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  • Artikel: DFG Deutsche Nationallizenzen  (4)
  • 1990-1994  (4)
  • 1960-1964
  • rodlikemicelle  (2)
  • Biological monitoring  (1)
  • Inorganic ions  (1)
Datenquelle
  • Artikel: DFG Deutsche Nationallizenzen  (4)
Materialart
Erscheinungszeitraum
  • 1990-1994  (4)
  • 1960-1964
Jahr
Schlagwörter
  • 1
    Digitale Medien
    Digitale Medien
    Biological monitoring of acrylonitrile exposure through a new analytical approach to hemoglobin and plasma protein adducts and urinary metabolites in rats and humans (1993)
    Springer
    International archives of occupational and environmental health 65 (1993), S. S103 
    Details
    ISSN: 1432-1246
    Schlagwort(e): Acrylonitrile ; Adducts ; Biological monitoring ; Gas chromatography ; Hemoglobin
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary A new, simple and fast procedure of measuring acrylonitrile (ACN) in ACN derived mercapturic acids such as S-(2-cyanoethyl)-L-cysteine(CyEC), and in hemoglobin (Hb) and plasma protein adducts and urinary metabolites in rats and humans exposed to ACN was developed. ACN in mercapturic acids or proteins was analyzed by capillary gas chromatography (GC) by liberating ACN at a high-temperature in the injector port of GC with or without oxidizing sulfur atoms of the ACN-bound cysteines into sulfoxide form by hydrogen peroxide in vitro. At 350 °C, more than 90% of ACN in authentic CyEC was recovered by this method. Increasing a single ip dose of ACN from 5 to 50 mg/kg produced proportional increases in ACN bound to Hb 24 hr after the treatment. The alkylation of plasma protein with ACN was about 1/10 as low as that of Hb. After repeated daily ip doses of 1–10 mg/kg, ACN in Hb decreased with a half-life of about 9 days. ACN was also detected in the blood of workers exposed to ACN for 1 to 10 years at a Siberian synthetic rubber factory.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00381317
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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    Artikel (Nationallizenzen)
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  • 2
    Digitale Medien
    Digitale Medien
    The viscoelasticity of spinnable solutions of alkyltrimethylammonium salicylates (1992)
    Springer
    Colloid & polymer science 270 (1992), S. 249-258 
    Details
    ISSN: 1435-1536
    Schlagwort(e): Viscoelasticity ; spinnability ; tetradecyltrimethylammoniumsalicylate ; hexadecyltrimethylammoniumsalicylate ; rodlikemicelle
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The viscoelasticity has been measured for aqueous solutions of tetradecyl-and hexadecyltrimethylammonium salicylates (C14TASal, C16TASal). The aqueous solutions of C14TASal without salt displayed the gel-like behavior at 10.0×10−2 g cm−3, but those more dilute than 3.2×10−2 g cm−3 presented the viscoelasticity similar to that of a Maxwell liquid. The Maxwell-like behavior was converted to the polymer-like one on the addition of (0.1–0.2) M NaBr or (0.02–0.2) M NaSal. The gel-like viscoelasticity can be connected with the spinnability of “cohesive fracture failure”, and the Maxwell-like and polymer-like viscoelasticities are concerned with the spinnability of “ductile failure”. The gel-like and Maxwell-like viscoelasticities originate in the pseudo-network formed by the pseudo-linkages between rodlike micelles, while the polymer-like viscoelasticity is caused by the entanglement of long rodlike micelles in semidilute and concentrated solutions. The aqueous solutions of C16TASal behaved very similar to those of C14TASal.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00655477
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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    Artikel (Nationallizenzen)
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  • 3
    Digitale Medien
    Digitale Medien
    The spinnability of viscoelastic solutions of tetradecyl- and hexadecyl-trimethylammonium salicylates (1990)
    Springer
    Colloid & polymer science 268 (1990), S. 460-468 
    Details
    ISSN: 1435-1536
    Schlagwort(e): Spinnability ; viscoelasticsurfactantsolution ; tetradecyltrimethylammoniumsalicylate ; hexadecyltrimethylammonium salicylate ; rodlikemicelle
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The spinnability was measured for aqueous viscoelastic solutions of tetradecyl- and hexadecyltrimethylammonium salicylates (C14TASal, C16TASal) in the absence and presence of sodium salicylate (NaSal) and sodium bromide (NaBr). The spinnability is classified into two types, D and C. While the intrinsic drawing length in type D is proportional to the drawing velocity, the drawing intrinsic length in type C decreases with the drawing velocity or is independent of it. The spinnability changes from type D to C, as the drawing velocity and the surfactant concentration increase, and the temperature lowers. The effect of salt is different between NaSal and NaBr. It can be assumed that a pseudo-network structure composed of rod-like micelles is formed in viscoelastic and spinnable surfactant solutions. Then, the spinnability depends on the balance between the elasticity and the viscosity in which the structure results.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF01411005
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Chromatography of inorganic ions on diethyl-(2-hydroxy-propyl)aminoethyl cellulose layers in hydrochloric acid and in HCl-ammonium chloride media (1991)
    Springer
    Chromatographia 31 (1991), S. 60-62 
    Details
    ISSN: 1612-1112
    Schlagwort(e): Thin-layer chromatography ; Diethyl-(2-hydroxy-propyl)aminoethyl (QAE)-cellulose ; Hydrochloric acid and chloride media ; Inorganic ions ; Re(VII)
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Summary Thin-layer chromatographic behavior of 49 inorganic ions has been systematically studied on diethyl-(2-hydroxy-propyl)aminoethyl (QAE)-cellulose, a strongly basic anion exchanger, in aqueous hydrochloric acid and in acid-ammonium chloride media (0.01 to 1.0 mol dm−3). Aspects of the adsorption behavior of the ions on the cellulose are compared with those on other anion exchangers in the same eluent system. Feasibilities of separation of multicomponent mixtures are proposed on QAE-cellulose in both media. In particular, the selective separation of Re(VII) from many other ions can be accomplished on these systems.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF02290497
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    Artikel (Nationallizenzen)
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