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  • 1
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A process has been developed that enables the rapid chemical vapor deposition of superconducting YBa2Cu3Ox. In this process a finely ground mixture of Y(tmhd)3, Ba(tmhd)2, and Cu(tmhd)2 (tmhd=2,2,6,6-tetramethyl-3,5-heptanedionate) is slowly fed, and pneumatically transported, directly into the chemical vapor deposition furnace. Because vaporizers are not used, the number of process parameters that must be controlled is greatly reduced. Deposition rates are at least an order of magnitude greater than those achieved by reagent sublimation. Films have been characterized by scanning electron microscopy, energy dispersive x-ray spectroscopy, x-ray diffraction, and resistance versus temperature measurements. Films produced on planar MgO substrates have Tc values that are significantly higher than previously reported for MgO.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 1337-1344 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Thermal stresses induced during cooling from the fabrication temperature of a fiber with a noncubic superconducting ceramic coating are analyzed theoretically. The coating considered has a preferred crystallographic orientation such that the c axis of the coating material is perpendicular to the fiber surface which, in turn, results in different thermal expansion coefficients in the radial and the tangential directions in the coating. The thermal stresses are shown to result both from the mismatch between the fiber and the coating, and from the thermal expansion anisotropy of the coating. Stresses due to bending of the fiber/coating to form a superconducting component are also addressed. A critical radius of curvature of bending is obtained below which segmentation of the coating is predicted.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 35 (2000), S. 1979-1984 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The microstructure of fiber-reinforced laminated SiC-C matrix composites has been studied using scanning and transmission electron microscopy (SEM and TEM) techniques. Different regions of the composites were found to exhibit microstructural differences due to the temperature gradient imposed during composite fabrication by the forced-flow thermal-gradient chemical vapor infiltration process. The matrix layers of alternating Carbon and SiC were found to be thicker but less clearly defined in the higher-temperature regions than in the lower-temperature regions. This feature was found to be more pronounced with increasing distance from the fiber surface. The medium temperature region was found to represent the intermediate point in the microstructural development of this composite. Possible qualitative explanations for the observed microstructural differences are suggested in the context of the temperature gradient and other process parameters employed.
    Type of Medium: Electronic Resource
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