ISSN:
1588-2780
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Energy, Environment Protection, Nuclear Power Engineering
Notes:
Abstract Reactions of recoil tritium with benzoic acid, acetanilide and β-phenethyl alcohol were studied using the3He/n,p/3H reaction. The tritium distribution in the aromatic ring is approximately uniform in all the irradiated compounds and the tritium activity per C−H bond in the methyl and ethylene groups is 7 to 8 relative to that of the corresponding ring as standard /=100/. These findings are substantially the same as those obtained previously by the6Li/n,α/3H reactions, suggesting the same mechanism of tritiation for both recoil reactions. The tritiated parent compounds were obtained in high radiochemical yields; 45% for benzoic acid, 30% for acetanilide, 12% for β-phenethyl alcohol.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02164990
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