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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Lithium zirconate, Li2ZrO3, has been reported as a candidate material for high-temperature CO2 separation. The reaction of Li2ZrO3 with CO2 is extremely fast, and the material can store significant quantities of CO2 at high temperature. The reacted CO2 can be regenerated by thermal cycling. Alternatively, a membrane system might be developed based on the reversible reaction process. For absorption and membrane separation, the particle size, crystal structure, and state of agglomeration of the Li2ZrO3 powders are important. Therefore, we have synthesized Li2ZrO3 using sol-gel procedures and compared its properties with powders made via a powder-mixing route and a commercial-grade powder. The morphologic and structural characteristics of the powders and their CO2 absorption properties are discussed.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-4846
    Keywords: membrane ; SAXS ; TEOS hydrolysis ; fractal dimension ; cluster-cluster aggregation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A study is performed to investigate the structure and shape of silicate molecules, grown from TEOS (tetra-ethyl-ortho-silicate) at 65°C, as building bricks for the preparation of gas separation membranes. The study is mainly carried out with in situ Small Angle X-ray Scattering (SAXS). The structure of the resulting silicate polymers could be interpreted in terms of fractals with a fractal dimension Df and a radius of gyration Rg. During the first minutes of reaction of TEOS with water in the presence of protons as catalysts fast hydrolysis take place with a heat effect of about 15–30 kJ/mol. Condensation (growth) of hydrolyzed species follows according to a diffusion-limited cluster-cluster aggregation (DLCCA). Growth is faster with higher amount of water and acid but a plateau-value is reached for both Rg and Df on a 60-hour timescale when a moderate amount of water or protons are present. These plateau-values are 15 nm and 1.8 for Rg and Df, respectively. The values of Rg and Df have large effects on gas separation performance of the resulting membranes made from these sols. With relatively small deviations in the values of Rg and Df a 2-decade difference in the permeation of helium through the membrane was observed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of anesthesia 11 (1997), S. 80-81 
    ISSN: 1438-8359
    Keywords: Pulmonary aspiration ; Postesophagectomy ; Regurgitation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Flow, turbulence and combustion 54 (1995), S. 237-247 
    ISSN: 1573-1987
    Keywords: riblets ; drag reduction ; bend
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Four riblet bends were tested to investigate the effects of riblets on pipe flows including the secondary flow on the Reynolds numbers; Re D =6×103−4×104. The pressure gradients on the smooth pipe downstream from the riblet bends were measured, and also the pressure losses of the bends only were measured. All riblet bends reduced the pressure gradient on the smooth pipe downstream from them, which means a drag reduction. Two of the riblet bends showed the maximum drag reduction of about 4 percent at Re D = 6500; this reduction rate was significant considering the uncertainty of the present experiments. Since the pressure losses of these two riblet bends were almost identical to that of the smooth bend at Re D = 6500, they could cause a net drag reduction of about 4 percent on the piping system including these bends at that Reynolds number. Furthermore, the velocity profiles measured by LDV indicated that the secondary flow becomes weaker downstream from the riblet bends when a drag reduction is recognized there.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of anesthesia 5 (1991), S. 95-96 
    ISSN: 1438-8359
    Keywords: Internal jugular vein ; Ultrasonography ; Pediatric surgery
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 615-622 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Characteristics of the gel layer were investigated by direct measurement of its concentration treating polyvinylalcohol and ovalbumin aqueous solutions, using cellulose acetate tubular ultrafiltration membranes. The concentration of the gel layer was not constant but a function of bulk concentration and feed velocity. The mass transfer coefficient obtained agreed with Deissler correlation. There was a definite correlation between the resistance of the gel layer and its concentration.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 907-915 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of osmotic pressure and solute adsorption on permeate flux during ultrafiltration of a solute that forms a gel-like layer on membrane surfaces was investigated. Ovalbumin solutions were ultrafiltrated using three different kinds of membranes, polyolefine, polysullfone, and polyacrylonitrile. Flux data were analyzed by three conventional models: gel polarization, osmotic pressure, and resistance in series.The experimental data were in conflict with all conventional models. Data analysis suggested that the main factors which influence permeate flux decline were osmotic pressure increase at the membrane surface and resistance caused by solute adsorption.A new model, which takes into account both osmotic pressure and resistance due to solute adsorption, is proposed. Permeate flux declines observed in the experiments fit this model quite precisely. The gel layer that forms on the membrane surface has little influence on permeate flux and can be neglected.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 1118-1120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 33 (1989), S. 856-861 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A forced-flow enzyme membrane reactor system for sucrose inversion was investigated using three ceramic membranes having different pore sizes. Invertase was immobilized chemically to the inner surface of a ceramic membrane activated by a silane - glutaraldehyde technique. With the cross-flow filtration of sucrose solution, the reaction rate was a function of the permeate flux, easily controlled by pressure. Using 0.5 μm support pore size of membrane, the volumetric productivity obtained was 10 times higher than that in a reported immobilized enzyme column reactor, with a short residence time of 5 s and 100% conversion of the sucrose inversion.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 1203-1208 
    ISSN: 0887-624X
    Keywords: plasma polymerization ; graft polymerization ; polyethylene ; poly(methylacrylate) ; membrane ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Using a plasma-induced graft polymerization technique, which is well known as a surface modification method, the grafted polymer was formed in pores of the porous material. This study examined the filling mechanism. Five thin porous films were sandwiched together, and employed as the substrate. The substrate was treated by plasma, and the change in surface tension and radical formation was measured for each sheet after the sheet was separated. The only surface on which surface-tension change was detected, was that of the sheet directly exposed to the plasma. Although plasma treatment made polymer radicals primarily on the outer surface of the sheet, the treatment also formed a few radicals inside the sheets. The radicals inside the sheets reacted with methylacrylate and grafted polymer formed in the pores. The location of grafted polymer depended on the balance between monomer diffusivity and reactivity. The grafting rate depended on which monomer solvent was used for the polymerization. Thus, the grafted membrane morphology could be controlled by varying the grating solvent composition. © 1996 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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