrane is a remnant of the upper crustal part of an Archaean oceanic plateau derived from partial melting of a mantle plume head. When the plateau reached the continental margin, it collided with the sedimentary terrane but was too buoyant to subduct. As a result, the volcanic section of the plateau was imbricated and obducted thus becoming a new piece of continental crust. The deeper zones were subducted and disappeared from the geological record.
    Type of Medium: Electronic Resource
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  • 3
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    Tübingen : Periodicals Archive Online (PAO)
    Arbeiten aus Anglistik und Amerikanistik. 12:1 (1987) 81 
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 53 (1995), S. 155-164 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Zusammenfassung Baddeleyit vom Palabora Igneous Complex, Südafrika, gehört zu den reinsten natürlichen Vorkommen von ZrO2. Dies wurde durch Analysen mit verschiedenen Methoden wie Mikrosonde, Neutronenaktivierung, Funken- und Thermionenmassenspektrometrie bestätigt. HfO2 ist mit 1.87 die einzige andere Hauptkomponente, auch die Konzentrationen der anderen HFSE sind relativ hoch im Vergleich zu den anderen Elementen, die nur wenige ppm erreichen. Die REE bilden ein U-förmiges Muster, das als Ausdruck einer stark LREE angereicherten Komponente im Ausgangsgestein gedeutet wird. Das hohe87Sr/86Sr-Initialverhältnis von 0.713085 und das negative ɛNdt von -10.7 belegen, daß diese Komponente über einen langen Zeitraum vor der Bildung des Palabora Igneous Complex angereichert gewesen war. Diese Daten deuten an, daβ der Baddeleyit aus einem Magma kristallisierte, das aus einem angereicherten Mantelreservoir stammte, ähnlich dem, das bei der Bildung der Gruppe 11 Kimberlite beteiligt war.
    Notes: Summary Baddeleyite from Palabora Igneous Complex, South Africa, is among the purest natural ZrO2 phases. This has been demonstrated by using various methods, i.e. microprobe, neutron activation, spark source and thermal ion mass spectrometry. HfO2 with 1.87% is the only other major component. The concentrations of other HFSE are also relatively high, compared to most other elements, that reach only a few ppm. The REE display a U-shaped pattern that is interpreted to be superimposed by a strongly LREE enriched source component. The high87Sr/86Sr initial of 0.713085 and the negative ɛNdt of −10.7 prove that this component was LILE enriched for a long time prior to the formation of the Palabora Igneous Complex. These data indicate that the baddeleyite crystallized from a magma which was derived from an enriched mantle reservoir, similar to that involved in the formation of group II kimberlites.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 69 (1980), S. 997-1012 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract Spark source mass spectrometry (SSMS) allows the determination of major, minor and trace elements in solid samples. The different techniques for quantitative multielement analyses are described and compared. A precision of about 2% is achieved by peak switching and isotope dilution. The applicability of SSMS in geo- and cosmochemistry is demonstrated by examples.
    Abstract: Résumé La spectrométrie de masse à étincelles (SSMS) permet de déterminer les éléments majeurs, mineurs et les traces dans des échantillons solides. Les différentes techniques pour l'analyse quantitative des éléments sont décrites et comparées. Par balayage séquentiel et dilution isotopique, une précision d'environ 2 % est atteinte. L'application de la «SSMS» en géo- et cosmochimie est démontrée à partir d'exemples.
    Notes: Zusammenfassung Die Funkenmassenspektrometrie (SSMS) ermöglicht die Bestimmung von Haupt-, Neben- und Spurenelementen in Festkörpern. Die verschiedenen Möglichkeiten der quantitativen Multielementanalyse werden beschrieben und verglichen. Mit dem Peaksprungverfahren und der Isotopenverdünnungsmethode erreicht man eine Genauigkeit von ungefähr 2 %. Die Anwendbarkeit der Funkenmassenspektrometrie in der Geo- und Kosmochemie wird an Hand von Beispielen gezeigt.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' journal of analytical chemistry 364 (1999), S. 380-384 
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract To obtain suitable geological reference materials for microanalytical purposes, a set of eight natural glasses was prepared by direct fusion of rock chips. Multi-ion counting spark source mass spectrometry (MIC-SSMS) has been applied for trace element analysis of these reference materials. The overall analytical uncertainty of the MIC-SSMS results was determined by considering 14 possible sources of errors. It generally ranges between 〈 2–7% depending on the element and its concentration. Nearly all MIC-SSMS data agree with the reference values within 0–10%, indicating that the estimate of the overall analytical uncertainty is reasonable.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Laser plasma ionization mass spectrometry (LIMS) is used in our laboratory as an in-situ microanalytical method for the investigation of solids, especially of rocks and minerals. To demonstrate the accuracy of this method we have analyzed homogeneous geological glass samples. The results are compared with data obtained from other analytical techniques. The performance of the LIMS method for geochemical investigations is discussed.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1432-1130
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The photoplate detection system of a spark source mass spectrometer has been recently replaced by a detector array consisting of 20 separate small channeltrons for simultaneous ion counting of up to 20 trace elements. The new multi-ion counting – spark source mass spectrometry (MIC-SSMS) technique combines the advantages of conventional SSMS with modern on-line detection of elements. It has important analytical features, such as simple and fast solid-state sample preparation, high precision (about 1–2%) and accuracy (4%) using multielement isotope dilution, high sensitivity which leads to short measuring times (10–50 min) and low detection limits (about 0.001–0.01 μg/g).
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 306 (1983), S. 431-436 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Analyses on fresh glass samples of mid-ocean ridge basalt yield a uniform ratio K/U = 12,700 ± 200. In contrast, Th/U increases systematically with Th concentration. From these results we calculate an upper limit (1.5 pW kg−1) and a best estimate (0.6 pW ...
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Hydrous, silica-rich melts migrating through the mantle are preserved as glass inclusions in mantle minerals in xenoliths from Philippine arc lavas. These melts, with chemistries that indicate an origin by very low degrees of melting of the subducted ocean crust, have altered their host ...
    Type of Medium: Electronic Resource
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