ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary Various divinyl-Schiff's base ligands 3 were synthesized from 2-hydroxy-5-vinylbenzaldehyde (2) and diamines. Copolymerization of 3 with styrene directly leads to covalently polymer bound ligands 4. Introduction of Co(II) resulted in the formation of the chelates 6. Covalently polymer bound chelates show high activity for the reversible binding of dioxygen under formation of mononuclear superoxo complexes. The chelates exhibit good activities for the oxidation of 2,6-di-tert-butylphenol (9).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00258022
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