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  • Analytical Chemistry and Spectroscopy  (2)
  • Cutaneous vasodilation  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    European journal of applied physiology 76 (1997), S. 116-121 
    ISSN: 1439-6327
    Keywords: Key words Warm-water immersion ; Esophageal temperature ; Cutaneous vasodilation ; Thermoregulation ; Heat loss
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract We demonstrated previously that esophageal temperature (T es) remains elevated by ≈0.5°C for at least 65 min after intense exercise. Following exercise, average skin temperature (T avg) and skin blood flow returned rapidly to pre-exercise values even though T es remained elevated, indicating that the T es threshold for vasodilation is elevated during this period. The present study evaluates the hypothesis that the threshold for sweating is also increased following intense exercise. Four males and three females were immersed in water (water temperature, T w = 42°C) until onset of sweating (Immersion 1), followed by recovery in air (air temperature, T a = 24°C). At a T a of 24°C, 15 min of cycle ergometry (70% VO2max) (Exercise) was then followed by 30 min of recovery. Subjects were then immersed again (T w = 42°C) until onset of sweating (Immersion 2). Baseline T es and T skavg were 37.0 (0.1)°C and 32.3 (0.3)°C, respectively. Because the T skavg at the onset of sweating was different during Exercise [30.9 (0.3)°C] than during Immersion 1 and Immersion 2 [36.8 (0.2)°C and 36.4 (0.2)°C, respectively] a corrected core temperature, T es (calculated), was calculated at a single designated skin temperature, T sk(designated), as follows: T es(calculated) = T es + [β/(1−β)][T skavg−T sk(designated)]. The T sk(designated) was set at 36.5°C (mean of Immersion 1 and Immersion 2 conditions) and β represents the fractional contribution of T skavg to the sweating response (β for sweating = 0.1). While T es(calculated) at the onset of sweating was significantly lower during exercise [36.7 (0.2)°C] than during Immersion 1 [37.1 (0.1)°C], the threshold of sweating during Immersion 2 [37.3 (0.1)°C] was greater than during both Exercise and Immersion 1 (P 〈 0.05). We conclude that intense exercise decreases the sweating threshold during exercise itself, but elicits a subsequent short-term increase in the resting sweating threshold.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 26 (1988), S. 675-678 
    ISSN: 0749-1581
    Keywords: Tribromobenzene ; 13C spin-lattice relaxation times ; correlation times ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The 13C spin-lattice relaxation times and nuclear Overhauser enhancements of protonated carbons in 1, 3, 5-tribromobenzene were measured in a number of solvents of widely varying viscosity, Derived reorientational correlation times were found to increase approximately linearly with solution viscosity, as predicted by hydrodynamic theories of rotational diffusion.Rotational correlation times calculated from the perrin stick model were two to three times longer than the measured τc values. Similarly, correlation times predicted by the Hu-Zwanzig slip model were too small by a factor of two. On the other hand, application of the newer Hynes-Kapral-Weinberg theory furnished reorientational correlation times that were in virtually quantitative agreement with the experimental results.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    Journal of Raman Spectroscopy 20 (1989), S. 27-30 
    ISSN: 0377-0486
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The Raman spectral bandwidths of two A1′ vibrations of 1,3,5-trifluorobenzene (TFB) were measured in the neat liquid as a function of temperature and in the solvents CH2Cl2 and CS2. The Raman and IR linewidths of two E′ modes were also measured in solution. Derived values of the two rotational diffusion constants, D⊥ and D∥, were compared with the predictions of several current theories. It was observed that the Hynes-Kapral-Weinberg (HKW) theory is superior to both the microviscosity-free rotor and Hu-Zwanzig ‘slip’ models of reorientational diffusion. Calculated values of D⊥ and D∥ for TFB in solution using the HKW model are in excellent agreement with the experimentally measured diffusion constants.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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