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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 1457-1459 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Internal photoemission has been observed in the spectral response of specially designed Ga0.47In0.53As-InP p+N− heterojunction photodiodes. Power-law fits to the internal photoemission as a function of photon energy allow precise determination of threshold energies from which the conduction-band discontinuity is easily and accurately deduced to be ΔEc=203±15 meV at room temperature. These measurements have been performed at temperatures from 135 to 297 K. The temperature dependence of ΔEc is described by ∂(ΔEc)/∂T=−0.2±0.1 meV/K.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 341-343 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of hydrogenation and subsequent annealing on unintentionally doped GaAs layers grown directly on Si substrates by metalorganic chemical vapor deposition have been characterized by capacitance-voltage measurements, Hall effect measurements, transmission electron microscopy (TEM), and energy dispersive spectroscopy (EDS). Significant reduction of the carrier concentration in the GaAs layers after hydrogen plasma exposure is obtained. TEM shows that the hydrogen plasma slightly etches the surface of the GaAs layers, and EDS demonstrates that the etched area becomes arsenic deficient and contains minute Ga particles. In addition, atomic hydrogen diffuses deeply along threading dislocations and microtwin interfaces into the GaAs layers and reacts with GaAs locally around the defects.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 1905-1907 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A mixture of 500 ppm CCl4 in H2 has been used to grow heavily doped p-type GaAs by low-pressure metalorganic chemical vapor deposition with TMGa and AsH3 as the group III and V sources, respectively. Carbon acceptor concentrations between 1×1016 and 1×1019 cm−3 were obtained. In addition, abrupt carbon-doping profiles were achieved with no noticeable memory effects. Carrier concentration was studied as a function of CCl4 flow, V/III ratio, growth temperature, and growth rate using electrochemical capacitance-voltage profiling. Carbon incorporation was found to depend on CCl4 flow, V/III ratio, and growth temperature. Carbon incorporation had no dependence on the growth rate.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 54 (1989), S. 1262-1264 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Two mechanisms controlling residual carbon acceptor incorporation in GaAs grown by atmospheric pressure metalorganic chemical vapor deposition have been identified: (1) the removal of the first methyl group from trimethylgallium in the gas phase, and (2) the removal of the first hydrogen atom from AsH3 adsorbed on the substrate surface. An analysis of the chemical reactions involved shows that the likely source of the residual carbon acceptor is the surface adsorbed trimethylgallium molecule rather than other carbon species in the reactor.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Minority-carrier electron-diffusion coefficients and lifetimes have been measured in heavily doped p-type GaAs using the zero-field time-of-flight (ZFTOF) technique. The materials studied included C-doped GaAs grown by molecular-beam epitaxy (MBE) using graphite as the dopant source, C-doped GaAs grown by metalorganic chemical-vapor deposition (MOCVD) using CCl4 as the dopant source, and Be-doped GaAs grown by MBE. Room-temperature photoluminescence intensity measurements were made on the structures and the results are compared with ZFTOF measurements of lifetime. The graphite-doped material (p∼1019 cm−3) exhibited diffusion lengths of less than 1000 A(ring). MOCVD-grown C-doped GaAs, which was optimized by adjusting the growth conditions to maximize the room-temperature photoluminescence intensity, had diffusion lengths comparable to those measured in Be-doped GaAs for hole concentrations of 1×1019 and 5×1019 cm−3. Comparison of photoluminescence intensities also suggests that addition of In to very heavily doped MOCVD-grown GaAs (p(approximately-greater-than)1020 cm−3) to eliminate the lattice mismatch with respect to the substrate does not result in an improvement in lifetime.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Carbon-doped GaAs with carbon concentrations ranging from 2×1017 cm−3 to 2.6×1020 cm−3 has been characterized by variable temperature Hall effect measurements, secondary ion mass spectrometry (SIMS), and double-crystal x-ray diffraction (DCXD). The samples studied were grown by metalorganic chemical vapor deposition (MOCVD) and by metalorganic molecular beam epitaxy (MOMBE). The hole mobility is dominated by degenerate conduction for hole concentrations ≥1×1019 cm−3, and the 77 K resistivity is typically 30%–35% lower than at 300 K in these samples. The mobilities of C-doped p+-GaAs are found to be significantly higher than for Zn- or Be-doped p+-GaAs for doping concentrations in excess of 2×1018 cm−3. The maximum achievable hole mobilities for C-doped material grown by the two techniques are nearly identical, indicating that neither MOCVD nor MOMBE has an inherent advantage over the other for producing low-resistivity p-type GaAs. SIMS analysis and Hall effect measurements reveal that the total carbon concentration, [C], is higher than the as-grown hole concentration, p, in the most heavily doped samples. DCXD measurements show general agreement with the lattice mismatch predicted by Vegard's law. However, for [C](approximately-greater-than)1020 cm−3 a discrepancy between the predicted and measured mismatch suggests that partial lattice relaxation or the presence of interstitial carbon may need to be considered in order to adequately describe the lattice contraction.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 55 (1989), S. 1205-1207 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report a new effect in which hydrogen-passivated acceptor impurities in p-type GaAs are reactivated by low-intensity, above band gap illumination. Low-temperature photolumines cence was used to monitor the acceptor reactivation process. The light-induced reactivation is persistent at cryogenic temperatures, but the material relaxes back to the hydrogen-passivated state after annealing at moderate temperatures. Preliminary kinetic considerations, as well as the implications of this phenomenon on the fundamental and technological aspects of hydrogen passivation in semiconductors, are briefly discussed.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 72 (1998), S. 3479-3481 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A high concentration of hydrogen in the alloy ambient slows the formation of PdGe contacts and increases the resistance of the PdGe to GaAs etchants. The effects of alloy ambient on alloy formation, specific contact resistance, and chemical reactivity of PdGe contacts on n-type GaAs have been studied. A very low specific contact resistance of 〈1×10−7 Ω cm2 has been achieved on GaAs with PdGe contacts alloyed at 300 °C for 15 min in a hydrogen ambient. These results indicate that PdGe may be a desirable contact for GaAs-based transistors. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 52 (1988), S. 691-693 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: High-power coupled-stripe (ten-stripe) AlxGa1−xAs-GaAs quantum well lasers that are fabricated by hydrogenation are described. Continuous (cw) room-temperature thresholds as low as Ith=90 mA and internal quantum efficiency as high as 85% are demonstrated. Continuous 300 K laser operation generating 2×375 mW (0.75 W) at 910 mA (10Ith) or 57% efficiency is described (8-μm-wide stripes on 12 μm centers). Minimal heating effects are observed up to the point of catastrophic failure.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 52 (1988), S. 296-298 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The impact ionization coefficients in AlxGa1−xAs have been experimentally determined for compositions x≤0.4. These data are necessary for accurate device design and modeling. Both α, the electron ionization coefficient, and β, the hole ionization coefficient, decrease with increasing x, and there is no appreciable change in the ratio α/β over the range of compositions and electric fields studied.
    Type of Medium: Electronic Resource
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