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  • 61.70Tm  (1)
  • adsorbate-adsorbate interactions  (1)
  • 1
    ISSN: 1572-9028
    Schlagwort(e): scanning tunneling spectroscopy (STM) ; surface reactions ; surface restructuring ; dynamics ; adsorbate-adsorbate interactions
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Recently, we have studied the interaction of reactive adsorbates H, C, O, and S with Ni and Cu surfaces by scanning tunneling microscopy (STM). In this paper, we briefly illustrate and discuss how such studies provide significant insight into the understanding of dynamic surface processes such as adsorbate-induced restructuring, surface reactions, and adsorbate-adsorbate interactions. The STM results demonstrate that there is a strong coupling between the chemisorption/reaction process and the distortion of the metal surface.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Applied physics 29 (1982), S. 141-145 
    ISSN: 1432-0630
    Schlagwort(e): 61.80Jh ; 61.70Tm ; 64.75+g
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau , Physik
    Notizen: Abstract Ion-beam mixing by 500-keV xenon ions has been studied in targets consisting of 2000-Å films of aluminium on a polycrystalline aluminium substrate, onto which has been evaporated a 500-Å overlayer of copper. Both long- and short-range-mixing processes have been identified, by RBS analysis of the irradiated targets, as a deep copper tail in the aluminium and interfacial broadening, respectively. The long-range component varies linearly with xenon fluence, is temperature-independent in the interval 40–500 K, and is not influenced by the presence of an interfacial oxide layer between the copper and aluminium layers. The number of long-range-mixed atoms is in agreement with theoretical estimates of the recoil mixing. The short-range mixing, which is the dominating process, has a squareroot dependence on xenon fluence and is independent of temperature between 40 and 300 K, increasing rapidly at higher temperatures. The broadening attributed to the short-range mixing is explained by interstitial diffusion within the cascade. For small xenon fluences, interfacial oxide layers inhibited both short-range mixing and thermal diffusion. Higher xenon fiuences subdued the inhibition.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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