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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 45 (1973), S. 372-373 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 45 (1973), S. 1971-1973 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Global change biology 11 (2005), S. 0 
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: The dynamics and demography of roots were followed for 5 years that spanned wet and drought periods in native, semiarid shortgrass steppe grassland exposed to ambient and elevated atmospheric CO2 treatments. Elevated compared with ambient CO2 concentrations resulted in greater root-length growth (+52%), root-length losses (+37%), and total pool sizes (+41%). The greater standing pool of roots under elevated compared with ambient CO2 was because of the greater number of roots (+35%), not because individuals were longer. Loss rates increased relatively less than growth rates because life spans were longer (+41%). The diameter of roots was larger under elevated compared with ambient CO2 only in the upper soil profile. Elevated CO2 affected root architecture through increased branching.Growth-to-loss ratio regressions to time of equilibrium indicate very long turnover times of 5.8, 7.0, and 5.3 years for control, ambient, and elevated CO2, respectively. Production was greater under elevated compared with ambient CO2 both below- and aboveground, and the above- to belowground ratios did not differ between treatments. However, estimates of belowground production differed among methods of calculation using minirhizotron data, as well as between minirhizotron and root-ingrowth methods. Users of minirhizotrons may need to consider equilibration in terms of both new growth and disappearance, rather than just growth.Large temporal pulses of root initiation and termination rates of entire individuals were observed (analogous to birth–death rates), and precipitation explained more of the variance in root initiation than termination. There was a dampening of the pulsing in root initiation and termination under elevated CO2 during both wet and dry periods, which may be because of conservation of soil water reducing the suddenness of wet pulses and duration and severity of dry pulses. However, a very low degree of synchrony was observed between growth and disappearance (production and decomposition).
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 28 (1998), S. 44-50 
    ISSN: 1432-0789
    Keywords: Key words Nitrous oxide ; Methane consumption ; Nitrification ; Oxides of nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  Land use changes in semiarid grasslands have long-lasting effects. Reversion to near-original conditions with respect to plant populations and productivity requires more than 50 years following plowing. The impact of more subtle management changes like small, annual applications of N fertilizer or changing cattle stocking rates, which alters N redistribution caused by grazing and cattle urine deposition, is not known. To investigate the long-term effects of N addition to the Colorado shortgrass steppe we made weekly, year-round measurements of N2O and CH4 from the spring of 1990 through June 1996. Fluxes of NOx (NO plus NO2) were measured from October 1995 through June 1996. These measurements illustrated that large N applications, either in a single dose (45 g N m–2), simulating cattle urine deposition, or in small annual applications over a 15-year period (30 g N m–2) continued to stimulate N2O emissions from both sandy loam and clay loam soils 6–15 years after N application. In sandy loam soils last fertilized 6 years earlier, average NOx emissions were 60% greater than those from a comparable, unfertilized site. The long-term impact of these N additions on CH4 uptake was soil-dependent, with CH4 uptake decreased by N addition only in the coarser textured soils. The short-term impact of small N additions (0.5–2 g N m–2) on N2O, NOx emissions and CH4 uptake was observed in field studies made during the summer of 1996. There was little short-term effect of N addition on CH4 uptake in either sandy loam or clay loam soils. Small N additions did not result in an immediate increase in N2O emissions from the sandy loam soil, but did significantly increase N2O flux from the clay loam soil. The reverse soil type, N addition interaction occurred for NOx emissions where N addition increased NOx emissions in the coarser textured soil 10–20 times those of N2O.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1432-0789
    Keywords: Denitrification ; Flooded soil ; 15N ; Urea ; 15N balance ; Wetland rice ; Oryza sativa L.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary It is commonly assumed that a large fraction of fertilizer N applied to a rice (Oryza sativa L.) field is lost from the soil-water-plant system as a result of denitrification. Direct evidence to support this view, however, is limited. The few direct field, denitrification gas measurements that have been made indicate less N loss than that determined by 15N balance after the growing season. One explanation for this discrepancy is that the N2 produced during denitrification in a flooded soil remains trapped in the soil system and does not evolve to the atmosphere until the soil dries or is otherwise disturbed. It seems likely, however, that N2 produced in the soil uses the rice plants as a conduit to the atmosphere, as does methane. Methane evolution from a rice field has been demonstrated to occur almost exclusively through the rice plants themselves. A field study in Cuttack, India, and a greenhouse study in Fort Collins, Colorado, were conducted to determine the influence of rice plants on the transport of N2 and N2O from the soil to the atmosphere. In these studies, plots were fertilized with 75 or 99 atom % 15N-urea and 15N techniques were used to monitor the daily evolution of N2 and N2O. At weekly intervals the amount of N2+N2O trapped in the flooded soil and the total-N and fertilized-N content of the soil and plants were measured in the greenhouse plots. Direct measurement of N2+N2O emission from field and greenhouse plots indicated that the young rice plant facilitates the efflux of N2 and N2O from the soil to the atmosphere. Little N gas was trapped in the rice-planted soils while large quantities were trapped in the unplanted soils. N losses due to denitrification accounted for only up to 10% of the loss of added N in planted soils in the field or greenhouse. The major losses of fertilizer N from both the field and greenhouse soils appear to have been the result of NH3 volatilization.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 27 (1998), S. 221-229 
    ISSN: 1432-0789
    Keywords: Key words Climate change ; IPCC ; Land-use change ; Greenhouse effect ; Ozone destruction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  Contributors to the Intergovernmental Panel on Climate Change (IPCC) generally agree that increases in the atmospheric concentration of greenhouse trace gases (i.e., CO2, CH4, N2O, O3) since preindustrial times, about the year 1750, have led to changes in the earth's climate. During the past 250 years the atmospheric concentrations of CO2, CH4, and N2O have increased by 30, 145, and 15%, respectively. A doubling of preindustrial CO2 concentrations by the end of the twenty-first century is expected to raise global mean surface temperature by about 2  °C and increase the frequency of severe weather events. These increases are attributed mainly to fossil fuel use, land-use change, and agriculture. Soils and climate changes are related by bidirectional interactions. Soil processes directly affect climatic changes through the production and consumption of CO2, CH4, and N2O and, indirectly, through the production and consumption of NH3, NOx, and CO. Although CO2 is primarily produced through fossil fuel combustion, land-use changes, conversion of forest and grasslands to agriculture, have contributed significantly to atmospheric increase of CO2. Changes in land use and management can also result in the net uptake, sequestration, of atmospheric CO2. CH4 and N2O are produced (30% and 70%, respectively) in the soil, and soil processes will likely regulate future changes in the atmospheric concentration of these gases. The soil-atmosphere exchange of CO2, CH4, and N2O are interrelated, and changes in one cycle can impart changes in the N cycle and resulting soil-atmosphere exchange of N2O. Conversely, N addition increases C sequestration. On the other hand, soil processes are influenced by climatic change through imposed changes in soil temperature, soil water, and nutrient competition. Increasing concentrations of atmospheric CO2 alters plant response to environmental parameters and frequently results in increased efficiency in use of N and water. In annual crops increased CO2 generally leads to increased crop productivity. In natural systems, the long-term impact of increased CO2 on ecosystem sustainability is not known. These changes may also result in altered CO2, CH4, and N2O exchange with the soil. Because of large temporal and spatial variability in the soil-atmosphere exchange of trace gases, the measurement of the absolute amount and prediction of the changes of these fluxes, as they are impacted by global change on regional and global scales, is still difficult. In recent years, however, much progress has been made in decreasing the uncertainty of field scale flux measurements, and efforts are being directed to large scale field and modeling programs. This paper briefly relates soil process and issues akin to the soil-atmosphere exchange of CO2, CH4, and N2O. The impact of climate change, particularly increasing atmospheric CO2 concentrations, on soil processes is also briefly discussed.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1573-0867
    Keywords: 15N ; residual N ; Sesbania ; urea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Field studies were conducted during two consecutive wet seasons in flooded rice (Oryza sativa L.) to determine the effect of green manure on urea utilization in a rice-fallow-rice cropping sequence. Replicated plots were fertilized with 60 to 120 kg of urea N ha−1 in three split applications (50, 25 and 25%) with or without incorporation of dhaincha (Sesbania aculeata L.) (100 kg N ha−1). During the first crop only 31 to 44% of the urea added was used by the rice. Incorporatingin situ grown dhaincha (GM) into the soil at transplanting had little effect on urea utilization. Forty-four to 54% of the N added was not recovered in the soil, rice crop, or as nitrate leachate during the first cropping season. Incorporation of GM had no effect on fertilizer N recovery. Only about 2% of the urea N added to the first rice crop was taken up by the second rice crop and, as in the first crop, the GM had little effect on residual N, either in amount or utilization.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 37 (1994), S. 191-200 
    ISSN: 1573-0867
    Keywords: control options ; denitrification ; nitrification ; N2O
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract This paper addresses three topics related to N2O emissions from agricultural soils. First, an assessment of the current knowledge of N2O emissions from agricultural soils and the role of agricultural systems in the global N2O are discussed. Secondly, a critique on the methodology presented in the OECD/OCDE (1991) program on national inventories of N2O is presented. Finally, technical options for controlling N2O emissions from agricultural fields are discussed. The amount of N2O derived from nitrogen applied to agricultural soils from atmospheric deposition, mineral N fertilizer, animal wastes or biologically fixed N, is not accurately known. It is estimated that the world-wide N2O emitteddirectly from agricultural fields as a result of the deposition of all the above nitrogen sources is 2–3 Tg N annually. This amounts to 20–30% of the total N2O emitted annually from the earth's surface. An unknown, but probably significant, amount of N2O is generated indirectly in on and off farm activities associated with food production and consumption. Management options to limitdirect N2O emissions from N-fertilized soils should emphasize improving N-use efficiency. Such management options include managing irrigation frequency, timing and quantity; applying N only to meet crop demand through multiple applications during the growing season or by using controlled release fertilizers; applying sufficient N only to meet crop needs; or using nitrification inhibitors. Most of these options have not been field tested. Agricultural management practices may not appreciably affect indirect N2O emissions.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1573-0867
    Keywords: Nitrogen loss ; denitrification ; acetylene ; irrigation ; urea ; nitrogen isotopes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The effectiveness of wax coated calcium carbide to provide a slow release of acetylene to inhibit nitrification and denitrification in soil was evaluated in a field experiment with irrigated wheat (cv. Condor) grown on a red brown earth in the Goulburn-Murray Irrigation Region. The effect of the inhibitor treatments on biomass and grain yield was determined in 25 m × 3 m plots, and the effect on recovery, in the plant-soil system, of urea-N applied at sowing was determined in 0.3 m × 0.3 m microplots using a15N balance technique. The inhibitor limited ammonium oxidation, prevented nitrogen loss by denitrification for 75 days, increased N accumulation by the wheat plants, increased grain N and resulted in a 46% greater recovery of applied nitrogen in the plant-soil system at harvest. However, the inhibitor treatment did not increase grain yield because of waterlogging at the end of tillering and during stem elongation.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1573-0867
    Keywords: nitrification ; denitrification ; 15N balance ; nitrogen loss
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Poor N fertilizer use efficiency by flooded rice is caused by gaseous losses of N. Improved fertilizer management and use of nitrification inhibitors may reduce N losses. A microplot study using15N-labelled urea was conducted to investigate the effects of fertilizer application method (urea broadcast, incorporated, deep-placed) and nitrification inhibitor [encapsulated calcium carbide (ECC)] treatments on emission of N2+N20 and total loss of applied N on a grey clay near Griffith, NSW, Australia. Both incorporation and deep placement of urea decreased N2+N2O emission compared to urea broadcast into the floodwater. Addition of ECC significantly (P 〈 0.05) reduced emission of N2+N20 from incorporated or deep-placed urea and resulted in increased exchangeable ammonium concentrations in the soil in both treatments. Fifty percent of the applied N was lost when urea was broadcast into the floodwater. Total N loss from the applied N was significantly (P 〈 0.05) reduced when urea was either incorporated or deep placed. In the presence of ECC the losses were reduced further and the lowest loss (34.2% of the applied N) was noted when urea was deep-placed with ECC.
    Type of Medium: Electronic Resource
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