ISSN:
1572-8838
Keywords:
cell reversal
;
gas evolution
;
monocell batteries
;
overcharging
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Electrical Engineering, Measurement and Control Technology
Notes:
Abstract Beginning with a construction based on a C-size (LR-14) battery container ('can'), encased in a strong PMMA-support and fitted with a removable cell top equipped with a manometer and a gas-outlet valve, a second and, finally, a more refined third generation cell was developed. The final (3rd generation) design provides additional options for experimental work. For example, the system can be flushed with inert gas; a regulating gas-flow valve has been fitted to feed precisely a gas chromatograph with the gaseous reaction products and a reference electrode to measure anode and cathode potentials individually has also been incorporated. Since AA cells (LR-6) are the dominant monocell battery size, test cells of the second generation were fitted with an adapter to accomodate either a C- or an AA-size. However, the most recent system was designed exclusively for AA-sized cans. The different cell designs are described and examples of their practical application (e.g., overcharge experiments) are given.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1003455721233
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