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  • 1
    Digitale Medien
    Digitale Medien
    Growth and metabolic changes in weanling rats with lesions in the dorsomedial hypothalamic nuclei (1972)
    Springer
    Experimental brain research 15 (1972), S. 424-429 
    Details
    ISSN: 1432-1106
    Schlagwort(e): Hypothalamus ; Metabolism ; Growth ; Dorsomedial Nucleus body composition
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary When compared with sham-operated ad libitum-fed controls, weanling rats with lesions primarily destroying the dorsomedial hypothalamic nuclei (DMNL rats) showed reduced ponderal and linear growth and food intake, normal carcass fat but increased carcass protein. Among the metabolic parameters measured, DMNL rats showed only decreased incorporation of palmitate into epididymal fat pad phospholipid and triglyceride. When sham-operated controls were pair-fed with DMNL rats, they showed growth changes almost identical with those observed in lesioned rats. However, their carcass protein was lower than both that of the lesioned rats and the ad libitum-fed controls. Metabolically, the sham-operated, pair-fed controls showed decreased incorporation of palmitate into triglyceride of epididymal fat pads and decreased oxidation of glucose and increased incorporation into total lipid of the diaphragm. When previous data on growth hormone, insulin, triglyceride and cholesterol are compared with the present findings it is suggested that dorsomedial lesions cause a subcaloric-type dwarfism that does not involve adenohypophyseal secretions and their target organs affecting growth.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00234127
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  • 2
    Digitale Medien
    Digitale Medien
    Normal plasma growth hormone levels in growth-retarded weanling rats with dorsomedial hypothalamic lesions (1973)
    Springer
    Experimental brain research 18 (1973), S. 374-382 
    Details
    ISSN: 1432-1106
    Schlagwort(e): Growth retardation ; Hypothalamus ; Dorsomedial lesions ; Rat
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin
    Notizen: Summary Weanling rats received bilateral electrolytic lesions destroying the areas of the ventromedial (VMN) and dorsomedial (DMN) hypothalamic nuclei, respectively. Trunk blood was collected at sacrifice (Experiment 1 and 2∶ 31 days, Experiment 3∶ 14 days) for the determination of plasma growth hormone (GH) by radioimmunoassay. Rats with DMN lesions showed consistently normal to slightly elevated plasma GH levels while animals with VMN lesions showed significantly reduced plasma GH levels. Linear growth was reduced by both types of hypothalamic lesions but body weight gains and food intake were reduced only in the DMN lesioned rats. Carcass fat was greatly elevated in VMN lesioned rats, moderately elevated in one experiment in the DMN animals and normal in another experiment. These data confirm a previous hypothesis that growth retardation in DMN rats is not due to low circulating GH level but rather represents a hypocaloric-type dwarfism.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1007/BF00239106
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  • 3
    Digitale Medien
    Digitale Medien
    Fracture toughness and crack instability in tough polymers under plane strain conditions (1987)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 1128-1136 
    Details
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The plane strain fracture toughness and fracture mechanisms of several tough engineering plastics have been studied and compared with poly(methyl methacrylate) (PMMA), a relatively brittle polymer. The tough polymers all are observed to form a multiple craze zone at the crack tip, which is shown to be the primary source of plane strain fracture toughness in these materials. The multiple craze zone is retained during slow crack growth but is metastable, and at a critical stress intensity and associated crack velocity, the system passes through a transition to a greatly accelerated single craze mode of unstable propagation.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pen.760271504
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  • 4
    Digitale Medien
    Digitale Medien
    Structure-Property-Processing relationships of polyurethane-polyester interpenetrating polymer networks (1989)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 397-404 
    Details
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Interpenetrating polymer networks of polyurethane and unsaturated polyester were prepared by reaction injection molding (RIM) and transfer molding. The structures of the molded samples were analyzed by electron microscopy and dynamic mechanical analysis. It was found that polymer morphology and dynamic mechanical properties depend strongly on the molding temperature, reaction rate and reaction sequence. Simplified structure models based on Takayanagi's model and sample morphology can predict the storage modulus reasonably well but not the tanδ.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pen.760290608
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  • 5
    Digitale Medien
    Digitale Medien
    A free radical copolymerization model for simulating reactive processing of unsaturated polyester resins (1990)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 684-692 
    Details
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A free radical copolymerization model is proposed for simulating the reaction rates and conversions of styrene monomer and unsaturated polyester resins during curing. This model is based on film theory in which the rate constants reflect both reaction and diffusion resistances. Differential scanning calorimetry in combination with Fourier transform infrared spectroscopy is used to measure the overall and individual reactivities of reacting species. Model parameters are determined from experimental data. The applicability of this model is demonstrated in a cure simulation.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pen.760301108
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  • 6
    Digitale Medien
    Digitale Medien
    Comparison of thermal and infrared spectroscopic analyses in the formation of polyurethane, unsaturated polyester, and their blends (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 36 (1988), S. 1325-1342 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Differential scanning calorimetry (DSC) and infrared spectroscopy (IR) are two widely used techniques for the measurement of polymerization kinetics. Reactions of several thermoset polymers: a polyurethane, two unsaturated polyester resins, and polyurethane-polyester blends, were measured by these two methods. Results indicate that the thermal method is easy to use, and can generate both kinetic and thermal information. It is, however, less accurate and cannot detect detailed reaction mechanisms because the measurement relies upon the overall heat generation during reaction. Fourier transform infrared (FTIR) spectroscopy, on the other hand, can provide detailed kinetic information for multicomponent reactions such as styreneunsaturated polyester and polyurethane-polyester blends. Data analysis, however, is more tedious and requires reliable calibration. For an accurate kinetic measurement, both methods should be used because the results from both experiments can calibrate each other.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1988.070360607
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  • 7
    Digitale Medien
    Digitale Medien
    Mixing characteristics of urethane based materials and polyurea in RIM (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 37 (1989), S. 251-266 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: To facilitate the study of new reaction injection molding (RIM) materials on a practical scale, a lab-scale mini-RIM machine was constructed. This machine is capable of delivering up to approximately 250 cc of material at rates of up to 125 cc/s. The RIM machine was first tested with conventional materials such as crosslinked and linear polyurethanes. The effect of varying the nozzle Reynolds number upon the adiabatic temperature rise corresponded to the results reported in previous works. Following this verification, two developmental materials, a polyurethane/polyester interpenetrating polymer network and a polyurea, were examined. The polyurea material showed a very strong dependency on mixing up to a Reynolds number above 400. The 75/25 PU/PEster reaction exotherms also showed a dependency upon mixing. However, this dependency is noticeable only in the polyester portion of the reaction, which can be attributed to the mixing sensitivity of the redox-type initiators used.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1989.070370120
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  • 8
    Digitale Medien
    Digitale Medien
    Processing of polyurethane-polyester interpenetrating polymer network (IPN) (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 36 (1988), S. 1157-1176 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The kinetics and heat transfer during the curing of a polyurethane-polyester interpenetrating polymer network (IPN) were investigated experimentally and theoretically. A model based on the additivity rule of constituent ingredients was used to predict the IPNs reaction kinetics and heat transfer. Compared with the adiabatic temperature rise measured during reaction injection molding and the temperature profiles measured during a casting process, the model prediction is close to the experimental data. Deviations of model prediction from experimental results were found in the comparison of reaction rate profiles measured by differential scanning calorimetry. This suggests that reaction interactions may exist in the polymerization system.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1988.070360517
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  • 9
    Digitale Medien
    Digitale Medien
    Microgel formation in the free radical crosslinking polymerization of ethylene glycol dimethacrylate (EGDMA). I. Experimental (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 257-267 
    Details
    ISSN: 0887-624X
    Schlagwort(e): ethylene glycol dimethacrylate resin ; microgel ; bimodal polymers ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: An important feature of free radical crosslinking polymerization of ethylene glycol dimethacrylate (EGDMA) resin is the formation of heterogeneous structure through intramolecular reaction. Such structure formation affects not only the cure behavior and rheological changes of the resin but also the physical properties of the formed polymers. In this study, the reaction kinetics, morphological changes, and characteristics of formed polymers were examined by a differential scanning calorimeter, a Rheometrics Dynamic Analyzer, a dynamic light scattering goniometer, and a Fourier transfer infrared spectrometer. Experimental data showed the formation of bimodal polymers before gelation. These polymers are partially crosslinked and can be considered as microgel particles. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pola.1995.080330208
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  • 10
    Digitale Medien
    Digitale Medien
    Microgel formation in the free radical crosslinking polymerization of ethylene glycol dimethacrylate (EGDMA). II. Simulation (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 269-283 
    Details
    ISSN: 0887-624X
    Schlagwort(e): ethylene glycol dimethacrylate resin ; translational diffusion ; segmental diffusion ; microgel ; percolation model ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The simulation of free radical crosslinking polymerizations of multifunctional monomer by a percolation model was performed on a two-dimensional lattice with periodical boundaries. The model was formulated in such a way that a variety of monomers, translational diffusion of monomer and polymer molecules, segmental diffusion of polymer, shielding effects, microgel formation, and unequal reactivities of vinylene bonds can be considered. Simulation results of the 2-D model agreed well with those of a 3-D model. The percolation model was able to qualitatively verify several experimental results. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pola.1995.080330209
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