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  • 1995-1999
  • 1970-1974  (2,024)
  • 1970  (2,024)
  • Polymer and Materials Science  (1,970)
  • Engineering  (54)
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  • 1995-1999
  • 1970-1974  (2,024)
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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 811-824 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The root-mean-square end-to-end distance has been calculated for a model allowing free rotation about glycoside bonds for the general case of polysaccharides having a disaccharide repeating unit. Numerical estimates are given for several naturally occurring structures based on an idealized pyranose unit in the C1 chair conformation. Extrapolation procedures which make use of the intrinsic viscosity [η] in good solvents to obtain unperturbed dimensions do not represent, data for hyaluronic acid very well, especially at low molecular weights. However, order-of-magnitude estimates suggest that this polymer behaves similarly to other polysaccharides, and probably has stiffer local structure than typical non-ionic synthetic polymers. A double logarithmic plot of the product of [η] and M̄w, the weight-average molecular weight, against the degree of polymerization in the range for M̄w of 104 to 2 × 104 permits a straight-line fit of available data for all the glycosaminoglycans, including heparin and the chondroitin sulfates, as well as sodium carboxymethyl cellulose. This result suggests similarity of short-chain hydrodynamic behavior of these polymers.
    Additional Material: 4 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 875-875 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970) 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 865-874 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A common approximation for deriving solutions to the Lamm equation is to neglect diffusion. This paper presents a singular perturbation technique that allows one to estimate the band spreading due to nonzero diffusion coefficient. We illustrate the general mathematical technique by its application to sedimentation when pressure effects are important. Comparison of the approximate solution with accurate numerical solutions shows that the relative errors are of the order of 1% both for concentration and concentration gradient for parameters of chemical interest.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 891-896 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Glycogen acquires a negative charge in both alkaline and acidic solutions and can move in an electrical field, its mobility being related to the degree of alkalinity or acidity. There is a slight increase in relative viscosity at both ends of the pH spectrum. These effects and the changes in nuclear magnetic resonance as a function of pH are interpreted.
    Additional Material: 3 Tab.
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  • 6
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The viscosity of bovine liver glutamate dehydrogenase solutions was studied at 10 and 20° C in 0.2.M sodium phosphate buffer at pH 7, in the concentration range 0.1-8 mg/ml. A method for the study of the viscosity of very dilute solutions of associating enzymes is described. It was found that the reduced specific viscosity ηsp/c of glutamate dehydrogenase continuously increases with increasing enzyme concentration, from about 4 ml/g at the lowest concentrations to about 16 ml/g at 8 mg/ml. In the presence of 10-3M GTP and 10-3M NADH the viscosity increase is much smaller and the results can be extrapolated to zero enzyme concentration to yield an intrinsic viscosity [η] = 3.2. The values of ηsp/c in phosphate buffer alone apparently extrapolate to the same value of [η], or to a value close to it. We also observe that, in the presence of toluene ηsp/c increases very much more with enzyme concentration: ηsp/c already equals 16 ml/g at a concentration of 0.75 mg/ml. These observations are in good agreement with the hypothesis that the active oligomer of glutamate dehydrogenase (MW = 312,000) associates with increasing enzyme concentration to form linear rodlike polymers of indefinite length. This association is strongly diminished by the addition of 10-3M GTP, 10-3M NADH. Toluene, on the other hand, promotes reversible association to linear polymers of very high molecular weight. The transverse and axial rotary frictional coefficients of macroscopic bodies, similar to a physical model for the structure of glutamate dehydrogenase recently advanced, were determined. Assuming that the viscosity of the model is equal to that of an ellipsoid of rotation with identical frictional coefficients, we calculate [η] = 3.26 ml/g according to Kuhn and 3.20 ml/g according to Simha, for the glutamate dehydrogenase oligomer, in good agreement with the result derived from the study of enzyme solutions.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 911-922 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Molecular monolaycrs of poly(β-benzyl L-aspartate) spread at. an air-water interface have been studied. The results obtained both by direct observations on the monlayer and from examination of collapsed films with polarized infrared spectroscopy and electron diffraction are consistent with the presence of right handed α-helices in the mono-layer when the molecular weight is high. When 1% (v/v) isopropanol is present in the subphase the right-handed helix prevails, provided that the monolayer is first spread on water. Monolayers of low molecular weight polymer appear to form the crossed-β structure. Orientated collapsed films of high molecular weight polymer can be converted to the left-handed α-helical and to the ω-conformation, and the mechanisms are discussed. The surface chemistry of this polymer is compared with that of related polymers and a consistent pattern of behavior emerges.
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1017-1028 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Low-angle light scattering results reported previously demonstrated that measurements on high molecular weight native DNA must be made at angles below 30° in order to obtain correct molecular weights. Earlier light-scattering data obtained on denaturated DNA at angles above 30° showed no change in molecular weight upon denaturation, even though other techniques clearly showed that strand separation occurred. This paper reports low-angle measurements on solutions of calf thymus and T7 DNA denatured under acidic conditions. The results demonstrate that a halving of molecular weight consistent with strand separation is detected by light scattering only when low-angle data are used to obtain correct molecular weights for native material. As expected from theoretical considerations, the scattering from denatured DNA is a linear function of sin2(θ/2), where θ is the angle of observation. This result shows that anticipated experimental artifacts have no significant effect on the low-angle measurements and demonstrates that the curvature in the scattering envelope observed for native DNA below 30° is an inherent property of the native molecule.
    Additional Material: 4 Ill.
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  • 9
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The kinetics for the cis-trans isomerization of long-chain poly-L-proline has been studied as a function of pressure, temperature, and solvent composition in the acetic acid + n-propanol solvent system. Our complete kinetic curves were fitted by Monte Carlo techniques, and rate constants for nucleation, growth, and termination were estimated. It was found that for the formation of a cis-helix, high pressure, low temperature, and increased acetic acid content of the solvent, lowered the rate of nucleation relative to growth. The inverse seems to be t rue for the formation of a trans-helix. Molecular models suggest that this behavior of the kinetic constants can be due to the exposure of peptide units to solvent in the transition state for trans nucleation, and the burying of peptide units in the transition state for cis nucleation. It is further suggested from our analysis of complete kinetic curves that at least one of the assumptions usually made in the analysis of relaxation kinetics is invalid for poly-L-proline.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1039-1047 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Solutions of amylose in ethylenediamine yield a crystalline film complex upon evaporation of solvent. The x-ray analysis indicates the presence of a tetragonal-shaped cell with a symmetry approximating that of space group P212121. The amylose sixfold helix has a diameter of 13.3 Å and a translation period of 8.0Å. Chemical and physical analyses support a complexing ratio of one ethylenediamine molecule to every two glucose units. The structure is nearly identical to any amylose-dimethyl sulfoxide complex previously examined. The square mode of packing arrangement appears to result from complexation between amylose chains. Such complexing indicates a much greater degree of amylose interaction than is observed in amylose complex structures having a hexagonal close-packing arrangement.
    Additional Material: 1 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1049-1058 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: pH titration measurements of poly- S-carboxymethyl-L-cysteine were undertaken in the aqueous Nacl solution in relation to the β form-random coil transition. The titration curves show a marked molecular weight dependence because of the shortened chain length of materials. Comparison of the optical rotatory dispersion parameter a0 with the titration curve reveals that the titration curve apparently reflects a β structure-random coil transition. The β form of this polymer is assumed to be an intramolecular β form, rather than a β structure stabilized by an intermolecular hydrogen bond, at least in the polymer concentration range considered here. The standard free energy change per amino acid residue for the transition from un-ionized random coil to un-ionized β form is estimated to be about -750 cal/mole residue in the range of 0.005-0.2M NaCl concentration.
    Additional Material: 4 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1059-1077 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The circular dichroism (CD) spectra of the four usual deoxymononucleosides, all sixteen deoxydinucleotides, and a number of trinucleotides have been measured. The dimer spectra are quite different from the sum of the spectra of their constituent monomers. This indicates the presence of base-stacked conformations analogous to those found for ribonucleoside diphosphates. The CD spectra of several deoxytrinucleotide diphosphates and single-strand f 1 DNA can be calculated fairly well by using a semi-empirical nearest-neighbor approach. There is little or no effect of terminal phosphate or of salt concentration on the optical properties of most deoxy oligomers. The possibility of simultaneous analysis of mixtures of deoxypurine or deoxypyrimidine sequence isomers has been examined. This seems to be a viable approach for the analysis of purine runs but cannot promise much success for pyrimidine runs.
    Additional Material: 7 Ill.
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  • 13
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1079-1103 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The circular dichroism spectra of all 16 ribodinudeoside phosphates containing the bases adenine, uracil, cytosine, and guanine have been measured at room temperature and neutral pH. These results are compared with the circular dichroism spectra of the corresponding deoxy compounds. From the optical properties it is clear that the geometry of the base-stacked conformation of ribo compounds must differ substantially from that of deoxy compounds. Because of this, it is not possible to draw firm conclusions about the relative extent of stacking in most ribo and deoxy compounds. The optical rotatory dispersion of about a dozen deoxy and ribodinucleoside phosphates has been studied as a function of temperature. These results confirmed the conclusions drawn earlier from measurements at a single temperature. Several dinucleoside phosphates containing a 2′ → 5′ phosphodiester bond have also been examined. These compounds have a substantial degree of base stacking at room temperature. The geometry of the stacked conformation is different from that of either the normal ribo dimer or the deoxy dimer. The role of the 2′-hydroxyl group in stabilizing base stacked geometries has been examined by studies on C-2′-O-methyl-pC. This compound has optical properties almost identical to those of CpC. This suggests that the effect of the 2′ hydroxyl is felt indirectly through its perturbation of the geometry of the sugar ring rather than directly by hydrogen bonding. It is not possible at present to identify precise conformational differences among deoxy-, ribo-and 2′ → 5′ ribodinucleoside phosphates.
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  • 14
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1119-1124 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1349-1360 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The influence of single-strand breaks on the kinetics of the relaxation of DNA in a solution of low ionic strength has been investigated by a temperature jump method. The relaxation of DNA after a jump of 0.7 °C in the melting region has been monitored by measuring the extinction at 260 nm. For essentially monodisperse T4 DNA (M = 130 × 106) two distinct relaxation times have been observed, that depend markedly on the initial extent of denaturation 1 - θ. The larger relaxation time decreases from 450 sec to about 300 sec, the smaller one from 55 see to 30 when 1 - θ increases from 0.03 to about 0.8. The dependence of these relaxation times on the average number of single-strand breaks per molecule (p) appears to be very small up to p = 100. However, the relative contribution of the slow process decreases sharply when p increases from 0.6 to 30 and remains nearly constant for larger p. The observations are discussed in the light recent theories of the kinetics of denaturation.
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  • 16
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1361-1372 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Measurements have been made of the intensity of light scattered from aqueous solutions of calf thymus DNA with and without the application of electric fields. For fields approaching 150 V/cm and frequencies below 2.5 KHz, changes (ΔI) of up to 10% in the residual scattered intensity were observed. In agreement with previous dielectric and electric birefringence measurements, a low frequency dispersion of ΔI was observed, from which a rotary diffusion constant (D) of 1200 s-1 was determined. Interpreting the electric field data in terms of the classical dipolar orientation theory led to values of 2.4 × 10-25 cm (7.4 × 10-14 esu) and 4.3 × 10-25 cm (13 × 10-14 esu) for the permanent dipole moment and the anisotropy of the electric polarisabilities respectively. Furthermore the permanent dipole moment was along the major molecular axis and the particles orientated in the field as rigid entities. The zero field data indicated a molecular shape which was not rodlike but corresponded to the Kratky-Porod “stiffness” parameter of x = 24 for the wormlike coil model. Although curved, the molecules appeared to orientate in low-intensity electric fields as rigid, but not rodlike molecules. The implications of this on recent discrepancies in D determined by two or more dynamic relaxation methods is briefly discussed.
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  • 17
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1391-1402 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The buoyant density of T-4 DNA was determined by equilibrium sedimentation in a density gradient, of mixed solutions of cesium and magnesium chlorides and bromides. The preferential hydration was calculated from these data, allowing appropriately for the exchange equilibrium of DNA with Cs+ and Mg++ ions. The charge and intrinsic solvation of the counterions were found to have no appreciable effect on the hydration of the DNA, the extent of solvation depending only on the thermodynamic, activity of the water. Various reasonable hypotheses are discussed to account for these results.
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  • 18
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 1373-1389 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reaction of 27 SMS2 RNA with formaldehyde normally results in an unfolded, 13.4 S form. At acidic pH, however, and under the proper ionic conditions, a compact component sedimenting at 36-40 S was obtained. The molecular weight of this species corresponds to a dinner. The formaldehyde concentration was not critical, and approximately the same number of base pairs had been opened in the compact and in the unfolded form. Presumably dimers, which had been specifically formed under defined conditions, were stabilized by formaldehyde-induced crosslinks. Similar dimers were formed by 16 S and by 23 S ribosomal RNA, but not by tRNA.
    Additional Material: 7 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 445-457 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The change in apparent molal volume φ of DNA on thermal denaturation in carbonate buffer at pH 11.0 has been determined by the dilatometric method. It was found that φ increases sigmoidally during the helix-coil transition. Several methods, including a colorimetric technique that closely simulates the conditions used in the dilatometric experiments, were employed to estimate the protons lost by the DNA during the transition. These measurements indicated that the extent of the proton loss depends on the counterion present, increasing in the order Li+ 〈 Na+ 〈 K+ 〈 Cs+. The major part of the volume changes observed during the denaturation is due to the volume changes expected to accompany the transfer of protons from the bases guanine and thym ne to carbonate ions. As has been previously reported for the denaturation of DNA at neutral pH, the volume change directly due to the change in shape of the polymer molecules is so small as to be experimentally undetectable.
    Additional Material: 7 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 569-588 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The coupling of theoretical optical calculations with experimental data provides a check of the validity of the theory or provides conformational information. The theory was validated by studies in which the approximate conformation was located independently. These studies have shown that a theory restricted to the two lowest energy transitions for each chromophore gives qualitative agreement with experiment. On the other hand, for some of the proline derivatives, the theoretical treatment allows detailed conformational assignments. Both successes and failures in correlating theory with experiment are discussed. The results presented provide a basis for assessing the prospects for relating protein and polypeptide optical activity to their conformations.
    Additional Material: 8 Ill.
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  • 21
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ethidium bromide inhibits the formation of ultraviolet-induced pyrimidine dimers in DNA. The efficiency of dimer inhibition increases with increasing energy of the exciting photons. The efficiency of energy transfer from the DNA singlet to the dye singlet, as monitored by sensitized fluorescence, is independent of wavelength. The efficiency of singlet-singlet transfer agrees with that for dimer inhibition at photon energies corresponding to excitation of the lowest singlet state of DNA. Our results support a model in which dimers are formed both directly from the singlet state and also from the triplet state, with triplets arising from higher vibrational levels of the singlet.
    Additional Material: 7 Ill.
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  • 22
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 689-696 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The intercalation model of DNA-hydrocarbon binding appears reasonable, but rests on indirect evidence only. To test the model, a size criterion for binding has been proposed. The size criterion is based on the assumption that hydrophobic forces play a major role in the binding of hydrocarbons to DNA. It states that hydrocarbons which are small enough to intercalate into DNA and be well protected from contact with the medium, will be found to bind to DNA; those that are too large will not. We report results on the binding of fourteen polycyclic aromatic hydrocarbons to DNA. Predictions based on the size criterion were found to be valid in all cases tested.
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  • 23
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 697-715 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The dialysis data of Huang and Ts'o for the cooperative binding of adensine to polyuridylic acid are analyzed here using a grand-partition function Ising model method similar to that originally employed for polyelectrolytes by Rice and Nagasawa. An appropriate modification permitting the treatment of the sliding degeneracy of the two polyuridylic acid strands is also included. In addition to the previously estimated stacking energy of about -6 kcal/mole one also obtains the free energy change F̄ for the transfer of a single adenosine molecule from a fixed site in solution to a fixed site on the polyuridylic acid. This binding energy falls in the range F̄ = -140 to +620 cal/mole, indicating that binding in the 1:2 (purine: pyrimidine) complex is either very weak or repulsive. The absence of any comparable cooperative stacking of adenosines in solution at the same concentration together with the likely repulsive character of the binding implies that the stacking energy must contain a significant contribution from other processes than simple stacking of adenosines. A generalization of the theory to treat multicomponent binding and longer-range interactions is effected, and the form applicable to simultaneous binding of both adenosine and guanosine by polyuridylic acid is presented.
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  • 24
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 739-744 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The present communication describes a new way of studying helix-random coil transformations of polypeptide, poly-(γ-benzyl L-glutamate), in benzene-trifluoracetic acid (TFA) and chloroform-TFA systems. The difference between the PMR chemical shift of TFA with and without the polypeptide, measured as Δ, may be used to follow the conformational transition. This technique is particularly useful for concentrated solutions, where the PMR peaks of the polymer are so broad that no valuable information may be derived. As the TFA content increases in the system (at constant polymer concentration), Δ decreases normally whether the polymer is helical or random. However, Δ changes in a different way in the helix-random coil transition region, and actually increases with increasing TFA content. This peculiar behavior is explained in terms of the solvation of the helix and random coil structures.
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  • 25
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 745-748 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 26
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 717-738 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new procedure for evaluating u and σ characterizing σ-helix-forming polypeptides in solution was derived from Nagai's theory for the helix-coil transition of such polymers. Here u is the activity for helix formation from random coil, and σ is the helix initiation parameter. The necessary data are the helical content fN at fixed solvent and temperature as a function of N, where N is the degree of polymerization of the polypeptide sample. Such data were obtained from ORD measurements on a number of fractionated samples of poly-N5-(3-hydroxypropyl)-L-glutamine (PHPG) in mixtures of water and methanol covering the complete range of composition and at various termperatures (5-40°C). When analyzed in terms of the proposed procedure, they yielded values of σ which were in the range (3.2 ± 0.6) × 10-4, substantially independent of solvent composition and temperature. These values were much larger than those obtained recently for σ of poly(β-benzyl-L-aspartate) in m-cresol and in a mixture of chloroform and DCA. The data for [η] and s0 (limiting sedimentation coefficient) as functions of molecular weight indicated that the molecular shape of PHPG in pure methanol is essentially rodlike, whereas that in pure water is not entirely randomly coiled but rather may be regarded as an interrupted helix. These indications were consistent with the results from ORD measurements. When plotted against the corresponding values of fN, the values of [η] and [s0] for PHPG in mixtures of water and methanol of various compositions and temperatures formed smooth composite curves, and we attributed these phenomena to the fact that σ of PHPG was nearly constant under these solvent conditions. Here [s0] stands for a reduced limiting sedimentation coefficient which is equal to the inverse friction factor of the solute molecule.
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  • 27
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    New York : Wiley-Blackwell
    Biopolymers 9 (1970) 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 28
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    New York : Wiley-Blackwell
    Biopolymers 9 (1970), S. 765-782 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The interaction of purine with DNA, tRNA, poly A, poly C, and poly A. poly U complex was investigated. In the presence of purine, the nucleic acids in coil form (such as denatured DNA, poly A and poly C in neutral solutions, or tRNA) have lower optical rotations. In addition, hydrodynamic studies indicate that in purine solutions the denatured DNA has a higher viscosity and a decreased sedimentation coefficient. These findings indicate that through interaction with purine, the bases along the poly-nucleotide chain are unstacked and are separated farther from each other, resulting in increased assymmetry (and possibly volume) of the whole polymer. Thus, the de-naturation effect of purine reported previously can be explained by this preferential interaction of purine with the bases of nucleic acids in coil form through a hydrophobic-costacking mechanism. Results from studies on optical rotation and helix-coil transition show that the interaction of purine is greater with poly A than with poly C. The influence of temperature, Mg++ concentration, ionic strength, and purine concentration on the effect of purine on nucleic acid conformation has also been investigated. In all these situations the unraveling of nucleic acid conformation occurs at much lower temperatures (20-40°C lower) in the presence of purine (0.2-0.6M).
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  • 29
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The characteristic ratio of unperturbed cellulose chain was computed as a function of the angle τ at, the bridge oxygen atom and the degree of polymerization. Very high values of the order of 40 or more, depending on the angle at the bridge oxygen atom, have been obtained for this ratio, indicating that cellulose chains are highly extended. The average dimensions of cellulose chains are found to be sensitive even for small changes in the angle at the bridge oxygen, and these chains attain the character of a random coil in very high molecular weight range (degree of polymerization greater than 2000). The large differences in the unperturbed dimensions of cellulosic chains observed in different solvents have been attributed to the possible small changes in the angle τ caused by specific solvent, interactions.
    Additional Material: 5 Ill.
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  • 30
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The conformational properties of block copolymers of poly-L-leucine in water have been examined. The degree of polymerization of the poly-L-leucine block was 11 and 21, respectively, for samples prepared by the Merrifield procedure, and 56 for a sample prepared by the polymerization of leucine N-carboxyanhydride. The optical rotatory dispersion parameter b0 was used to obtain the helix content θh at various temperatures. Application of the Lifson-Roig theory gave the following parameters for the transition of a residue from a coil to a helical state: v = 0.05-0.011, ΔH = +100 cal/mole, ΔS = +0.70-1.00 e. u. These parameters, as well as those for other polyamino acids, are accounted for by hydrophobic bonds involving the nonpolar side chains in the helical and randomly coiled forms. From the data for poly-L-alanine and theoretical values of the thermodynamic parameters for hydrophobic bond formation, the parameters for formation of a polyglycine helix are computed. By separating the contributions of the backbone, it is possible to obtain a set of thermodynamic parameters for the side-chain contributions of a number of polyamino acids. Increased size of the nonpolar side chain (with a larger contribution from hydrophobic bonding) makes a larger contribution to the stability of the α-helix which is reflected, among other ways, in a higher helix content at given temperature.
    Additional Material: 7 Ill.
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  • 31
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polymerization of DL-β-phenylalanine N-carboxyanhydride (NCA) initiated by poly(N-benzylglycine)diethylamide (DEA) and poly(N-methyl-DL-alanine)DEA has been investigated. As previously reported, polysarcosine DEA, poly-N-ethylglycine DEA, and poly-N-n-propylglycine DEA showed marked accelerations in the polymerization of DL-β-phenylalanine NCA as compared with the polymerization initiated by low molecular weight, amines having similar base strength. However, this phenomenon (the chain effect) was not observed with the two polymer catalysts studied in the present investigation With poly-N-methyl-DL-alanine DEA, adsorption of DL-β-phenylalanine NCA onto the polymer chain takes place, though not so effectively as with other polypeptides, so the absence of chain effect was ascribed to a reduced flexibility of the polymer chain. With poly(N-benzylglycine)DEA, the reactivity of terminal base group was found to be much lower than that of other polymer catalysts. However, the absence of the chain effect would be attributed to the rigidity of polymer chain of poly-N-benzylglycine DEA due to the bulkiness of the N-benzyl group.
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  • 32
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    Biopolymers 9 (1970), S. 799-810 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Molecular weights by osmometry (M̄n), light scattering (M̄w), and sedimentation-diffusion (MsD) were determined for selected fractions and unfractionated samples of hyaluronic acid in the molecular weight range 3 × 104-1.7 × 106. For the determination of MsD from the sedimentation coefficient s, a calibration procedure based on the data of Laurent, Ryan, and Pietruszkiewicz gave the following relations in 0.2M NaCl: log (s-1)0 = 14.681 - 0.413 log MsD and log D0 = -3.828 - 0.568 log MsD, where subscript, zero refers to zero concentration and D is the diffusion coefficient. The average Mandelkern-Flory parameter β in 0.2M NaCl is 3.0 × 106. Data for the intrinsic viscosity [η] may be fitted for M 〉 105 by [η] = K′Ma, where K′, a are in 0.2M NaCl, 0.0228, 0.816; in 0.5M NaCl, 0.0318, 0.777; in 0.1 M HCl, 0.0279, 0.763, respectively. Below M = 105, [η] appears to fall below the values calculated, possibly due to non-Gaussian behavior of short chains. The second virial coefficient A2 in 0.5M NaCl approaches the ideal Donnan value, decreasing slightly with increasing molecular weight. The friction parameter P is about 20% smaller than that of uncharged polymers of similar dimensions. The flexible coiling nature of this polymer is confirmed.
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  • 33
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    Biopolymers 9 (1970), S. 843-864 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The formation of a slowly sedimenting form of 23-S ribosomal RNA from E. coli has been investigated by analytical ultracentrifugation and thermal denaturation in aqueous solution and in formamide. Evidence is presented that the slow form of 23-S arises as a result of nucleate damage to the RNA in the 50-S ribosome. The 30-S ribosome (and 16-S RNA), is unaffected. The slow form of 23-S RNA cannot be demonstrated under conditions of complete denaturation in formamide, but only by partial denaturation in aqueous solution of low ionic strength (〈 0.01M Na). Apparent maintenance of the integrity of 23-S RNA in formamide after nuclease treatment suggests that this may not be a simple linear molecule. An alternative model is suggested containing a circular element in the structure.
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  • 34
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    Biopolymers 9 (1970), S. 825-842 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Uniform LiDNA fiber specimens of nearly 20 m length have been prepared with a wet-spinning method developed by the author. Samples immersed in the spinning bath (80% ethyl alcohol containing 0.4M LiCl) have been subjected to mechanochemical study involving stretching, relaxation, and contraction measurements. A special technique was developed to transfer the sample from the Teflon-coated cylinder used in spinning to the sample column of the mechanochemical apparatus without stretching or removing the sample from the spinning bath. Force-strain curves of samples consisting of two fiber bundles showed an initial region of low slope followed by a region of high slope and a second region of low slope up to rupture. Some thicker specimens showed an aging effect which abolished the initial low-slope region and was interpreted as indicative of crystallization. Force-strain curves of two-bundle samples showed a strong influence of temperature with a complete loss of tensile strength of the LiDNA fibers in the spinning bath at about 55°C. Furthermore, samples at zero strain exhibited a contractile force when subjected to temperatures above about 40°C; the contractile process was pronounced with samples kept above 48°C. On contraction these samples obtained a zero-force length 20-30% of the original. These data are taken as evidence for a helix-to-coil transition occurring in the DNA, the low melting temperature being caused by the chemical influence of the ambient aqueous alcohol-LiCl bath.
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  • 35
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    Biopolymers 9 (1970), S. 1029-1038 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The molecular weight of native DNA is shown to decrease by at least a factor of two on denaturation by heat or alkali. This result is obtained only if low-angle (〈30°) light-scattering measurements are used. High-angle measurements (〉30°) do not reveal a decrease in molecular weight on denaturation due to the incorrect value for native DNA. The dn/dc value for both native and denatured DNA is 0.166 ml/g ± 0.003 ml/g. Methods are described for the clarification of native and denatured DNA solutions for light scattering by the use of membrane filters.
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  • 36
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    Biopolymers 9 (1970), S. 991-1000 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Electric dichroism studies on poly(γ-benxyl L-glutamate) show that the addition of small amounts (up to 5%) of trifluoroacetic acid causes complete disappearance of dichroism in contrast to the electric birefringence, which drops to an observable plateau at 20% of its initial value. This loss of dichroism cannot be explained simply by a decrease in the effective dipole moment of the benzyl ester side chains, and the nature of this interaction is explored by nuclear magnetic resonance and infrared spectral studies. Theories of the helix-coil transition which require an initial protonation of the helix backbone to form a more flexible rod consisting of helical segments interrupted by regions of random coil are shown to be inadequate to describe the changes in poly(γ-benzyl L-glutamate) effected by small amounts of trifluoroacetic acid. Rather, trifluoroacetic acid in small amounts interacts with the ester carbonyl oxygen in the side chain, either by hydrogen bonding or protonation, before there is evidence of any effect on the backbone or of loss of helix content.
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  • 37
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    Biopolymers 9 (1970), S. 1229-1237 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Raman spectra of poly-L-lysine hydrochloride and poly-∊-carbobenzoxy-L-lysine in the solid state have been obtained and are consistent with the presence of an α-helical structure. The Raman spectrum of poly-L-lysine in aqueous solution suggests the presence of random coil structures.
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  • 38
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 39
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    Biopolymers 9 (1970) 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 40
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The nonbonded interaction energy of disaccharides, mannobiose and galactobiose and polysaccharides mannan and galactan have been computed as a function of dihedral angles (φ,ψ). The conformation (40°, -20°) has been preferred for the mannan chain from nonbonded interaction energy considerations. The O5…O3′ type of intramolecular hydrogen bond has been found to be possible in the above conformation. Comparison of the allowed region of mannan with those of cellulose and xylan indicates that the monomer unit, in mannan chain has slightly higher freedom of rotation than that of cellulose and less than that of xylan. As in cellulose and mannan, the freedom of rotation of the monomer units in β-1,4′ galactan is highly restricted. Unlike mannan (which prefers an extended conformation) the β-1,4′ galactan prefers a helical conformation similar to amylose. Just as in amylose the O2…O3′ type hydrogen bond between contiguous residues is also possible in β-1,4′ galactan.
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  • 41
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 23 Ill.
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  • 42
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    Biopolymers 9 (1970), S. 1475-1502 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The predictions of the presently accepted molecular exciton model for the optical activity of helical polypeptides are in reasonable agreement with experimental spectra in the accessible wavelength range. However, crucial verification requires the detect of a significant negative rotatory hand just below the accessible range. A computer-oriented method is utilized to obtain information concerning the inaccessible range. Optical rotatory dispersion computed by evaluation of the Kronig-Kramers integral transform from the experimentally determined circular dichroism of several helical homopolypeptides in solution are compared with the experimentally determined optical rotatory dispersion. Computed and experimental curves are congruent within an uncertainty approaching that of the experimental technique, whatever the polypeptide sample lot, side chains, and solvent. It is shown that t his agreement is not a computational or experimental artifact. These results can be interpreted in two ways: (1) that the predicted band does not exist, and (2) that the perturbation of the predicted band is being negated by other inaccessible bands in the vacuum ultraviolet. Arguments are presented to show that the first of these two possibilities is more probable.
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  • 43
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    Biopolymers 9 (1970), S. 1511-1530 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The potential problem is formulated for rodlike macroions and reduced to a single dimensionless equation with appropriate boundary conditions. A method of solution based on piecewise linearization of the potential equation is detailed and compared with two other approaches. It is suggested that the present method yields improved estimates of macroion charges. Some numerical results are included, and the relation between electrophoretic charge and macroion charge is considered.
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  • 44
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    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 45
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 3-3 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 46
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 2-2 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 47
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 5-32 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The program given here assembles and solves symmetric positive-definite equations as met in finite element applications. The technique is more involved than the standard band-matrix algorithms, but it is more efficient in the important case when two-dimensional or three-dimensional elements have other than corner nodes. Artifices are included to improve efficiency when there are many right hand sides, as in automated design. The organization of the program is described with reference to diagrams, full notation, specimen input data and supplementary comments on the ASA FORTRAN print-out.
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  • 48
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 33-43 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In the design of a guyed mast the design specification often imposes limits on the allowable deflection of the mast under wind and other lateral loads. While the deflected form of a mast depends on many different design parameters, the guy erection tensions form one of the simplest means of controlling the lateral displacements. The paper describes a procedure for calculating these tensions in the case of a mast required to have a specified set of displacements under a given set of lateral loads. It also discusses the case where specified deflections are not to be exceeded under a number of different loading conditions.
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  • 49
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 45-59 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper is concerned with the development of a computational algorithm for the solution of the uncoupled, quasi-static boundary value problem for a linear viscoelastic solid undergoing thermal and mechanical deformation. The method evolves from a finite element discretization of a stationary value problem, leading to the solution of a system of linear integral equations determining the motion of the solid. An illustrative example is included.
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  • 50
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 61-71 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The transient field problem of the type encountered in heat conduction problems is formulated in terms of the finite element process using the Galerkin approach. Curved two-dimensional and three-dimensional, isoparametric elements are used in a time-stepping solution and their advantages illustrated by means of several examples.
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  • 51
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The proposed finite element model is based on separate assumptions of interior and interelement displacements and on the assumed boundary tractions of each individual element. The associated variational functional for this model is presented. This method has the same merits of the assumed stress method (References 3 and 4) in that a compatible displacement function at the interelement boundary can be easily constructed, while it can easily be used for shells with distributed loads.
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  • 52
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 117-131 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method for the analysis of field problems is described. The algorithm is based upon the generalized Betti-Maxwell theorem. Using a set of known solutions to problems with similar boundary conditions produces a set of ‘integral’ equations for the required solution. Using any convenient numerical integration formula reduces the problem to the solution of a set of simultaneous algebraic equations. The accuracy of the solution depends upon the accuracy of the integration formula as applied to the problem under consideration and is independent of the known auxiliary solutions. The method is described in detail as applied to harmonic problems.
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  • 53
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 85-98 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Considerable attention has been devoted in the literature on numerical methods towards securing energy convergence of solutions for, say, linearly elastic plate bending problems. Although energy convergence is necessary it by no means follows that the derived bending moments and shearing forces converge uniformly at a given point and it is this kind of feature which the engineer is really seeking.This question is examined in the context of a problem which is of particular interest to the civil engineering field and concerns the bending of a square plate under uniformly distributed load; the plate has simply supported edges and contains a central square hole with free edges. The solution to this multiply connected and mixed boundary value problem is obtained through a recently developed modification to the Rayleigh-Ritz method which has very general application and renders the solution mathematically valid up to the internal corner points where the bending moments are singular. Use is made of triangular equilibrium finite elements in conjunction with continuous eigenfunctions. Although it is already known that the order (i.e. the eigenvalue) of the singularity at the internal corners is available by inspection, it is an interesting feature of the present solution that a good approximation to the amplitude is also obtained by an inspection of the finite element results.
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  • 54
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 99-116 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The convergence rates of eigenvalue solutions using two finite plate bending elements are studied. The elements considered are the well-known 12 degree of freedom, non-conforming rectangular element and the 16 degree of freedom, conforming rectangular element. Three problems are analysed, a square plate simply supported on two opposite sides with the other two sides clamped, simply supported, or free. Closed form, finite element solutions for these problems are obtained by using shifting E-operators.With few exceptions, eigenvalue solutions found with the non-conforming element converge from below the exact answers at an asymptotic rate of n-2, where n is the number of elements on a side. However, since the array size needed for such convergence is very large, little can be said about the convergence rates for practical arrays. The conforming element solutions converge from above at an asymptotic rate of n-4. A comparison of the errors involved in using these two elements shows that the conforming element is far superior to the non-conforming element.
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  • 55
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 145-146 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 56
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    International Journal for Numerical Methods in Engineering 2 (1970) 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 57
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 146-147 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
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  • 58
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 133-144 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper presents a labour-saving method of discretizing irregular and inhomogeneous two-dimensional continua into triangular elements. The method uses a magnetic pen to record node point data and a computer program to generate element data. This technique eliminates the tedium in the manual generation of data and the delay due to mistakes which would otherwise arise frequently for a complex mesh.
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  • 59
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 151-157 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A finite element formulation which includes the piezoelectric or electroelastic effect is given. A strong analogy is exhibited between electric and elastic variables, and a ‘stiffness’ finite element method is deduced. The dynamical matrix equation of electroelasticity is formulated and found to be reducible in form to the well-known equation of structural dynamics, A tetrahedral finite element is presented, implementing the theorem for application to problems of three-dimensional electroelasticity.
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  • 60
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 175-188 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical method is presented for the solution of the radially symmetric heat conduction problem in a melting sphere. The method employs the embedding technique; this permits the solution to be written in the form of an ordinary integro-differential equation which is readily solved numerically by means of a forward integration scheme. The accuracy of the method is briefly discussed and numerical results for both constant and variable heat inputs are presented.
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  • 61
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 159-174 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper is concerned with the development of general discrete models for the analysis of boundary-value problems in the first strain-gradient theory of elasticity. Extensions of the finite element method are constructed for this purpose, and general equations of motion are derived for finite elements of a class of micro-polar materials which are characterized by strain energy functions involving strains and second gradients of strains or displacements. The notion of generalized nodal doublets is introduced. The problem of a composite consisting of a strain-gradient sensitive microlayer embedded between semi-infinite bodies is examined as an example problem. Some of the results are compared with available exact solutions.
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  • 62
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Methods for the analysis of complex, highly redundant structures subjected to intermittent loads causing biaxial membrane stress and stress reversal into the plastic range are presented. The Bauschinger effect in multi-axial stress is taken into account by the use of Ziegler's modification of Pragers kinematic hardening theory. The implementation of this plasticity theory in the discrete element methods involves the application of the loading in small increments. A linear relationship between increments of plastic strain and of stress, arising out of the theory, is used in conjunction with a linear matrix equation that governs the elastic behaviour of the structure. In the latter equation, plastic strains are interpreted as initial strains. A solution to the linear matrix equation, expressed in terms either of stress or of total strain, may be obtained by utilizing one of two alternative procedures. The methods are capable of treating materials which exhibit elastic-plastic behaviour involving ideal plasticity, linear or non-linear strain hardening, or limited strain hardening. Application is made to several representative structures. Comparison of some of the results with existing test data for both monotonic and reversed loading shows good correlation.
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  • 63
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 221-228 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A general digital computer method based on a Sturm sequence procedure is described for determining the natural frequencies and associated modes of undamped free vibration of frames and other structures whose stiffness and mass matrices are of band form. A program which uses the method for the analysis of plane multi-storey building frames is outlined, and numerical results are presented for a simple test case and for a 19-storey frame.
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  • 64
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 207-219 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A newly developed numerical Laplace transform inversion technique is described. A derivation of the method, termed the ‘multidata method’, is presented along with a description of a similar collocation method. Similarities and differences between the two numerical methods are described and discussed. Results of parameter studies of both methods are presented which demonstrate the sensitivity to error displayed by the collocation method and the magnitude of the improvement in accuracy obtainable with the multidata method as compared with the collocation method, especially when errors exist in the function to be inverted.
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  • 65
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 229-241 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In this study, finite element solution procedures are developed for an elastica problem of inextensible beams. The element stiffness matrices are obtained by using Galerkin's method. Results of a numerical example compare reasonably well with those obtained by using the elliptical integral.Extensions of this research are currently being made to include membrane effects of beams and to develop plate element stiffness matrices for elastica problems of plate structures.
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  • 66
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 243-252 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This report summarizes an experimental application of the finite element approach to two-dimensional inviscid fluid flow.The method results in a matrix equation relating the vector of velocities at the nodal points with the vector of singularities. The singularities, which are concentrated at the nodes, consist of a source and a vortex.On solution of this equation (defining the flow in the region), boundary conditions must te stipulated. This usually involves setting the internal singularities to zero and making certain modifications ro those lying on the boundary of the region.Some results of the application to a particular problem are included in the paper.
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  • 67
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 253-257 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Some typical results of an extensive series of evaluations of parallelogram-shaped plate bending elements with increasing levels of sophistication are presented. It is shown that, contrary to experience in other fields of stress analysis, this sophistication does not lead to striking improvements in accuracy in the solution of simple rectangular and skew plate problems. A computational procedure is described whereby stiffness matrices may be automatically generated from the minimum of input data specifying the displacement modes prescribed for the element.
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  • 68
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 259-264 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A conforming plate bending solution using simple polynomial deflection functions of third-degree inside each triangular element is presented. In order to avoid normal slope discontinuities along the sides of the elements, the plate displacement parameters are subjected to ‘slope continuity conditions’ acting as constraints to the minimum potential energy problem. This is then solved by the classical method of Lagrange introducing multipliers as new auxiliary variables. If a special variational formulation of the problem is used, it can be shown that the Lagrangean multipliers are generalized stress parameters. The suggested solution is therefore basically a ‘mixed’ solution, the unknown variables of the problem being both displacement and stress parameters. Several numerical results are presented.
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  • 69
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 265-275 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Approximate formulations of non-uniform beam element stiffness matrices for dynamic and elastic instability analysis are derived. Displacement functions for the uniform beam segment are employed in this development. Moment of inertia and area of the element are prescribed by arbitrary powers of the axial co-ordinate. Numerical results are obtained and compared with both analytical solutions and numerical solutions based upon stepped representations using uniform section elements. The significance of the inclusion of taper considerations within individual elements upon solution accuracy and convergence characteristics is also examined. This subject problem and solution approach demonstrates that the upper bound character of minimum energy solutions may be difficult to exploit under practical circumstances.
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  • 70
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 277-282 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This article describes-a new method, suitable for use on a digital computer, for evaluating the singular double integral of Hayes which determines the transonic wave drag of a slender body. Comparison with known exact results and with an earlier computer program described by Eminton shows the present method to be accurate as well as economic in computer time.
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  • 71
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 283-293 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The complementary variational principle has been used to derive the differential equations and the associated boundary conditions of the vibrating plate in terms of bending moments. It is shown that in this formulation, the plate possesses an infinite number of zero frequency modes in which the plate remains in a state of constant strain under a set of self-equilibrating bending moments. In applying the Rayleigh Ritz procedure for the non-zero frequency modes of the plate, it is shown that it the assumed functions are orthogonal to only a finite number of zero frequency modes, then one may obtain frequencies which are lower than the true frequencies of the plate. An iliustrative example is given in the paper.
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  • 72
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 299-299 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 74
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 301-303 
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    Keywords: Engineering ; Engineering General
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  • 75
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    International Journal for Numerical Methods in Engineering 2 (1970) 
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  • 76
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 307-310 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Convergence of a finite element procedure for the solution of the fourth-order equations is proved. A generalization of this result is mentioned and some remarks concerning the numerical results obtained at the Computing Centre of the Technical University in Brno are given.
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  • 77
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 311-333 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Digital filters are finding wide applications in signal processing aspects of such fields as engineering, geophysics and biosignal analysis. The design of a digital filter and its realization with near minima computer word length are two problems which can be solved by computer-aided design techniques In this paper, the automated design of the initial filter (recursive type) only is considered. Both of the basic design methods - the direct and indirect approaches - have been analysed, and compute programs have been written to implement the various design techniques. The present program are limited to the design of flat loss type filters specified by their gain rather than their phase character istics. although provision has been made to allow for other types of design in the indirect approach Design examples are given, and the results analysed with a view to the suitability and limitations of the different design techniques.
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  • 78
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 353-361 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper demonstrates the applicability of general non-linear programming methods to the solution of buckling problems. The minimum energy formulation of the buckling condition is shown to yield an unconstrained non-linear programming problem, for which several numerical methods of solution are readily available. Some of these methods are discussed and numerical results are presented for stiffened plates with in-plane as well as lateral loads.
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  • 79
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 335-352 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Stiffness matrices are formulated for the torsional and lateral stability analysis of structures composed of flexural members by the matrix displacement method. The formulations are based upon approximate displacement fields which represent the action of the element in simple flexure. Example problems, for which exact solutions are known, illustrate the accuracy and convergence characteristics of the derived formulations.
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  • 80
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 363-385 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A solution has been formulated, which allows one to analyse all the major performance characteristics in a chain of impacting elastic ‘rods’. By allowing one end of the elastic chain to impact against a surface which resists penetration according to a specified penetration law it is possible to analyse the impact system of a variety of mechanical devices such as percussive tools and squeeze film dampers. Virtually, unlimited variety in the number and geometry of the impacting rods, and virtually unlimited complexity in the form of the reaction of the terminal face is permitted. A computer program for treating one or two elastic rods has been developed. The program prints out all important stresses as well as the stress history at several selected points. It also prints out the depth of penetration, the energy transferred from rod to rod, the overall energy transfer into the receiver, rebound velocities and times of separation between rods and between rod and 4receiver. Agreement with exact solutions and experiments is demonstrated.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 387-395 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A technique of differential displacements is presented whereby problems involving elastic contact are solved by the finite element method. The technique is applied to axisymmetric situations in which statically indeterminate conditions occur and is shown to provide a means for resolving these conditions in terms of contact stresses. Three typical engineering problems are analysed to demonstrate the technique in cases where body forces, thermal gradients and external applied forces are acting.
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  • 82
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 415-418 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Recent advances in finite element techniques have enabled full three-dimensional stress analyses to be undertaken. Economy and accuracy can only be achieved simultaneously if the characteristics of the element are understood. Preparatory work is described in which suitable pitching and disposition of brick-type elements are established for the analysis of cylinders.The information derived is put to use in the analysis of a cylinder-cylinder intersection. A favourable comparison is made with an independently computed solution.
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  • 83
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 397-414 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The velocity field of a semi-contained turbulent jet, as constructed by Abramovich, is used to arrive at the temperature distributions in the initial region of a turbulent flow film cooling situation taking into account both the development of the jet boundary layer and the wall boundary layer. After suitable profiles of eddy thermal conductivity are established, a finite difference form of the thermal energy equation is derived, shown to be unconditionally stable, and solved numerically with the aid of an IBM System 360 computer to yield the temperature distributions. Wieghardt's parameter for collapsing the temperature profiles onto a single curve in film cooling situations, when suitably modified, also collapse the analytical results to essentially a single curve even as near as 2·7 slot heights from the injection point, thus verifying the temperature similarity in film cooling which has been experimentally observed even very near the injection point. Results in graphical form are presented which allows one to construct the actual temperature profile for a fairly wide range of the relevant parameters.
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    International Journal for Numerical Methods in Engineering 2 (1970) 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 453-454 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 419-451 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A general formulation for the curved, arbitrary shape of thick shell finite elements is presented in this paper along with a simplified form for axisymmetric situations. A number of examples ranging from thin to thick shell applications are given, which include a cooling tower, water tanks, an idealized arch dam and an actual arch dam with deformable foundation.A new process using curved, thick shell finite elements is developed overcoming the previous approximations to the geometry of the structure and the neglect of shear deformation.A general formulation for a curved, arbitrary shape of shell is developed as well as a simplified form suitable for axisymmetric situations.Several illustrated examples ranging from thin to thick shell applications are given to assess the accuracy of solution attainable. These examples include a cooling tower, tanks, and an idealized dam for which many alternative solutions were used.The usefulness of the development in the context of arch dams, where a ‘thick shell’ situation exists, leads in practice to a fuller discussion of problems of foundation deformation, etc., so that practical application becomes possible and economical.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 459-476 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The stiffness equation is derived for curved elements of orthotropic axi-symmetric thin shells, and equivalent applied loads are found for shells subjected to initial strains, applied surface loads and body forces. The Lure approximation of thin shells and displacement field approximation by polynomials of arbitrary degree are included in the formulae derived.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 477-494 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A computational procedure based on gradient iterative techniques is proposed for the solution of large problems to which the finite element method is applicable. In linear problems the procedure can be used either for solving the set of algebraic equations or for the complete inversion of the matrix of coefficients. Special attention is focused on the practical aspects of the procedure concerning its realization on the digital computer.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 495-507 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A finite element method to determine unsteady aerodynamic influence coefficients, consistent with the stiffness and inertia properties of a lifting surface in supersonic flow, is described. This is basically a kinematic method, which reduces the dynamical equations of a non-conservative system to a simple and elegant form. It is illustrated by application to a delta wing using triangular elements to calculate steady and unsteady lift and moment coefficients. Throughout the calculations only a coarse grid system has been employed and the answers have been compared with available results.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 509-522 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A simple program carrying out various vector operations in two- or three-dimensional spaces is presented. The listings are given in A.S.A. FORTRAN IV. The program is of particular application in various forms of three-dimensional and shell analysis as it can create and transform locally orthogonal co-ordinates, etc. While these applications motivated its design, it is of very general use one such application is illustrated by applying the program to general perspective projection.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 523-533 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A procedure is presented for the automatic renumbering of network type equations prior to solution by sparse matrix techniques. The method takes an arbitrary input sequence and creates an order which makes possible solution of complex network systems by reducing demand for computer storage and time.Examples are presented to demonstrate the procedure in action and show that, even in cases where the system has been carefully numbered, considerable improvement can be achieved. The procedure is also applicable to band matrix solution techniques.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 579-595 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: The feasibility of achieving a preassigned stress state by changing the stiffness of determinate and indeterminate pin connected structures is presented. A new force method with all element forces (or stresses or areas) as independent variables is developed. The possibility but futility of getting the element areas by inverting and pre-multiplying the coefficient matrix with the external load vector when areas are chosen as variables is shown. The relationship existing between the compatibility equations and the plastic strength of pin connected structures is illustrated. Possible design methods for trusses under single or multiplicity of load conditions, the design of truss geometry and the relations between fully stressed and minimum weight structures are examined and illustrated through several examples.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 563-577 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This paper deals with solving two-dimensional variational problems of second- and third-order by the finite element method. To each meshpoint are associated three or six basic functions of class C1 or C2. The expression of the admissible functions on a triangular and rectangular element are given here in a general form which is specially suitable for computation.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 535-549 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The eigenvalue method is well-known as an aid to the solution of a wide range of engineering problems. In power system analysis it has relevance to travelling wave phenomena,1 sensitivity and dynamic stability in synchronous multimachine2 systems, critical speed calculation, vibration of structures and other related topics. The method of numerical solution of eigenvalues depends on the size and nature of the problem and often where large matrices are involved presents great difficulties.This paper describes in detail the application of the escalator method and diakoptics to large eigenvalue problems. The escalator method is a well-established one which consists of a systematic way of escalating from a 2 × 2 matrix up to any desired order in steps of one row and column at a time. The diakoptical method reduces computer storage, calculation time and improves accuracy. This results in the more economical solution of large and complicated problems which cannot be conveniently solved by any orthodox method. The paper deals with problems of degeneracy and means of overcoming these by simple routine processes. It concludes by indicating the particular advantages of the method and its usefulness for a wide variety of general engineering problems.
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    International Journal for Numerical Methods in Engineering 2 (1970), S. 551-561 
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    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A novel integral equation technique is employed for the analysis of dynamic stability problems. The governing equation of the linearized parametric resonance problem is transformed into an integral equation. The kernel of the integral equation is computed as the influence function for the deflection and/or bending moment of a corresponding beam.The highest derivative of the governing function (in our case fourth derivative of the displacement function) is chosen as the basic unknown. Using the formal analogy with the differential equation of the beam flexure this highest derivative is comprehended as some unknown transverse ‘load’. The distribution of this ‘load’ is a priori assumed to be polygonal. Using elementary methods of structural analysis, the displacements due to the assumed ‘load’ are determined. These displacements, arrayed into a square matrix, approximate the kernel of the governing integral equation.The subsequent procedure via Hill's determinant is a conventional one. The results prove to be accurate enough even for a very modest number of points of integration. This reflects the fact that the method is based on numerical integration rather than on numerical differentiation.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 97
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 2 (1970), S. 597-600 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: In any mesh, rules exist that interrelate the number of internal and external sides, vertices, etc. and the total number of elements. These are given explicitly for plane meshes of triangles and quadrilaterals, and for solid meshes of tetrahedra and cuboidal elements. The method is quite general and discovers all such independent rules that exist. Thus, for a plane mesh of T elements having Vi internal and Vb boundary vertices and Si internal and Sb boundary sides, then \documentclass{article}\pagestyle{empty}\begin{document}$$\begin{array}{l} T = \frac{1}{3}\left({S_b + 2S_i} \right) = V_b + 2V_i + 2H - 2\quad{\rm (for\,triangular\,elements)}\\ T = \frac{1}{4}\left({S_b + 2S_i} \right) = \frac{1}{2}\left({V_b + 2V_i} \right) + H - 1\quad{\rm (for\,quadrilateral\,elements)} \\ \end{array} $$\end{document} where H is the number of internal boundaries (holes) there might be. For solid meshes, these two-dimensional equations relating elements to sides generalize to \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{6}\left({F_b + 2Fi} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{4}\left({F_b + 2Fi} \right){\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are Fb boundary and Fi internal faces. Unfortunately, there is no direct generalization of the two-dimensional equations relating vertices and elements: it is only possible to do this by including the Ei internal and Eb boundary edges: \documentclass{article}\pagestyle{empty}\begin{document}$$ \begin{array}{l} T = \frac{1}{8}E_b + \frac{1}{2}\left({E_i - V_i + H - h - 1} \right){\rm\quad (for\,cuboid\,elements)} \\ T = \frac{1}{3}E_b + E_i - V_i + H - H - 1{\rm\quad (for\,tetrahedral\,elements)} \\ \end{array} $$\end{document} where there are H through holes and h cavities.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 98
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 19-34 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: It is demonstrated that dicarboxylic acids of uniform lengths, obtained by degrading chain-folded polyethylene single crystals, can be converted to paraffins via the intermediate diiodide by means of the procedure of Barton et al. Thus we are now in the position of obtaining uniform paraffins of chain lengths longer than hitherto available for the study of the crystallization of oligomeric chains. Measurements of melting points and heats of fusion revealed major differences between the paraffins and the corresponding parent dicarboxylic acids. It follows that such measurements on the unmodified products of the nitric acid degradation cannot be used directly for the assessment of the chain traverse length and the degree of crystallinity. It was found further, that the intermediate diiodide is a sufficiently close approximation to the paraffin for the purposes just quoted.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 89-103 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The theoretical justification for using M[η], or a similar quantity, as a universal calibration parameter in GPC is reviewed. The equation based on this parameter is applied to transform the primary calibration curve, obtained by means of polystyrene samples, into calibration curves for poly-α-methylstyrene, polypropylene, and linear polyethylene. The Mark-Houwink equations for these polymers, as they are used in the transformation, are discussed. The resulting GPC calibration curves are compared with molecular weights and peak elution volumes of fractionated poly-α-methylstyrene and polypropylene. The same comparison is made with samples of polypropylene and polyethylene having very broad molecular weight distributions. The agreement lies within experimental error.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 148-152 
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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