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  • 2005-2009
  • 1985-1989
  • 1960-1964  (6)
  • 1930-1934
  • 1962  (6)
  • 1931
  • Dyes/Pigments  (4)
  • Natural products  (2)
Source
Material
Years
  • 2005-2009
  • 1985-1989
  • 1960-1964  (6)
  • 1930-1934
Year
Keywords
  • 1
    Electronic Resource
    Electronic Resource
    Mixed-Phase Pigments with Rutile Structures (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 41-45 
    Details
    ISSN: 0570-0833
    Keywords: Dyes/Pigments ; Rutile structure ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Until the present time, new color pigments have been developed by isotypic and homotypic mixed-phase formation. This paper deals primarily with heterotypic mixed-phase formation for the preparation of new colored and white pigments with the rutile structure. Dioxides and difluorides crystallizing in the rutile lattice-form were chosen as host-lattices for the mixed-phase formation. Hosts of the general formula AB2 can accommodate, as guests, in the form of solid solutions, oxides and/or fluorides with different structures. Characteristically, the mean statistical cation-radius lies between 0.55 and 0.98 Å, with single radii between 0.46 and 0.98 Å. Relative quantities are so chosen that the cation to anion ratio of 1:2 prescribed by the host lattice, as well as electroneutrality, is maintained.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196200411
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    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    The Application of Mass Spectrometry in Organic Chemistry: Determination of the Structure of Natural Products (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 98-111 
    Details
    ISSN: 0570-0833
    Keywords: Mass spectrometry ; Natural products ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mass spectrometry is a very useful method for the determination of the structure of organic compounds although the technique has not yet been widely employed in this field. Of particular interest is the high sensitivity of the instrument, making possible the use of very small amounts of sample, and the information obtainable regarding the size of the molecule and position of the groups therein. A certain volatility is required and the choice of a suitable derivative is, therefore, sometimes of importance. The fragmentations of the molecules in the ion source may be considered as reactions of “carbonium ions without solvent.” The application of the method in the determination of the structure of some natural products is outlined, using lipids, amino acids, peptides and alkaloids as examples.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196200981
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Conversion of Natural Substances by Microbial EnzymesExtended version of lectures delivered in Braunschweig(1960), Berlin (1960), and Basel (1961). (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 178-195 
    Details
    ISSN: 0570-0833
    Keywords: Enzyme catalysis ; Natural products ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Micro-organisms form enzymes that catalyze many reactions which are difficult to carry out in the laboratory or which involve many steps. Enzymes even react with substances which are normally foreign to them. The frequently high stereospecificity of microbiological reactions is of particular significance. The most important types of reactions are: hydroxylations, dehydrogenations (oxidations), and hydrogenations (reductions), cleavage of ester and C-C bonds, and transglycosidations. The variety of the compounds converted is extremely great.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196201781
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Heterocyclic Azo Dyes by Oxidative CouplingXXIII. Communication in this series. XII. Communication, S. Hünig and F. Müller, Liebigs Ann. Chem. 651, 89 (1962).Dedicated to Prof. Dr. O. Bayer on the occasion of his 60th birthday. (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 640-646 
    Details
    ISSN: 0570-0833
    Keywords: Azo dyes ; Dyes/Pigments ; Oxidative coupling ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New findings in the field of oxidative coupling reactions are reported. These involve: extension of this type of reaction to amidrazone system displaying (vinylogous) tautomerism and to unsymmetrical diarylhydrazines; elucidation of the coupling mechanism for these arylhydrazines and for the amidrazone systems previously described; the properties of some dyes, complexed with heavy metals, and the synthesis of tetraazapentamethine and penta-azapentamethine dyes.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196206401
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    Paper (German National Licenses)
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  • 5
    Electronic Resource
    Electronic Resource
    Dyeing of Poly(acrylonitrile) Fibers with Azatrimethinecyanines (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 532-537 
    Details
    ISSN: 0570-0833
    Keywords: Polyacrylonitrile ; Fibers ; Azatrimethinecyanines ; Dyes/Pigments ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Like all basic dyes, azatrimethinecyanines possess a good dyeing affinity for acrylic fibers. Compounds with isolated nitrogen atoms in the trimethine chain show insufficient light fastness, whereas good to excellent fastness to light is displayed by compounds having neighboring nitrogen atoms in the chain. Thus, a working hypothesis stating that the light fastness of trimethinecyanines on acrylic fibers is improved by progressive replacement of methine groups by nitrogen atoms has been partially confirmed.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196205321
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    Paper (German National Licenses)
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  • 6
    Electronic Resource
    Electronic Resource
    Reactivity of Dichloro- and Trichloropyrimidyl Dyes and the Sensitivity of their Dyeings to Hydrolysis (1962)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 568-572 
    Details
    ISSN: 0570-0833
    Keywords: Trichloropyrimidyl dyes ; Dyes/Pigments ; Dichloropyrimidyl dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several examples are used to show that the reactivity of dichloro- and trichloropyrimidyl dyes and the sensitivity of their dyeings to hydrolysis are determined by the nature of the bridge unit between the chromophore and the reactive system. The tendency of the dyeings to hydrolyze in acid and, more particularly, in alkaline media increases with increasing reactivity of the dyes. In alkaline media, dyeings made with dyes containing oxygen bridges are cleaved mainly between the reactive system and the chromophore, while in dyeings made with dyes containing imino or methylimino bridges, the linkage between the reactive system and the cellulose is hydrolyzed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196205681
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    Paper (German National Licenses)
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