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  • 2000-2004  (3)
  • 2001  (3)
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  • 2000-2004  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 114 (2001), S. 2698-2706 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: To explore how a structured excess charge distribution affects the hydration of an anion, we report mid-IR, argon predissociation spectra for the hydrated superoxide cluster anions, O2−⋅(H2O)n, 1≤n≤5. This size range was chosen to establish the evolution of the structures through the putative shell closing [Weber et al., Science 287, 2461 (2000)] for superoxide hydration at the tetrahydrate. Whereas the observed bonding motifs for n≤4 are those of single water molecules and dimeric subclusters bound to the ion, the pentahydrate spectrum displays strong bands in the region typically associated with ring modes of the water trimer. The present results reinforce the conclusion that the tetrahydrate adopts an especially robust structure in which each water molecule forms a single ionic H bond to one of the lobes of the π* highest occupied molecular orbital in superoxide. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 115 (2001), S. 10718-10723 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Photodetachment spectra of CH3NO2−⋅Arn clusters in the mid-IR are dominated by three strong resonances. These are assigned to autodetaching (AD) C–H stretching vibrational transitions in the valence (as opposed to dipole-bound) form of the molecular anion on the basis of a H/D isotopic substitution study and their solvation dependence. The AD resonances disappear promptly upon addition of the third argon atom, while the resonant structure appears in the action spectrum for formation of CH3NO2− photoproducts for n≥2. The strong argon solvation dependence of the photoproducts is traced to the rapidly changing endoergicity of the electron loss channel due to the differential solvation behavior of the valence anion relative to the neutral. We discuss a statistical limit for this competition, and introduce an intramolecular vibrational energy redistribution mediated AD mechanism unique to polyatomic anions. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 72 (2001), S. 4098-4105 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: The results of experimental and theoretical studies, aiming at a quantitative characterization of photoion-induced energy broadening effects in a laser photoelectron source, are reported. The electron source is based on two-step cw laser photoionization of potassium atoms in a collimated beam. In the experimental studies, the attachment spectra for the formation of (N2O)9O− cluster ions through a narrow vibrational Feshbach resonance (full width at half maximum 2.3 meV) were measured as a function of the photocurrent. The theoretical studies involved Monte Carlo simulations of the broadening effects and were based on potential distributions caused by realistic spatial distributions of the photoions. Using the corresponding electric field distribution, trajectories were calculated for a representative ensemble of electrons, and effective electron energy distributions were obtained from averages over the electron trajectories in the volume relevant for electron attachment. Furthermore, the effects of additional weak electric fields, applied along the atomic beam direction, have been simulated. For our geometry (ionization volume about 2 mm3) the effective space charge related energy width is found to be about 16 μeV/pA. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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