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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 45 (1973), S. 372-373 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 45 (1973), S. 1971-1973 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0789
    Keywords: Nitrification ; Denitrification ; Nitrification inhibitors ; 15N balance ; Nitrous oxide ; Greenhouse gases
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The effectiveness of wax-coated calcium carbide (as a slow-release source of acetylene) and nitrapyrin in inhibiting nitrification and emission of the greenhouse gases N2O and CH4 was evaluated in a microplot study with dry-seeded flooded rice grown on a grey clay near Griffith, NSW, Australia. The treatments consisted of factorial combinations of N levels with nitrification inhibitors (control, wax-coated calcium carbide, and nitrapyrin). The rate of nitrification was slowed considerably by the addition of wax-coated calcium carbide, but it was inhibited only slightly by the addition of nitrapyrin. As a result, the emission of N2O was markedly reduced by the application of wax-coated calcium carbide, whereas there was no significant difference in rates of N2O emission between the control and nitrapyrin treatments. Both nitrification inhibitors significantly reduced CH4 emission, but the lowest emission rates were observed in the wax-coated calcium carbide treatment. At the end of the experiment 84% of the applied N was recovered from the wax-coated calcium carbide treatment compared with ∼ 43% for the nitrapyrin and control treatments.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-0789
    Keywords: Nitrogen immobilization ; Mineralization ; Nitrification ; Nitrification inhibitor ; Acetylene ; CaC2 ; 15N enrichment ; Urea
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The effect of acetylene (provided by wax-coated calcium carbide, CaC2) on N transformations in a red-brown earth was measured in a field experiment with irrigated wheat by determining the change in the concentration and 15N enrichment of the organic N and mineral N pools with time. The study was conducted in the Goulburn-Murray Irrigation region of south-eastern Australia using 0.3 m by 0.3 m microplots fertilized with 15N-labelled urea (10 g N m-2; 5 atom% 15N). Acetylene was effective in slowing the nitrification of both unlabelled and labelled N. Nitrate derived from the added fertilizer reached a maximum 19 days after sowing in the treatment without CaC2, whereas little nitrate accumulated in the 8 g CaC2 m-2 treatment. There was significant immobilization of the urea N by 19 days after sowing in all treatments, but the extent of immobilization was not affected by the acetylene. The addition of acetylene slowed net mineralization of labelled and unlabelled N from the organic N pool, and resulted in increased accumulation of both unlabelled and labelled N in wheat tops.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 27 (1998), S. 221-229 
    ISSN: 1432-0789
    Keywords: Key words Climate change ; IPCC ; Land-use change ; Greenhouse effect ; Ozone destruction
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  Contributors to the Intergovernmental Panel on Climate Change (IPCC) generally agree that increases in the atmospheric concentration of greenhouse trace gases (i.e., CO2, CH4, N2O, O3) since preindustrial times, about the year 1750, have led to changes in the earth's climate. During the past 250 years the atmospheric concentrations of CO2, CH4, and N2O have increased by 30, 145, and 15%, respectively. A doubling of preindustrial CO2 concentrations by the end of the twenty-first century is expected to raise global mean surface temperature by about 2  °C and increase the frequency of severe weather events. These increases are attributed mainly to fossil fuel use, land-use change, and agriculture. Soils and climate changes are related by bidirectional interactions. Soil processes directly affect climatic changes through the production and consumption of CO2, CH4, and N2O and, indirectly, through the production and consumption of NH3, NOx, and CO. Although CO2 is primarily produced through fossil fuel combustion, land-use changes, conversion of forest and grasslands to agriculture, have contributed significantly to atmospheric increase of CO2. Changes in land use and management can also result in the net uptake, sequestration, of atmospheric CO2. CH4 and N2O are produced (30% and 70%, respectively) in the soil, and soil processes will likely regulate future changes in the atmospheric concentration of these gases. The soil-atmosphere exchange of CO2, CH4, and N2O are interrelated, and changes in one cycle can impart changes in the N cycle and resulting soil-atmosphere exchange of N2O. Conversely, N addition increases C sequestration. On the other hand, soil processes are influenced by climatic change through imposed changes in soil temperature, soil water, and nutrient competition. Increasing concentrations of atmospheric CO2 alters plant response to environmental parameters and frequently results in increased efficiency in use of N and water. In annual crops increased CO2 generally leads to increased crop productivity. In natural systems, the long-term impact of increased CO2 on ecosystem sustainability is not known. These changes may also result in altered CO2, CH4, and N2O exchange with the soil. Because of large temporal and spatial variability in the soil-atmosphere exchange of trace gases, the measurement of the absolute amount and prediction of the changes of these fluxes, as they are impacted by global change on regional and global scales, is still difficult. In recent years, however, much progress has been made in decreasing the uncertainty of field scale flux measurements, and efforts are being directed to large scale field and modeling programs. This paper briefly relates soil process and issues akin to the soil-atmosphere exchange of CO2, CH4, and N2O. The impact of climate change, particularly increasing atmospheric CO2 concentrations, on soil processes is also briefly discussed.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 28 (1998), S. 44-50 
    ISSN: 1432-0789
    Keywords: Key words Nitrous oxide ; Methane consumption ; Nitrification ; Oxides of nitrogen
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract  Land use changes in semiarid grasslands have long-lasting effects. Reversion to near-original conditions with respect to plant populations and productivity requires more than 50 years following plowing. The impact of more subtle management changes like small, annual applications of N fertilizer or changing cattle stocking rates, which alters N redistribution caused by grazing and cattle urine deposition, is not known. To investigate the long-term effects of N addition to the Colorado shortgrass steppe we made weekly, year-round measurements of N2O and CH4 from the spring of 1990 through June 1996. Fluxes of NOx (NO plus NO2) were measured from October 1995 through June 1996. These measurements illustrated that large N applications, either in a single dose (45 g N m–2), simulating cattle urine deposition, or in small annual applications over a 15-year period (30 g N m–2) continued to stimulate N2O emissions from both sandy loam and clay loam soils 6–15 years after N application. In sandy loam soils last fertilized 6 years earlier, average NOx emissions were 60% greater than those from a comparable, unfertilized site. The long-term impact of these N additions on CH4 uptake was soil-dependent, with CH4 uptake decreased by N addition only in the coarser textured soils. The short-term impact of small N additions (0.5–2 g N m–2) on N2O, NOx emissions and CH4 uptake was observed in field studies made during the summer of 1996. There was little short-term effect of N addition on CH4 uptake in either sandy loam or clay loam soils. Small N additions did not result in an immediate increase in N2O emissions from the sandy loam soil, but did significantly increase N2O flux from the clay loam soil. The reverse soil type, N addition interaction occurred for NOx emissions where N addition increased NOx emissions in the coarser textured soil 10–20 times those of N2O.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 11 (1991), S. 116-120 
    ISSN: 1432-0789
    Keywords: Denitrification ; Flooded soil ; 15N ; Urea ; Wetland rice ; Oryza sativa L
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary The efficiency of N use in flooded rice is usually low, chiefly due to gaseous losses. Emission of CH4, a gas implicated in global warming, can also be substantial in flooded rice. In a greenhouse study, the nitrification inhibitor encapsulated calcium carbide (a slow-release source of acetylene) was added with 75, 150, and 225 mg of 75 atom % 15N urea-N to flooded pots containing 18-day-old rice (Oryza sativa L.) plants. Urea treatments without calcium carbide were included as controls. After the application of encapsulated calcium carbide, 3.6 μg N2, 12.4 μg N2O-N, and 3.6 mg CH4 were emitted per pot in 30 days. Without calcium carbide, 3.0 mg N2, 22.8 μg N2O-N, and 39.0 mg CH4 per pot were emitted during the same period. The rate of N added had a positive effect on N2 and N2O emissions, but the effect on CH4 emissions varied with time. Carbon dioxide emissions were lower with encapsulated calcium carbide than without. The use of encapsulated calcium carbide appears effective in eliminating N2 losses, and in minimizing emissions of the “greenhouse gases” N2O and CH4 in flooded rice.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Biology and fertility of soils 17 (1994), S. 263-268 
    ISSN: 1432-0789
    Keywords: Methane consumption ; Methanotrophs Urea ; Ammonium oxidation ; Differential inhibition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Concentrations of CH4, a potent greenhouse gas, have been increasing in the atmosphere at the rate of 1% per year. The objective of these laboratory studies was to measure the effect of different forms of inorganic N and various N-transformation inhibitors on CH4 oxidation in soil. NH 4 + oxidation was also measured in the presence of the inhibitors to determine whether they had differential activity with respect to CH4 and NH 4 + oxidation. The addition of NH4Cl at 25 μg N g-1 soil strongly inhibited (78–89%) CH4 oxidation in the surface layer (0–15 cm) of a fine sandy loam and a sandy clay loam (native shortgrass prairie soils). The nitrification inhibitor nitrapyrin (5 μg g-1 soil) inhibited CH4 oxidation as effectively as did NH4Cl in the fine sandy loam (82–89%), but less effectively in the sandy clay loam (52–66%). Acetylene (5 μmol mol-1 in soil headspace) had a strong (76–100%) inhibitory effect on CH4 consumption in both soils. The phosphoroamide (urease inhibitor) N-(n-butyl) thiophosphoric triamide (NBPT) showed strong inhibition of CH4 consumption at 25 μg g-1 soil in the fine sandy loam (83%) in the sandy clay loam (60%), but NH 4 + oxidation inhibition was weak in both soils (13–17%). The discovery that the urease inhibitor NBPT inhibits CH4 oxidation was unexpected, and the mechanism involved is unknown.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1432-0789
    Keywords: Denitrification ; Flooded soil ; 15N ; Urea ; 15N balance ; Wetland rice ; Oryza sativa L.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Summary It is commonly assumed that a large fraction of fertilizer N applied to a rice (Oryza sativa L.) field is lost from the soil-water-plant system as a result of denitrification. Direct evidence to support this view, however, is limited. The few direct field, denitrification gas measurements that have been made indicate less N loss than that determined by 15N balance after the growing season. One explanation for this discrepancy is that the N2 produced during denitrification in a flooded soil remains trapped in the soil system and does not evolve to the atmosphere until the soil dries or is otherwise disturbed. It seems likely, however, that N2 produced in the soil uses the rice plants as a conduit to the atmosphere, as does methane. Methane evolution from a rice field has been demonstrated to occur almost exclusively through the rice plants themselves. A field study in Cuttack, India, and a greenhouse study in Fort Collins, Colorado, were conducted to determine the influence of rice plants on the transport of N2 and N2O from the soil to the atmosphere. In these studies, plots were fertilized with 75 or 99 atom % 15N-urea and 15N techniques were used to monitor the daily evolution of N2 and N2O. At weekly intervals the amount of N2+N2O trapped in the flooded soil and the total-N and fertilized-N content of the soil and plants were measured in the greenhouse plots. Direct measurement of N2+N2O emission from field and greenhouse plots indicated that the young rice plant facilitates the efflux of N2 and N2O from the soil to the atmosphere. Little N gas was trapped in the rice-planted soils while large quantities were trapped in the unplanted soils. N losses due to denitrification accounted for only up to 10% of the loss of added N in planted soils in the field or greenhouse. The major losses of fertilizer N from both the field and greenhouse soils appear to have been the result of NH3 volatilization.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Global change biology 11 (2005), S. 0 
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: The dynamics and demography of roots were followed for 5 years that spanned wet and drought periods in native, semiarid shortgrass steppe grassland exposed to ambient and elevated atmospheric CO2 treatments. Elevated compared with ambient CO2 concentrations resulted in greater root-length growth (+52%), root-length losses (+37%), and total pool sizes (+41%). The greater standing pool of roots under elevated compared with ambient CO2 was because of the greater number of roots (+35%), not because individuals were longer. Loss rates increased relatively less than growth rates because life spans were longer (+41%). The diameter of roots was larger under elevated compared with ambient CO2 only in the upper soil profile. Elevated CO2 affected root architecture through increased branching.Growth-to-loss ratio regressions to time of equilibrium indicate very long turnover times of 5.8, 7.0, and 5.3 years for control, ambient, and elevated CO2, respectively. Production was greater under elevated compared with ambient CO2 both below- and aboveground, and the above- to belowground ratios did not differ between treatments. However, estimates of belowground production differed among methods of calculation using minirhizotron data, as well as between minirhizotron and root-ingrowth methods. Users of minirhizotrons may need to consider equilibration in terms of both new growth and disappearance, rather than just growth.Large temporal pulses of root initiation and termination rates of entire individuals were observed (analogous to birth–death rates), and precipitation explained more of the variance in root initiation than termination. There was a dampening of the pulsing in root initiation and termination under elevated CO2 during both wet and dry periods, which may be because of conservation of soil water reducing the suddenness of wet pulses and duration and severity of dry pulses. However, a very low degree of synchrony was observed between growth and disappearance (production and decomposition).
    Type of Medium: Electronic Resource
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