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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 1635-1637 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A mechanism for the transient-enhanced interdiffusion of GaAs-AlGaAs interfaces during rapid thermal annealing of ion-implanted heterostructures is proposed. The model is based on the solution of the coupled diffusion equations involving the excess vacancies and the post-implantation Al distribution following ion implantation. Both initial distributions are obtained from the solution of a three-dimensional Monte Carlo simulation of ion implantation into a heterostructure sample. In general, the model is valid for time frames within which impurity diffusion does not occur appreciably so that impurity-enhanced diffusion remains a weak effect.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 1359-1365 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rapid thermal annealing has been used to diffuse Zn into GaAs from a thin film zinc silicate source prepared by atmospheric pressure chemical vapor deposition. For a diffusion temperature of 650 °C, comparisons were made with conventional, open-tube furnace annealing and the diffusivities were found to be similar, in contrast to previous experimental work. In the temperature range 650–750 °C, sharp zinc diffusion profiles are observed. Above 750 °C, kinks are seen in the diffusion profiles. These kinks are also observed when semi-insulating substrates are used instead of silicon doped n+ -substrates. Previously, we have introduced a zinc diffusion model based on the pairing of interstitial Zn with all acceptor species present during diffusion. The dominant species are found to be substitutional Zn and the gallium vacancy, where the concentration of the latter is a function of the background doping concentration. The results of this model are shown to agree with all of our experimental evidence and are also consistent with our experimental observation of two distinct activation energies for zinc diffusion into n+ -doped GaAs substrates, 1.1 eV and 2.6 eV for temperatures above and below ∼790 °C, respectively.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 2087-2090 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Experimental results of enhanced interdiffusion of GaAs-AlGaAs interfaces are reported. These are obtained by implanting Ar ions at doses ranging from 2×1013 to 5×1014 cm−2 into heterostructure samples followed by rapid thermal annealing at 950 °C for 30 s. The degree of intermixing decreases from the surface up to the projected ion range and is a function of the implantation dose. It is postulated that this variation results from the coalescence of some of the excess vacancies into extended defects, which are then unavailable to assist in the enhanced interdiffusion process. By assuming that the concentration of mobile vacancies at any depth is proportional to the ion's electronic energy loss and inversely proportional to the ion's nuclear energy loss, the calculated intermixing results are shown to be in good agreement with the experimental data.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 60 (1986), S. 602-606 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electron microscopy/diffraction and electron energy-loss spectroscopy, including low-loss and core-edge structures, were used to characterize and study the atomic arrangement in amorphous SnO2 prepared by reactive sputtering. The gross features in the energy-loss spectra are the same as for crystalline SnO2, whereas the fine structures are smeared out. The diffraction pattern of amorphous SnO2 is qualitatively well described by assuming each tin atom to be surrounded by six oxygen atoms at a distance of 2.05 A(ring), two tin atoms at 3.19 A(ring), and eight tin atoms at 3.71 A(ring), which suggests the same local atomic arrangement as in crystalline SnO2.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 2464-2466 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A model is presented that is able to account successfully for the Zn diffusion profiles in n+-GaAs. The model is based on a previously developed formalism whose basis is the retarding of the interstitial Zn diffusivity because of Coulomb pairing between interstitial and substitutional Zn. By extending the model to include Coulomb pairing of interstitial Zn with all acceptors present during diffusion, the resulting theoretical profiles are shown to be in very good agreement with the data while using only one adjustable parameter.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 545-551 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The phenomenon of transient-enhanced interdiffusion of GaAs-AlGaAs interfaces during rapid thermal annealing of ion-implanted heterostructures is studied. It is shown that the important properties that influence the degree of interdiffusion are the temperature, the concentration of excess vacancies, and the ability of the vacancies to diffuse freely. A model is presented to explain these observations; it is based on the solution of coupled diffusion equations involving excess vacancy and Al distributions following ion implantation. Both initial distributions are obtained from the solution of a three-dimensional Monte Carlo simulation of ion implantation into a heterostructure sample. The model is found to be in excellent agreement with several sets of experiments. More specifically, it is shown to be valid for as-implanted vacancy concentrations below 6×1019 cm−3.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 1145-1147 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Layer intermixing in MeV Si-implanted GaAs/AlGaAs superlattices (SLs) with doses between 3×1015 and 1×1016 /cm2 has been examined by transmission electron microscopy and secondary-ion mass spectrometry. After either rapid thermal annealing at 1050 °C for 10 s or furnace annealing at 850 °C for 3 h, all the SLs showed a highly crystalline, defect-free zone in the near-surface region followed by a band of secondary defects, with the maximum density located about 1 μm below the surface. A totally mixed region, within the secondary defect band, occurred only in the SL implanted to 1×1016 Si/cm2 and annealed at 850 °C for 3 h. At lower doses or under rapid thermal annealing, only slight Al/Ga interdiffusion was observed, primarily in the layers that contained the high density of dislocation defects. For either annealing condition, the Si concentration profiles showed only slight broadening and they correlated with the distribution of secondary defects as well as with the depth of the intermixed layer. The effects of dynamic annealing and surface on the implantation energy dependence, i.e., MeV vs keV, of layer intermixing are discussed.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 53 (1988), S. 2531-2533 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have studied the disordering phenomenon in GaAs-AlGaAs superlattices induced by Si implantation followed by rapid thermal annealing. Disordering has been detected in superlattices implanted with 220 keV Si+ at doses ≥1×1015 cm−2 and annealed at 1050 °C for 10 s. The amount of disordering saturates with time after 10 s annealing, whence the lattice damage caused by the implantation is predominantly annealed out and little Si diffusion detected. The transient disordering is attributed to defect-induced layer intermixing occurring during the annealing of the implantation damage. The defect-induced disordering has been simulated by solving two coupled diffusion equations for aluminum and vacancies, and good qualitative agreement with experimental results has been obtained.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 651-653 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Intermixing of AlGaAs-based interfaces is known to be enhanced by capping wafers with a layer of SiO2. Assuming that this enhancement results from the introduction of additional Ga vacancies into the sample, it is possible to obtain the temperature-dependent equilibrium Ga vacancy diffusivity. Experiments are performed whereby SiO2-capped quantum well samples are annealed at temperatures ranging from 800 to 1025 °C. Calculated photoluminescence shifts are compared with the measured spectra, and a relation for the Ga vacancy diffusivity of the form 0.962 exp(−2.72/kBT) cm2/s is obtained. Using this relation, the equilibrium Ga vacancy concentration can be computed via an ensemble Monte Carlo simulation. The resulting expression is 1.25×1031 exp(−3.28/kBT) cm−3.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0040-6090
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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