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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 57 (1985), S. 1022-1028 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Infrared reflection and transmission measurements were used to study the thermally induced regrowth of (100) oriented, Be-implanted GaAs samples. The samples used in this study were implanted at low temperature (−100 °C) with 250-keV Be ions to a fluence of 6×1015 cm−2. The samples were postannealed at temperatures ranging from 100 to 550 °C. Isochronal and isothermal annealing at a series of temperatures between 180 and 240 °C were performed. Infrared reflection spectra were analyzed by using a three or four layer dielectric model. Analysis of the annealing data suggests that an amorphous layer first anneals to a second metastable amorphous state and then becomes a damaged crystalline layer after annealing at 220 °C for 12 h. The observed regrowth is not by a simple epitaxial process. After annealing at 400 °C for 1 h, the damage in the layer is reduced sufficiently for the refractive index to recover almost to the preimplantation value. On annealing at 450 °C free carriers are observed. From the measured average regrowth rate for the amorphous layer at various anneal temperature, an effective activation energy is estimated to be about 1.45 eV. This compares with activation energies of 2.3 eV for Si and 2.0 eV for Ge.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 1927-1935 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Free-charge carriers in both room- and low-temperature Be-implanted GaAs were generated by annealing at 400, 450, and 475 °C and were observed by using both infrared reflection and electrical measurements. Annealing at 400 °C for 2 h removes homogeneously most of the damage-related changes in the refractive index. Longer annealing (∼50 h) or shorter term annealing at higher temperature produces free carriers. A computer model including plasma effects was used to fit the reflection curves. In general the infrared analysis results and the electric data were in reasonable agreement. Results for the room-temperature-implanted samples show the free-carrier density profile, approximated by joined half-Gaussians, to be (i) a standard deviation for the deeper half-Gaussian (σh≤0.1 μm), which is about the same or smaller than that observed by secondary ion mass spectrometry measurements (∼0.13 μm) for the Be profile, and (ii) a peak position 1.2 μm, which is deeper than the Be ion peak at 0.95 μm. Both peak positions remain essentially unchanged during the anneals. Activation of carriers at these low temperatures is not seen in either Si- or Zn-implanted GaAs. The Zn-implanted material has a weak effect at 500 °C, while the Si-implanted material has none up to 550 °C. The free-carrier profile is considered as the combination of the concentration distributions of dopant ions, Ga vacancies, and possible compensating damage-related states. The discussion centers on the detailed results for the Be case.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 59 (1986), S. 1936-1945 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A study is given of the effect of ion implantation on the carrier density and the infrared dielectric constant of heavily doped, high-carrier density, n-type GaAs as measured by infrared reflection. Hydrogen ions were implanted at 300 keV at room temperature and carbon ions at 380 keV at near-liquid-nitrogen temperature. For H and C ions the effects of the implantation and subsequent annealing from 100 to 550 °C are examined. The 1H ion implantation and annealing results are compared with available SIMS data and with the carrier density profile obtained from capacitance-voltage measurements of a progressively etched sample. The 1H and carrier compensation profiles are clearly related and show a compensated layer ∼3 μm thick for the as-implanted samples. A deeply diffused layer is present after annealing and the depth grows with anneal temperature. After 500 °C annealing the carrier compensation in the diffused layer disappears but the original layer is still compensated. The 12C-implanted sample shows both carrier compensation and substantial damage-related changes in the dielectric constant. Annealing removes the damage-related changes and no compensated diffused layer such as that observed for hydrogen was present. An effective diffusion constant for the hydrogen related defect can be estimated but its value is dependent upon the model used. Different models give Deff=D0effe−Ea/kT with Ea about 1 eV but with D0eff values which are strongly model dependent.
    Type of Medium: Electronic Resource
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