ISSN:
0170-2041
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation of New Vicinal Tricarbonyl Compounds and Some of Their Sulfur AnaloguesMesoxalamides 5, benzoylglyoxylamides 19, and pivaloylglyoxylamides 26 are prepared from the corresponding malonamides 4, benzoylacetamides 17 and pivaloylacetamides 24, respectively, by suitable oxidation reactions. Some of the sulfur analogues of 5, 19, and 26, including the first stable 2-thiomesoxalic acid derivative 11b, are also obtained. The spectroscopic properties of the compounds are discussed.
Notes:
Durch geeignete Oxidationsreaktionen gelingt die Überführung der Malonamide 4 in Mesoxalamide 5, der Benzoylacetamide 17 in Benzoylglyoxylamide 19 und der Pivaloylacetamide 24 in Pivaloylglyoxylamide 26. Auch Schwefelanaloga von 5, 19 und 26, darunter das erste stabile 2-Thiomesoxalsäurederivat 11b sind zugänglich. Die spektroskopischen Eigenschaften der dargestellten Verbindungen werden diskutiert.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.198319831006
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