ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The parameters α, β and γ of the equation WΔsGf(MX) = αBKT + βET + γ were calculated and analysed for different salts (MX) in pure solvents and in non-aqueous solvent-water mixtures (S). Among 109 different equations, only 64 were taken for the final analysis since in the case of 38 equations the parameters BKT and ET were highly correlated. After a statistical analysis and normalization, on the basis of the coefficients α and β obtained, it was found that the ions analysed may be divided into three classes characterized by the different dependences of α on β: class I, H+, Li+, Na+, Rb +, Cs+, Me4N+, Cl-, Br- and I-, where αN = 1.074βN + 1.639; class II, Ag+, Cl-, Br-, I-, OAc-, SCN- and N3- where αN = 2.057βN + 2.147; and class III, Ph4As+, BPh4-, Ph4C and Ph4Ge, where αN is variable and βN is almost constant. Two main conclusions can be drawn out from the results obtained: the behaviour of ions considered as Lewis acids and bases reflects different hard-soft properties of the ions, and the behaviour of the Ph4As+ ion is different from that of BPh4-.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610040706
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