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  • 1985-1989
  • 1955-1959  (951)
  • 1930-1934
  • 1830-1839
  • 1957  (951)
  • Organic Chemistry  (515)
  • Cell & Developmental Biology  (325)
  • Chemical Engineering  (111)
Material
Years
  • 1985-1989
  • 1955-1959  (951)
  • 1930-1934
  • 1830-1839
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Keywords
  • 101
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 191-197 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Vapor-liquid equilibria of two binary systems, benzene-n-hexane and benzene-cyclohexane, were measured at pressures from 4 to 18 atm. The three-constant Redlich-Kister equation was found satisfactory for correlation.With the benzene-n-hexane system no azeotrope occurred; with the benzene-cyclohexane system an azeotrope appeared, and the mole fraction of cyclohexane in it diminished with increase in pressure. Lack of correction for fugacity in the vapor phase introduced a maximum error of 4% in activity coefficients at highest pressure.
    Additional Material: 15 Ill.
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  • 102
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 213-222 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Data were obtained in flat-plate continuous-flow thermogravitational columns to check the theory developed by Furry, Jones, and Onsaer and a modification of this theory proposed by the authors. Separations of ethyl alcohol-water and benzene-n-heptane mixtures were measured, flow rate, column length, temperature difference, spacing between plates, and inclination of the plates being varied in the experiments. Theory and data are in qualitative agreement for the range of variables studied. Quantitative agreement exists between theory and experiment in the region of practical design for liquid-thermal-diffusion plants.Equations to aid in the design of thermal-diffusion plants are developed, and a plant to treat 1,000 bbl./day of a liquid aromatic-aliphatic mixture is designed and costs are estimated.
    Additional Material: 13 Ill.
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  • 103
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 230-235 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reaction kinetics for the catalytic dehydrogenation of sec-butyl alcohol to methyl ethyl ketone has been investigated at atmospheric pressure and temperatures ranging from 650° to 750°F. in the presence of solid brass spheres, 1/8 in. in diameter. The nature of this catalyst permitted a direct evaluation of the surface involved in this reaction and allowed the definition of a surface-feed ratio to be expressed as S/F in place of the conventional weightfeed ratio W/F commonly used in catalytic studies. Feed compositions ranged from secbutyl alcohol to mixtures containing high percentages of methyl ethyl ketone and hydrogen.In these studies mass transfer effects were found to be significant and, for a proper representation of conditiated at the catalyst surface, must be taken into account. The effect of feed compositions on the initial rates of reaction showed that the rate-controlling step was the desorption of hydrogen involving a single-site mechanism.In addition, the results of these studies have been used to produce values of height of reactor unit HRU which have been found to correlate with mass velocity and temperature. The HRU provides a simple means of calculating the depth of catalyst necessary to effect a designated conversion.
    Additional Material: 12 Ill.
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  • 104
    Electronic Resource
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 223-229 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A radioisotope technique has been utilized to study the point holdup of the dispersed phase and some operational flow characteristics in a packed countercurrent liquid-liquid extraction tower. The system used was toluene-water and the packing was Raschig rings. The toluene dispersed phase was tagged with gamma-radiating iodine-131.The study revealed that holdup experiences a hysteresis cycle with variations of the continuous-phase flow rate. Correlating equations are presented for “total” and permanent holdup, below loading, to account for this hysteresis. Entrance effects and flow maldistribution effects are readily determined by the method utilized. Displacement studies demonstrated that no simple “operational” dispersed-phase flow holdup exists, but rather a complex dispersed-phase movement, which involves all the “nonhysteresis” permanent holdup.
    Additional Material: 9 Ill.
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  • 105
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 248-256 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 106
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 262-267 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In spite of the importance of hydrogenation procesing operations in the refining of petroleum there are only limited experimental volumetric and phase equilibrium data concerning mixtures of hydrocarbons and hydrogen. An investigation of the volumetiric and phase behavior of the hydrogen-n-hexane system was therefore undertaken.The experimental study involved measurements of the specific volume of four mixtures of hydrogen and n-hexane at eight temperatures between 40° and 460°F. for pressures up to 10,000 lb./sq. in In addition, the composition of the gas phase in heterogeneous mixtures was determined at six temperatures within the interval mentioned above for pressures as high as 10,000 lb./sq. in.Little about this system was found to be qualitatively unusual except that the critical pressure exceeded 10,000 lb/sq. in. at all temperatures below 340°F. As would be expected, the dew-point gas was rather lean in n-hexane for temperatures below 220°F. and at pressures above 100 times the vapor pressure of n-hexane throughout the pressure range covered by this study.
    Additional Material: 6 Ill.
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  • 107
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 299-304 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The interaction between a turbulent air stream and a water film flowing parallel to it was studied. The variables explored were the liquid flow rate, the gas flow rate, and the film height. The data were correlated in terms of a liquid and a gas Reynolds number. Thinner films or films having a lower Reynolds number were more stable. For the experiments reported in this research the transition from a smooth surface to a surface possessing two-dimensional waves occurs at hUτρliquid/µliquid of about 520. Transition from two-dimensional waves to a “pebbled” surface occurs at a value of this parameter of about 600. Theories presented in the literature for the initiation of waves on a liquid surface do not adequately describe the experimental results.
    Additional Material: 14 Ill.
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  • 108
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 318-320 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper presentes a correlation to predict the equilibrium ratios of hydrogen in hydrocarbon mixtures by use of the parameters of pressure and convergence pressure. Also a procedure to predict convergence pressures of hydrogen-containing mixtures was developed from a correlation of critical loci. With the predicted convergence pressure the measured values of hydrogen equilibrium ratios in binary hydrogen-paraffin mixtures were predicted with a statistical deviation of 8.1% for 237 measurements. Including hydrogen-olefin and multicomponent mixtures of hydrogen, paraffins, and olefins, the statistical deviation was found to be 11.3% for a total of 375 comparisons with measured values of hydrogen equilibrium ratios.
    Additional Material: 6 Ill.
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  • 109
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 325-329 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The surface tensions against air of acetone-water solutions have been measured over the entire composition range from 20°C. to generally within 1° to 10°C. of the normal boiling points. The capillary-height method was employed and the results are thought to be accurate to better than ±0.5%.
    Additional Material: 3 Ill.
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  • 110
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 343-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Constant layer moisture at the hot surface is found to exist during the constant-rate period of drying of sand on a hot surface in still air. It accounts not only for the constantrate period of drying itself but also largely for the length of the period.Temperature of the air-surface interface usually has minor effects on the rate of vaporization because equilibrium between vapor and the bed is not established during periods of rapid vaporization.Numerical relationships have not been established.
    Additional Material: 12 Ill.
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  • 111
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 361-365 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two-phase critical flow of steam-water mixtures has been investigated over a pressure range from 4 to 43 1b./sq.in. abs. and a quality range from saturated vapor to 1% (weight) vapor. Discharges were measured from 1/4-,1/2-, 3/4-, and 1-in. pipes and from annuli of intermediate cross-sectional areas. The experimental mass flow rates are always grteater than the values calculated on the basis of a homogeneous flow model. Several empirical methods for correlating the data were determined, and comparisons are presented of the predictions of several analytical flow models.
    Additional Material: 10 Ill.
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  • 112
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 373-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Applying both their own assumptions and the mechanism of lateral mixing proposed by Ranz (20), the authors obtained theoretical formulas for effective thermal conductivities ke in packed beds. Previously reported experimental data were analyzed with these equations, and the usable data for predicition of ke were shown.In order to see the influence of both packing characteristics and temperature on the effective thermal conductivities, experimental data were obtained with air for beds with various kinds of packing, i.e., iron spheres, porcelain packings, cement clinker, insulating fire brick, and Raschig rings. Correlation of these data with Equation (15) showed that this equation adequately expressed the heat transfer mechanisms in packed beds with motionless gases, especially at hight temperatures.
    Additional Material: 18 Ill.
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  • 113
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 391-394 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A rigorous method is presented for the evaluation of the heat requirements in binary batch fractionations which involve negligible column hold up. The method, in which the additional variables of the discontinuous process are taken into account, is a modification of the methods of Ponchon and Savarit for continuous operation. Two examples, one for a fractionation in which the composition of the product is constant and the other in which the reflux ratio is constant, are given as illustrations of the method.The application of the method permits more accurate evaluation of reboiler and condenser heat loads and, in turn, better design.
    Additional Material: 7 Ill.
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  • 114
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 276-279 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: On the assumption of laminar Newtonian flow, flow profiles are developed for both the vertical plate and cylindrical column by use of classical equations. From the flow profiles the mass transport, vertical pressure gradient, and optimal design parameters are calculated. With the Reynolds-number criterion used to ascertain the maximum nonturbulent velocity, minimal values for the plate distance and column radius can be calculated. An example is included for each case.
    Additional Material: 1 Ill.
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  • 115
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 268-275 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Values of total pressure drop are presented for the flow of vaporizing water in an internally heated 1-in. I.D. by 1½-in. O.D. annulus at mass velocities of 270 to 1,440, lb./(sec.)(sq.ft.), pressures of 9 to 180 lb./sq. in., and up to 0.34 fraction by weight vaporized. The total heated length over which boiling took place was as large as 6 ft. There is no evidence of “sonic” pressure jumps at the outlet. The results for the annulus mentioned lie within +30 to -11% of the Lockhart-Martinelli curve at higher qualities and with ±45% of the correlation at lower qualities where the actual quality is more uncertain. A simplified correlation in terms of quality and volume fraction of liquid predicted the two-phase frictional pressure drops with an average error of 41%.It was found that the ratio of the two-phase pressure drop through a 0.3-in. orifice to the drop with no vaporization was approximately a linear function of the quality in the vena contracta but was only one tenth to one third as great as would be predicted if the mixture were to expand as a homogeneous fluid. Prediction of orifice presure drops is improved if slip between vapor and liquid is considered.
    Additional Material: 12 Ill.
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  • 116
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The separation of 4.5 g. of americium from approximately a kilogram of light rare earths (primarily lanthanum) was achieved on a pilot plant scale by chromatographic displacement of the mixture from Dowex-50 resin with 0.1% ammonium citrate at pH 8 into hydrogen-form Dowex-50. The americium collected into a narrow band and was eluted free from lanthanum but contained an equal weight of cerium. A 6- and a 2-in.-diam. column were used in tandem. Use of a final column with a much smaller diameter would have permitted a cleaner separation from cerium, but this was left for a laboratory-scale separation by a different process. Precipitation, which was observed in the columns during the first runs, was later avoided entriely by use of high flow rates both initially and during the transfer between columns. No adverse effects were noted from ∼15 curies of alpha activity.
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  • 117
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 118
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 305-312 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The design variables that affect the pressure drop across dry perforated plates were determined and correlated. Average orifice coefficients were calculated for the perforated plates by using a modified form of the single-orifice flow equation.The variables which affected the orifice coefficients were found to be the hole diameter, hole pitch, plate thickness, fraction of the plate covered by the perforated area, and a Reynolds number based on the hole diameter. The orifice coefficients have been correlated with these variables in dimensionless groupings.The correlation presented covers a practicable range of variables for which the pressure drop may be predicted in design.
    Additional Material: 22 Ill.
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  • 119
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 484-489 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure drop due to fluid friction has been measured in a smooth tube; in six smooth concentric annuli; and between smooth, parallel, flat plates. The data cover the viscous, transition, and lower turbulent ranges of flow. Friction factors are in agreement with theory in the viscous range and can be correlated uniquely in the fully turbulent range by means of a modified hydraulic radius concept. Limits of the transition region in annuli are functions of the ration of inner and outer radii. Correlations in the fully turbulent range permit friction factors for the noncircular ducts to be predicted within the uncertainty of smooth-tube data. Such factors can be used for the prpose of correlating other variables as well as for direct calculation of pressure drop.
    Additional Material: 3 Ill.
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  • 120
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 439-442 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of axial mixing in straight pipes is analyzed by a modification of G. I. Taylor's analysis. The treatment presented here includes the effect of both Schmidt and Reynolds numbers throughout the turbulent-flow range. All applicable data on flow of gases and liquids are found to confirm the validity of the method.The analysis indicates that axial mixing increases rapidly as the flow approaches the laminar region, especially for liquids, and that pipe roughness causes a relatively small increase in axial mixing. Turbulent eddy diffusion in the axial direction has a negligible effect.The results of the analysis are applicable to those systems wherein the kinematic viscosity of the flowing mixture does not vary greatly from one region to another and in which the concentration region of interest is spread out along a sufficient length of pipe. These limitations are broad enough to permit most practical problems to be treated by the method.
    Additional Material: 2 Ill.
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  • 121
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 535-538 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The problem of diffusion in a moving medium with given motion of the boundaries is considered. The method presented yields the analytical solution to any desired degree of accuracy provided that solutions for certain associated problems of diffusion in a medium at rest with boundaries at rest are known. The method is applied to the analysis of partial and approximate solutions previously presented for the one-dimensional case of a spherical cavity in a liquid with radial boundary motion induced by evaporation.
    Additional Material: 5 Ill.
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  • 122
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 123
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 395-404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 15 Ill.
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  • 124
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    AIChE Journal 3 (1957), S. 418-427 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effects of the physical properties and volume flow rate of liquids on the surface area of sprays produced by a pressure type of atomizing nozzle were determined experimentally. the specific surface area of the sprays is correlated by an equation of two dimensionless groups in terms of the variables surface tension to the -1.0 power, kinematic viscosity to the -0.4 power, and volume flow rate to the 2.4 power. The volume flow rate is correlated by an equation of two dimensionless groups containing the variables viscosity to the 0.17 power, density to the -0.58 power, and spray pressure to the 0.42 power. The conversion of compression energy to surface-area energy appears to be constant at approximately 0.1%.
    Additional Material: 19 Ill.
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  • 125
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 9S 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 126
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 3 (1957), S. 431-431 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 127
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    AIChE Journal 3 (1957), S. 443-448 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method is presented for the analysis of a reaction between a porous solid and a gaseous reactant where the kinetic expression is linear in the concentration and where appreciable concentration gradients are established in the pore system as a result of diffusive transport rate. Two cases are treated mathematically: a single cylindrical pore initially of uniform diameter and a porous solid initially containing uniform cylindrical pores with random intersections. The mathematical solutions to the latter case are used to interpret the experimental results reported in the literature on the gasification of graphite rods with carbon dioxide. Values of the computed effective diffusivity are an order of magnitude smaller than the bulk diffusivity at the same temperature and pressure.
    Additional Material: 11 Ill.
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  • 128
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    AIChE Journal 3 (1957), S. 467-472 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previous papers have reported equilibrium data for the binary systems cyclohexaneheptane, heptane-toluene, and cyclohexane-toluene. This present study gives similar data for the ternary system cyclohexane-heptane-toluene and compares the activity coefficients with those predicted from the three limiting binaries.The ternary activity coefficients fall well in line between the limiting-binary data. Distribution is about as would be predicted by the ternary Margules equations. As an approximation, if the coefficients are plotted as a function of the aromatic concentration only, without consideration of the ratio of naphthenes to paraffins, reasonably good correlation is observed.
    Additional Material: 13 Ill.
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  • 129
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    AIChE Journal 3 (1957), S. 11D-11D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 130
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    AIChE Journal 3 (1957), S. 10D-11D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 131
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    AIChE Journal 3 (1957), S. 12D-12D 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 132
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    AIChE Journal 3 (1957), S. 83-91 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements are reported on axial mixing of binary gas mixtures at room temperature and atmospheric pressure in a random bed of spherical particles. By means of the Fick's Law equation for diffusion an axial Peclet number, dp U/Ez (where dp is particle diameter, U is interstitial velocity, and Ez is axial eddy diffusivity), was computed in terms of the ratio of the amplitudes of a sinusoidal concentration wave at the inlet and outlet of the bed. An experimental method was devised to eliminate end effects in the system. For the gas systems H2—N2 and C2H4—N2 and for Reynolds numbers between 100 and 400 the mean of twenty-one determinations of axial Peclet number was 1.88 ± 0.15. This value is in excellent agreement with a value of 2.0 predicted theoretically on the assumption that the bed acts as a series of n perfect mixers, where n is the number of particles traversed between inlet and outlet.Axial diffusivity for turbulent flow of gases among particles is about sixfold larger than radial diffusivity, previously determined. It is suggested that axial diffusivity may not, perhaps, be neglected in contacting devices, such as adsorbers and catalytic reactors.
    Additional Material: 10 Ill.
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  • 133
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    AIChE Journal 3 (1957), S. 117-120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 10 Ill.
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  • 134
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    AIChE Journal 3 (1957), S. 111-116 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The viscosity of a suspension is related to the properties of the suspending liquid and the suspended particles by measuring the viscosity of suspensions made up of closely sized materials such as glass spheres, plastic Zeolite spheres, blasting sand, and salt cubes in a wide range of concentrations in liquids of varying properties made up of castor oil, tetrabromoethane and carbon tetrachloride, or corn syrup and water. The measurements were made under carefully controlled conditions by means of a Brookfield viscometer, and the reproducibility of results was demonstrated by repetitive runs.Equations are derived to describe the viscosities of these various suspensions in terms of the viscosity and density of the suspending liquid and of the shape, size distribution, density, and concentration of solid particles. The range of concentration covered is from infinite dilution to near infinite viscosity.The results obtained can best be explained by postulating nonuniform distribution of particles in a suspension in a network of tetrahedral and simple cubical packings.
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  • 135
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    AIChE Journal 3 (1957), S. 101-110 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes further research on a 4-in. I.D. by 8-ft. spray tower of Elgin design. Previous work concerned limiting flow and holdup in this tower. Owing to its high capacity and low cost, the spray tower would have much greater commercial application in liquid-liquid extraction if its conditions of transient operation could be predicted and if it could be operated to yield low Ht values. This research attempts to show that transient conditions can be predicted and that low Ht values for both mass and heat transfer can be realized near the limiting flow conditions.Theroretical equations for rate of approach to steady state derived and tested for the systems ethylene dichloride-water-propionic acid and ethylene dichloride-water-acetic acid show that the approach depends on the ratio of the phase flow rates. This study is important for the prediction of start-up time for industrial towers.With the same systems the extraction capacity of the spray tower was investigated up to the condition of rejection. The results were correlated as KEa and Ht, OE vs. a function of the ratio of the phase flow rates. The dispersed-phase flow rate was found to have primary significance.The heat transfer rates between water as continuous phase and solvents of various denisties were correlated as Ht′ values plotted against a function of the ratio of the phase flow rates. The advantages of operation near rejection were demonstrated, and the effect of direction of heat transfer was found to be significant.
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  • 136
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    AIChE Journal 3 (1957), S. 121-126 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Values of thermal conductivity and temperature coefficients for thirty-five pure organic liquids, in addition to those previously reported, obtained with a previously described apparatus (Part I), are presented. Values of thermal conductivity or temperature coefficients for twenty-eight of these liquids have not been reported before. The experimentally determined maximum error is ±1.0%.The two methods for predicting the thermal conductivity of liquids previously proposed (Parts I and II) are extended to cover the types of compounds studied in this investigation, in particular ring compounds.The temperature coefficient of thermal conductivity was observed to decrease rapidly, approaching zero as the freezing point is approached. The existence of a transition temperature or region within the liquid state is shown and identified with the onset of molecular rotation.
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  • 137
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    AIChE Journal 3 (1957), S. 127-136 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass and heat transfer rates in extraction are studied theoretically and experimentally for the practical range of the variables involved. For the particular but typical case of liquid drops moving through another liquid a simple correlation for the over-all mass transfer coefficient is presented, which holds with a probable error of 20%.Included are systems in which the rate is limited by either coefficient, as well as systems in which both coefficients are significant. The correlation, valid for both directions of transfer with either phase dispersed, is useful for the extrapolation of performance from system to system in a given piece of equipment. Also, together with correlations for transfer area and effective driving force, it is part of the information needed for design.
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  • 138
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    AIChE Journal 3 (1957), S. 144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 139
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    AIChE Journal 3 (1957), S. 136-142 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The pressure-drop characteristics associated with one liquid and one gaseous phase flowing concurrently in a pipe or tube have yet to be understood. The operation of evaporators, boilers, and condensers has long stimulated interest in the pressure drop of steamwater mixtures, and more recently this specialized case of one-component, two-phase flow has received even greater attention from the applications in cooling nuclear reactors. The two-phase-flow problems have not been amenable to through theoretical analyses, and therefore empirical and semiempirical correlations have attained unusual prominence in practical applications. The present investigation employs a new research tool for the study of two-phase-flow structure.A variety of geometric flow patterns is possible. Bergelin, Alves, and others have classified these patterns according to visual appearance; whereas the Martinelli classifications were based upon whether the flow in each phase was termed viscous or turbulent. The distinction between viscous and turbulent flow in either phase is rather arbitrary, and if the Reynolds number for one phase, calculated on the basis of the total tube diameter, is greater than 2,000, the flow in the phase is called turbulent. This investigation is confined to the study of annular flow, in which most of the liquid is found in an annular ring surrounding the central vapor core and the flow in each phase is turbulent.Boiling or flashing occurs when superheated water rises in an insulated vertical tube at atmospheric pressure. For a separated two-phase flow geometry, the mean linear steam velocity may exceed that of the water. The fraction of the tube occupied by the steam (void fraction) at a given cross section cannot be obtained directly from a determination of the thermodynamic quality. Void fractions, however, must be known for the estimation of the pressure drops due to head and momentum changes.Void fractions and pressure drops for steam-water flows were measured in an 0.872-in. I.D. vertical tube at atmospheric pressure over a quality range of 0 to 4%. The test section was the hot leg of a natural-circulation loop, and the inlet liquid flow rate ranged from 1 to 3 ft./sec. A new technique for measuring void fractions was used, and the method utilizes the difference between the gamma-ray absorption coefficients of water and steam.
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  • 140
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    AIChE Journal 3 (1957), S. 10M 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 141
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    AIChE Journal 3 (1957) 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 142
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    AIChE Journal 3 (1957), S. 153-156 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 143
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    AIChE Journal 3 (1957), S. 176-180 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dynamics of agitating single- and two-phase liquid mixtures in the absence of an air-liquid interface was compared with that of similar systems with an interface. Two geometrically similar cylindrical vessels, 12 and 18 in. in diameter respectively, were used, each fitted with a similar six-bladed, disk-turbine impeller.New general correlation curves of power number with Reynolds number are presented which show that elimination of the air-liquid interface makes it possible to attain dynamic similarity in scale-up in unbaffled vessels but makes little difference in baffled vessels.
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  • 144
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    AIChE Journal 3 (1957), S. 187-190 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equilibrium isotherms are presented for the cation exchange of copper and sodium on Dowex-50 resin in solutions from 0.01 to 4N in chloride content, and the equilibrium data are correlated on the basis of the Donnan equilibrium. Data are also given on the water content of the resin and the diffusible ions present in this water.
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  • 145
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    AIChE Journal 3 (1957), S. 208-212 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effective correlations of turbulent velocities and friction losses for tubes and parallel plates recently published have been analyzed further in order to simplify their use and to extend the range of Reynolds number.Working diagrams have been developed from which turbulent friction losses and local velocities for tubes and parallel plates can be calculated without interpolation or trial-and-error procedures. Tentative values of parallel-plate friction factors and average-to-maximum velocity ratios in the transition region are also included, and new experimental values of the velocity ratio in smooth tubes are reported. The working diagrams permit more rapid, accurate, and consistent calculations of fluid behavior to be made over a wider range of operating conditions than was previously possible.
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  • 146
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    AIChE Journal 3 (1957), S. 236-241 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The decreasing solubility of hydrogen in hydrocarbons with decreasing temperature continues down to the freezing point of the hydrocarbons, around -300°F. This behavior is shown to be an enlargement of phenomena exhibited by normal hydrocarbon mixtures. Methods of predicting equilibrium-phase compositions are presented for hydrogen in ligh-hydrocarbon systems. The correlations are satisfactory for binary and certain ternary systems, but are not reliable for complex mixtures.
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  • 147
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    AIChE Journal 3 (1957), S. 242-248 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat transfer and friction measurements were made for air flow through a smooth copper pipe and six other commercial pipes, with a ratio of diameter to equivalent sand roughness varying from 640 to 64. The Reynolds number range was 10,000 to 80,000. Though some increase in heat transfer coefficients with roughness was found, the heat transmission per unit power loss always decreased.The momentum-heat-transfer anlogies of Reynolds and Colburn are shown to be inadequate for handling the experimental data. Those of Prandtl and Taylor, von Kármán, and Pinkel fail to show a required Reynolds number dependence of jh when friction factor has become independent of Reynolds number for a rough pipe. Martinelli's equation shows such dependence and, even in approximate form, gives good prediction of the experimental results.
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  • 148
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    AIChE Journal 3 (1957), S. 405-410 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Local convective thermal transfer is difficult to predict for nonuniform three-dimensional boundary flows. Direct measurements of local transfer from objects of practical interest are therefore useful in the prediction of thermal transfer and in an understanding of multidimensional boundary flows.Measurements of the gross and local transfer were made upon a silver sphere 0.5 in. in diameter and a ceramic porous sphere of the same size from which n-heptane was permitted to evaporate. The air stream had a level of turbulence of approximately 5.4% and only small variation in velocity with position. Temperature distributions in the boundary flows around these spheres were determined, and from these distributions local transfer coefficients were established for the forward hemisphere. The gross transfers were established from the electrical energy added to the silver sphere and from the quantity of n-heptane evaporated from the porous sphere.The local thermal transfers were in reasonable agreement with some of the theoretical analyses based upon a three-dimensional laminar-boundary layer. Satisfactory agreement was obtained between spatial integration of the local transfer and the simultaneously measured over-all values. These, in turn, were in fair agreement with correlated values of the gross thermal and material transfer from spheres.
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  • 149
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    AIChE Journal 3 (1957), S. 462-466 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A kinetic study of the catalytic vapor-phase hydrogenation of three aldehydes (acetaldehyde, propionaldehyde, and n-butyraldehyde) was made at low conversions with a commercial supported nickel catalyst. A simple initial rate equation was determined and found to agree with a mechanism suggested by the ideal kinetics of Hougen and known experimental evidence. By means of this equation the relative reactivities of the aldehydes were compared and found to agree with the predictions of organic theory. An improved reactor designed to ensure isothermal operation is described.
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  • 150
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    AIChE Journal 3 (1957), S. 480-483 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 151
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    AIChE Journal 3 (1957), S. 321-324 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 152
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    AIChE Journal 3 (1957), S. 331-335 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Extension of the kinetics of the catalytic oxidation of nitric oxide on activated carbon and silica gel confirms the rate-controlling step postulated by previous workers. The effect of variables including water vapor on the reaction rate is expressed by an equation containing the constants a, b, c, and w, which have been evaluated for both catalysts at 30°, 45°, and 60°C. The effect of water vapor is to reduce the reaction by reversible adsorption on the active sites of the catalyst. The value of w is dependent on temperature but independent of water-vapor concentration up to a relative humidity of 20%. Above 20% the value of w for activated carbon increases greatly with relative humidity, in agreement with the effect of capillary adsorption at high water contents.
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  • 153
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    AIChE Journal 3 (1957), S. 353-360 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Linear partial-differential eqations are often encountered when thermal or material diffusion in flowing systems is considered. Analytic solutions of such equations are known for only the simplest situations. In two examples a graphical method of solution is presented and demonstrated which makes feasible, without excessive labor or special computing facilities, the use of available knowledge concerning turbulent flow in the prediction of thermal or material transfers in complex situations involving linear steady flow.
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  • 154
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    AIChE Journal 3 (1957), S. 381-385 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Heat and mass transfer and coagulation are considered as related to the mean-square relative velocity between particle and fluid uR2 and eddy diffusion as described by the mean-square particle displacement, Xp2. The mathematical methods used are similar to those employed in the early calculations of the Brownian motion.The mean-square relative velocity is obtained as a function of particle characteristics, intensity of turbulence, and a fluid correlation coefficient. In the limiting case of equal particle and fluid density uR2 = 0, and for very heavy particles uR2 → uF2.A general expression for the eddy diffusivity is obtained is obtained which reduces to the same form as that of the fluid for the stationary state. However, the correlation coefficient to be used in the calculations depends on uR2. As a first approximation, it can be assumed that at a sufficiently long time from the introduction of the particles, fluid and particle diffusivities are equal.For short times after injection, the particle spread may be much less than that of the fluid. An illustrative calculation for the initial spreading of a jet of suspended particles is offered. In all cases an effort is made to organize the available experimental data within the framework of the theory.
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  • 155
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957) 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 156
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 190-200 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird der Einfluß der Temperatur der reduzierenden Zersetzung von Nickel-Magnesiumformiat-Mischkristallen und Nickel-Magnesiumoxalat-Mischkristallen auf die Oberflächengröße und die katalytische Aktivität der so hergestellten Nickel-Magnesiumoxydkatalysatoren untersucht.
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  • 157
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 177-178 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 158
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 179-189 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden Nachweisreaktionen für Pyrrole erprobt, die es ermöglichen, diese Körper auch in biologischem Material zu finden und zu trennen. Dabei erwiesen sich Isatin- und HgCl2-Verbindungen der Pyrrole als geeignet. Außerdem wurden Spektren der farbigen Kondensationsprodukte der Pyrrole und HgCl2-Verbindungen mit p-Dimethyl-aminozimtaldehyd ausgemessen, sowie die Pyrrole und deren Isatinverbindungen papierchromatographisch untersucht.
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  • 159
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 236-240 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Durch Einwirkung von Paraformaldehyd und Chlorwasserstoff auf einige 4-Alkoxyacetophenone wurden 2-Alkoxy-5-acetyl-benzylchloride glatt gewonnen. Aus letzteren konnten durch Umsetzungen die entsprechenden Aldehyde, Cyanide, Acetamide und Karbonsäuren erhalten werden.
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  • 160
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 257-259 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aus Diacetyl und Glycerin bildet sich das 2.3-Dimethyl-2.3-dioxy-6-methylol-dioxan-(1.4) (I). UV-Spektrum und Tri-[phenylurethan] von (I) bestätigen die Struktur des cyclischen Bis-halbacetals.
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  • 161
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 278-285 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An ternären flüssigen Systemen, deren eine Komponente als Alkohol polaren Charakter besitzt, wird die Gültigkeit der CAILLETET-MATHIASschen Regel überprüft und versucht, die Dichten der gesättigten Lösungen von Alkohol und Kohlenwasserstoff aus den Dichten der einzelnen Komponenten zu berechnen. Die Additivität der Dichten einiger binärer Systeme bei 20° C ist angegeben. Sämtliche Messungen wurden zwischen 20 und 60° C durchgeführt.
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  • 162
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 319-323 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Es wird über die Reduktion von seleniger Säure durch Karbonsäuren in Gegenwart von Kaliumpermanganat und Salzsäure berichtet. Die Versuchstemperaturen liegen bei 50 und 70° C. Es wird festgestellt, daß die Reduktion analog der von Goldchlorid verläuft.
    Notes: Reduction of selenous acid by certain carboxylic acids in presence of small quantities of KMnO4 has been studied. The observed enhanced reducing power of the carboxylic acids treated with KMnO4 towards selenous acid has been explained as being due to the formation of intermediate oxidation products of varying degree of stability, which strongly reduce selenous acid. In a few cases the presence of definite oxidation products has been indirectly proved. The results obtained are, in general, similar to those of gold chloride-carboxylic acid reactions studied by MACMAHON and SRIVASTAVA.
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  • 163
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    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Mittels einer 2,0proz. Lösung von β-Oxyäthyliminodiessigsäure als Elutionsmittel werden bei PH-Werten von 7-8 lanthanreiche Ceriterdengemische getrennt. Die zweite Austauschersäule läßt sich hierbei in der H+-Form verwenden. Das gegen Ende der Elution noch ausschließlich am Austauscher befindliche Lanthan kann durch Elutionsmittel höherer Konzentration rasch eluiert werden.Zum Zwecke der Trennung von Didymgemischen kann die zweite Austauscheräule anstatt mit Wasserstoffionen vorteilhaft auch mit Ionen der Yttererden beladen werden, wodurch neben der Trennung der Didym-Komponenten eine bemerkenswerte Fraktionierung des in der zweiten Säle eingesetzten Yttererdengemischs erzielt werden kann.Mit Austauschersäulen von 2,2 cm Durchmesser und 130 cm Länge lassen sich etwa 20 g Seltenerdoxyde in 4 bis 5 Tagen trennen, so daß größere Anteile reiner Oxyde oder doch Fraktionen binärer Gemische anfallen, welche durch Wiederholung des Verfahrens in die reinen Komponenten aufgespalten werden.
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  • 164
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    Journal für Praktische Chemie/Chemiker-Zeitung 5 (1957), S. 77-82 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nach einem kurzen Überblick über das Schrifttum wird der Reaktionsablauf bei der Darstellung von Chloranil aus Phenol durch Chlorieren in wäßrig-saurer Phase an Hand analytischer Daten und von Modellversuchen aufgezeigt.
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  • 165
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    Journal für Praktische Chemie/Chemiker-Zeitung 5 (1957), S. 97-100 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Um einen vertieften Einblick in die Primärvorgänge der Inkohlungsreaktionen von Braunkohlen in Gegenwart von Wasser zu bekommen, wurden die erhaltenen Sekundärkohlen verschwelt. Die Ergebnisse lassen den Schluß zu, daß bei Inkohlungsreaktionen die Decarboxylierung und Dehydratisierung ab etwa 300° C zugunsten einer Spaltung der Huminsäuren zurückgedrängt wird.
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  • 166
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 241-243 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird im folgenden eine Methode beschrieben, die es gestattet, Zink durch innere Elektrolyse analytisch zu bestimmen. Seines hohen negativen Abscheidungspotentials wegen, wird als Anode Natriumamalgam verwendet. Zinkmengen vor der Größenordnung 100 mg bei 50° C und 50 mg bei Zimmertemperatur werden innerhalb 45 Minuten niedergeschlagen. Die Genauigkeit der Methode wird angegeben.
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  • 167
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 270-277 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The insecticidal activity of some substituted sulphones and sulphonamides and their cyanoethylation products is discussed in relation to the already well-known insecticides. Some of the compounds prepared showed excellent activity. In the experimental part, the preparation of the substances thus tested has been described.
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  • 168
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 306-318 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Wäßrige Magnesiumchloridlösungen können bei Sättigung an diesem Salz geringe Mengen Magnesiumsulfat, Natriumchlorid und Kaliumchlorid enthalten. Derartige Lösungen fallen bei industriellen Verfahren der Carnallitverarbeitung an. Über Ionenausaustauscher auf Wofatit-Basis kann durch Austausch von Natrium- und Kalium-Ionen gegen Magnesium-Ionen der Magnesiumchloridspiegel dieser Lösungen entsprechend erhöht werden. Natrium- und Kalium-Ionen lassen sich über mehrere Stufen auf diese Weise weitgehend entfernen1.Ein Austausch der Sulfat-Ionen in diesen Lösungen gegen Chlor-Ionen kann bei der angewandten Methodik nur in geringem Maße erreicht werden.Die komplizierten Verhältnisse in den untersuchten konzentrierten Elektrolytlösungen benötigen lange Gleichgewichtseinstellungszeiten, führen zu speziellen anomalen Austauscheffekten und erschweren auch die theoretische Behandlung.
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  • 169
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 205-211 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In der vorliegenden Arbeit wird ein neues elektro-analytisches Verfahren zur schnellen und genauen Bestimmung des Thalliums mittels einer durchaus einfachen Apparatur vorgeschlagen. Die quantitative Bestimmung des Thalliums erfolgt in der Form eines Thallium(III)-oxyds, welches sich an der Platinelektrode (der Anode) abscheidet. Die Möglichkeit, eine innere Analyse mit einem auf einer indifferenten Elektrode verlaufenden Oxydationsprozesses durchzuführen, wurde bisher nicht zu analytischen Zwecken benutzt. Es wurde festgestellt, daß die Zusammensetzung des sich an der Anode abscheidenden Niederschlages der Formel Tl2O3 entspricht. Das Vorhandensein von Ag+ n. a. stört nicht die genaue Bestimmung des Thalliums.
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  • 170
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 212-214 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird über die Oxydation von o-Xylol in der flüssigen Phase mit Luft in Gegenwart von Kobaltstearat zur o-Toluylsäure berichtet und die Möglichkeit einer autokatalytischen Reaktion in Erwägung gezogen.
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  • 171
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    Journal für Praktische Chemie/Chemiker-Zeitung 4 (1957), S. 260-269 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die partielle Abspaltung eines Mols Wasser bei in 3-α Stellung substituierter 6 β-Oxycholansäure- und Allocholansäurederivaten führt im 1. Fall zur Darstellung der Δ6 - 3 α-Oxycholensäure und im 2. Fall zur Darstellung der Δ5 - 3 α-Oxycholensäure als Grundkörper. Von beiden Säuren wird die Herstellung einiger Derivate beschrieben. Zur Charakterisierung der Δ6-Sterinverbindungen der Normalreihe und zur Unterscheidung gegenüber den Isomeren Δ5-Verbindungen werden die bei 1650 cm-1 und bei 745 cm-1 auftretenden Banden der Δ6-Doppelbindung zugeordnet.
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  • 172
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 173
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    The @Anatomical Record 127 (1957), S. 75-95 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 4 Tab.
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
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    Topics: Medicine
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  • 175
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    The @Anatomical Record 127 (1957) 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 176
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    The @Anatomical Record 127 (1957), S. 163-171 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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    The @Anatomical Record 127 (1957), S. 173-185 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 178
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 179
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 180
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    The @Anatomical Record 127 (1957), S. 551-567 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 181
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    The @Anatomical Record 127 (1957), S. 527-537 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 12 Ill.
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    The @Anatomical Record 127 (1957) 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 183
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    The @Anatomical Record 127 (1957), S. 539-550 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 2 Ill.
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  • 184
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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    The @Anatomical Record 127 (1957), S. 735-753 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 2 Ill.
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  • 186
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    The @Anatomical Record 127 (1957), S. 755-756 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 187
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    The @Anatomical Record 128 (1957), S. 19-21 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 1 Ill.
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  • 188
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 6 Ill.
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  • 189
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    The @Anatomical Record 128 (1957), S. 77-89 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 190
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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    The @Anatomical Record 128 (1957), S. 223-231 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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    The @Anatomical Record 128 (1957), S. 300-360 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 193
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    The @Anatomical Record 128 (1957) 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 194
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    The @Anatomical Record 128 (1957), S. 361-377 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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  • 195
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    The @Anatomical Record 128 (1957), S. 69-75 
    ISSN: 0003-276X
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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    The @Anatomical Record 128 (1957), S. 91-111 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Additional Material: 1 Ill.
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  • 198
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    The @Anatomical Record 128 (1957), S. 149-169 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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    The @Anatomical Record 128 (1957), S. 201-211 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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    The @Anatomical Record 128 (1957), S. 213-221 
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    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
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