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  • 1
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 4671-4678 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Photon-gated persistent spectral hole burning was observed for metal-free tetraphenylporphine with halogenated anthracene derivatives in poly(methylmethacrylate) or poly(ethylene) at liquid-helium temperatures. The hole formation yield was markedly dependent on the polymer matrices and the sample composition as well as on the gating wavelength. The irreversible broadening of holes in the systems measured by temperature cycling experiment was smaller than that by proton tautomerization of tetraphenylporphine. We concluded that the hole formation mechanism is donor-acceptor electron transfer on the basis of combined analysis of the matix and acceptor concentration dependence of hole formation yield, the action spectrum of the gating photon and the photoproduct spectrum.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 5927-5929 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A study was carried out to improve permeability and coercivity of pure iron without decreasing its saturation magnetization. It was found that about 1-wt % addition of aluminum in combination with a high-temperature annealing process greatly increases its permeability (μm) up to 60 000, which is close to that of Permalloy B, and reduces its coercivity (Hc) to 0.2 Oe without decreasing the high-saturation magnetization of pure iron. This marvelous effect of the 1-wt %-Al addition can be attributed to a stabilization of the ferrite phase which enables ferrite grains to coarsen drastically due to abnormal grain growth during the high-temperature annealing. The ferrite stabilization also helps to avoid both residual strain and grain refining due to the austenite-ferrite phase transformation, which are thought to be undesirable for soft magnetic properties. In the present paper, the performance of this Fe–1-wt %-Al soft magnetic alloy, and an example of its practical application to the magnetic shielding, will be described.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 749-751 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: The dependence of the amount of aluminum trifluoride (AlF3) piled up at the interface of chemical vapor deposited tungsten and the aluminum under layer on the deposition time and subsequent annealing in ultrahigh vacuum (UHV) or in monosilane (SiH4) gas has been studied. AlF3 is formed by the reaction of the aluminum under layer with tungsten hexafluoride (WF6) during the initial state of tungsten chemical vapor deposition. Tungsten was deposited on an Al layer under selective deposition conditions by SiH4 reduction at 250 °C. X-ray photoelectron spectroscopy measurement reveals that the amount of AlF3 decreases with an increase in the tungsten deposition time and that the reduction of AlF3 by volatilization of aluminum fluorides, which occurs at higher temperatures ((approximately-greater-than)400 °C) is not observed at low temperature (270 °C). Annealing in SiH4 gas after the tungsten deposition was effective to reduce the amount of AlF3 compared with annealing in UHV. This result and thermochemical data would suggest that the dependence of the amount of AlF3 on the tungsten deposition time is explained by the reduction of AlF3 with hydrogen atoms supplied from the dissociation of SiH4.
    Materialart: Digitale Medien
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  • 4
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: A Cr-Ti underlayer is found to enhance the in-plane coercive forces of Co-Cr-Pt and Co-Cr-Ta films; the maximum coercive force was 3.5 kOe for (CoCr0.15)0.84Pt0.16/CrTi0.2. The crystallites of Cr-Ti grow in a more highly oriented and uniform manner than ones of Cr, and their lattice spacings are closer to those of Co alloys than Cr, improving the epitaxial growth of Co-alloy crystallites with c-axis in-plane oriented components on the Cr-Ti underlayer. The crystalline anisotropy constant of Co-Cr-Pt with a high Pt concentration is found by torque measurement to be larger than that of Co-Cr-Ta. These can produce extremely high coercive forces in Co-Cr-Pt/Cr-Ti. The C/Co-Cr-Pt/Cr-Ti thin film media with high coercive forces show excellent read/write characteristics; the linear densities at 50% signal drop are very high, 175 and 101 kFCI, for the C/Co-Cr-Pt/Cr-Ti media at head-to-magnetic layer spacings of 0.01 and 0.07 μm.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 374-379 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Two-color photon-gated persistent spectral hole burning (PSHB) via donor-acceptor electron transfer is reported in systems where the acceptor, 10-chloroanthracene, was intentionally branched to a side chain of the poly(methylmethacrylate) (PMMA) host polymer while the donor, metal-free tetraphenylporphine, was dispersed in the polymer. The systems, which had an acceptor concentration of up to 10−1 M, were prepared without aggregation of the acceptor. Spectral holes were burnt in the Qx(0,0) absorption band of the donor when the systems were simultaneously irradiated with a frequency-selective excitation (duration: 500 ps; energy: 200 nJ/cm2) and a gating excitation (wavelength: 514.5 nm; duration: 33 ms; energy: 14 μJ/cm2). The difference absorption spectrum between the unburned absorption spectrum and one recorded after photon-gated PSHB has confirmed that the hole formation mechanism is donor-acceptor electron transfer from a photoexcited donor to a ground-state branched acceptor. The thermal stability of burnt holes measured with a temperature cycling experiment increased when the acceptor was branched into PMMA. The effect of acceptor branching on the PSHB characteristics is discussed with reference to those for an acceptor-doped system.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 68 (1990), S. 5610-5614 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Effect of ball-forming conditions on the microstructure and the hardness of balls has been investigated in order to obtain soft balls suitable for a reliable ball-bonding process using copper wire. Copper balls formed in a room-temperature shield gas are found to be harder by 6 Hv than fully annealed copper wires of the same purity. This is caused by many dislocation loops which are generated in balls due to inclusion of gaseous impurities from the atmosphere and due to rapid solidification. On the other hand, copper balls formed in a shield gas heated above 175 °C are found to be softer by the amount of 4.5 Hv than balls formed in a room-temperature shield gas. This is due to disappearance of dislocation loops caused by the reduction of solidification rate and by elimination of gaseous impurities from the balls during solidification. Impurities, especially oxygen, are found to have a strong influence on the hardening of copper balls. From these results, we conclude that copper balls formed in a shield gas heated at 175 °C are suitable for mass production.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 58 (1991), S. 2583-2585 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Several organic materials with a bulky donor group have been developed for second-order nonlinear optics. Among these materials, 2-adamantylamino-5-nitropyridine (AANP) crystal has the largest second-order nonlinear optical coefficient. By second-harmonics measurement at 1.064 μm, coefficients of d31 and d33 were determined to be 80 and 60 pm/V, respectively. Angle-tuned phase-matched second-harmonic generation with a conversion efficiency=2×10−3 W−1 has been demonstrated using a 1 mm AANP bulk crystal at 1.064 μm.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 62 (1993), S. 411-413 
    ISSN: 1077-3118
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: We report the fabrication and characterization of thin-film grain boundary junctions in Tl-based superconductors on bicrystal substrates. Post-deposition processed Tl2Ba2CaCu2O8 films were grown on bicrystal SrTiO3 substrates, with varying degrees of misorientation angle θ. Critical current densities and current-voltage curves had a strong dependence on θ. For θ≥10°, there was a two-to-three order of magnitude reduction in critical current density, and for θ≥20°, the current-voltage curves displayed resistively shunted junction behavior. These high angle grain boundary junctions have features at 77 K that are attractive for device applications, including sharp voltage onsets, well-behaved dc magnetic and rf field dependence, IcRn products as large as 300 μV, and low 1/f noise. Simple dc superconducting quantum interference devices fabricated with these junctions exhibited transfer functions of up to 30 μV/Φ0 at 77 K.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Oxford, UK : Blackwell Publishing Ltd
    Annals of the New York Academy of Sciences 632 (1991), S. 0 
    ISSN: 1749-6632
    Quelle: Blackwell Publishing Journal Backfiles 1879-2005
    Thema: Allgemeine Naturwissenschaft
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 5149-5153 
    ISSN: 1089-7550
    Quelle: AIP Digital Archive
    Thema: Physik
    Notizen: Electrical treeing is often responsible for the breakdown of insulating materials used in power apparatus such as high-voltage transformers, cables, and capacitors. Insulation, such as crosslinked polyethylene (XLPE), used in underground high-voltage cables usually operates at temperatures above ambient. This paper describes the characteristics of luminescence, emitted prior to electrical tree inception, at a crosslinked polyethylene-semiconducting material (XLPE-semicon) interface held above room temperature. Use of a sensitive light detection system showed that XLPE subjected to elevated temperatures emits luminescence even without voltage application. This light was attributed to thermoluminescence which decreased with the decrease in the concentration of the crosslinking by-products present in the polymer. The spectra of thermoluminescence were only in the visible range. On the other hand, electroluminescence occurred when the XLPE-semicon interface was held above room temperature and subjected to high electric stress. This light did not depend on the concentration of the crosslinking by-products and the spectra of electroluminescence were in the visible and the ultraviolet ranges. It is proposed that XLPE-semicon interface held at elevated temperature and subjected to long-term voltage application initially emits both thermoluminescence and electroluminescence. As the crosslinking by-products exude out of the polymer, thermoluminescence decreases with time and ultimately ceases, but electroluminescence occurs as long as the voltage is applied to the polymer. Although the intensity of electroluminescence emitted at high temperature was lower than that emitted at ambient, sufficient ultraviolet radiation was emitted. The ultraviolet radiation could photodegrade the polymer and lead to electrical tree inception.
    Materialart: Digitale Medien
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