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  • 1985-1989
  • 1975-1979  (336)
  • 1890-1899
  • 1977  (336)
  • Chemical Engineering  (336)
  • 1
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Equilibria of reactions catalyzed by acetate kinase and adenylate kinase were studied experimentally and theoretically. Nucleotide conversions in excess of 90% were obtained with reactants (acetyl phosphate and one nucleotide) in stoichiometric proportion for ATP regeneration from either ADP via acetate kinase or AMP via the coupled enzyme system. Observed equilibrium constants, measured as a function of [Mg2+] at pH 7.4, ranged from about 1 to 9 for the reaction catalyzed by adenylate kinase and from about 50 to 400 for the reaction catalyzed by acetate kinase. These results agreed well with prediction of a theoretical model for the multiple equilibria between all species present in solution. Theoretical calculations showed that magnesium ion complexes and totally dissociated anions are the predominant species in solution at \documentclass{article}\pagestyle{empty}\begin{document}$p{\rm H}\tilde 〉 7{\rm and}[{\rm Mg}^{2 + } ]\tilde 〉 10^{ - 3} {\rm M}$\end{document}.
    Additional Material: 9 Ill.
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  • 2
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 116-117 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 118-120 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 4
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 134-134 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 5
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 144-160 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A group contribution molecular model is developed for the thermodynamic properties of polar and nonpolar liquids and their solutions, including energy of vaporization, ρVT relations, excess properties, and activity coefficients. The model is based on the cell theory in which the repulsive forces of molecules are expressed with a modified cell partition function derived from the Carnahan-Starling equation of state for hard spheres. The attractive forces are made up of group pair interaction contributions. Group and interaction properties have been determined for methyl, methylene, hydroxyl, and carbonyl. Extensive comparisons are made of predictions of the model with data for pure liquids and their solutions.
    Additional Material: 26 Ill.
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  • 6
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 177-184 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Diffusional mass transfer across membranes with uniform but low pore densities was studied experimentally as a function of stirring rate and pore area fraction. The results were analyzed in terms of a stagnant film boundary-layer model specially formulated for a heterogeneous membrane containing discrete pores. The overall membrane diffusional resistance is linearly related to the inverse of the pore area fraction of the membranes for a constant stirring rate. An equivalent boundary-layer thickness can be defined which is independent of membrane properties but a unique function of stirrer speed. These experimental boundary-layer thicknesses are greater by a factor of 3 than those predicted by a published Sherwood number correlation determined for homogeneous surfaces, but the stirring rate dependence is in excellent agreement with this same correlation.
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  • 7
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 203-205 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 8
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 192-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When a suspension of fine solid particles in a gaseous medium flows through a fibrous filter, particles deposit on the fibers forming chainlike agglomerates known as dendrites. This deposition pattern is responsible for the intrinsically transient behavior of the filter, leading to drastic increases of the filtration efficiency and of the pressure drop. Related phenomena are observed when aerosols flow through other types of porous media (for example, granular beds), or next to duct walls, around immersed objects, etc. A theoretical model of the particle dendrite growth was proposed recently by Payatakes and Tien. Here a revised and generalized version of that model is developed. The following major revisions are made: allowance is made for collisions with a particle in a given dendrite layer that lead to retension in the same layer, radial as well as angular contributions to deposition are considered, and the dendrite layer adjacent to the collector is allowed to contain more than one particle. These changes lead to a substantially more realistic theoretical model. Expressions for the transient behavior of a filter of differential thickness are obtained, based entirely on first principles. These, as it has been shown in a previous publication, can be used to predict the dynamic behavior of a macroscopic fibrous filter. The use and behavior of this model is demonstrated in the simple case of deposition by pure interception. The present treatment of deposition by pure interception is more rigorous than and supersedes that adopted in previous works.
    Additional Material: 12 Ill.
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  • 9
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 23-28 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Spin line tension, diameter attenuation, and the onset of the draw resonance instability are determined for a viscoelastic polymer melt, taking into account the changes in physical properties resulting from cooling of the filament. The theory predicts the experimentally observed stabilization of very short and very long filaments.
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  • 10
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 48-56 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Gas holdup and the ratio of the turbulent regime mechanical power consumed in aerated compared to that in nonaerated aqueous phases were measured in two laboratory sized tanks. Standard six-blade turbine (D/T = 1/3), six-blade paddle (D/T = 1/3), and four-blade paddle (D/T = 2/3) impellers were used over a wide range of impeller rotational speed and gas sparging rate. For all systems, the power ratio results were found to fit a semitheoretical correlation (derived from dimensional analysis) involving the impeller Weber number, the aeration number, and the ratio of dispersion and liquid densities. Empirical correlations for gas holdup in water, aqueous solutions of nonelectrolytes, and an aqueous electrolyte solution are given. The overall results lead to the conclusion that power ratio and gas holdup correlations are highly specific to a particular impeller type and are also dependent on the tank size and the liquid phase physicochemical properties.
    Additional Material: 7 Ill.
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  • 11
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 380-382 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 12
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 390-393 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
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  • 13
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 400-401 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
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  • 14
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 405-406 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 15
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 208-210 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 16
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Cycles in particle size and slurry density were experimentally observed in a mixed suspension, potassium chloride crystallizer equipped with a fines dissolver and having nonrepresentative product withdrawal. Cycling behavior was achieved with a product crystal elutriator but was also observed with changes in the orientation of the product removal tube, indicating that instability was induced by product classification. Simulation of the unstable runs with a dynamic model showed crystal size distribution (CSD) limit cycles of similar period using nucleation kinetics and process conditions measured experimentally. The computer simulation showed no tendency towards cycling for the stable runs.
    Additional Material: 16 Ill.
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  • 17
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 460-468 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A laboratory mixed suspension mixed product removal (MSMPR) crystallizer was operated with and without continuous fines segregation and destruction. Predicted improvements in product-crystal size were observed. By carefully representing the crystallizer flow pattern, quantitative agreement of crystal size distribution with prediction was achieved.
    Additional Material: 12 Ill.
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  • 18
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 477-482 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The experimental work reported here gives hydrate forming conditions in the water liquid-hydrocarbon liquid-hydrate region for five mixtures of methane and n-butane. Data available in the literature were used to establish the parameters in a computer program for predicting hydrate forming conditions in condensed systems. The method is shown to be reliable for several systems of widely variable composition.
    Additional Material: 2 Ill.
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  • 19
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 529-538 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Previous studies of copper-ion catalyzed ascorbic acid autoxidation have indicated zero-order, first-order, or Michaelis-Menten dependence of rate on ascorbic acid or copper concentrations and first- or half-order dependence on oxygen concentration. A simple mathematical model of gas-liquid mass transfer with liquid phase reaction accounts for the various behaviors. Use of an experimental technique that eliminates the mass transfer step shows that the oxidation rate dependence is first order in copper, half order in oxygen, and Michaelis-Menten in ascorbic acid concentrations.
    Additional Material: 9 Ill.
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  • 20
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 520-528 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is assumed that for pulverized fuel, the weight fraction W with a size larger than x can be expressed as W = exp(-bxn). This paper describes the theoretical development and experimental evaluation using pulverized anthracite burning at 30 lb/hr of a method of predicting the combustion rate of a pulverized fuel from the constants b and n in the above equation.
    Additional Material: 11 Ill.
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  • 21
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 592-596 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
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  • 22
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 362-375 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Methanol is overviewed from the standpoint of history: how the history relates to the present and how it could relate to the future. The overview includes ingredients (fuels, catalysts, etc.), synthesis gas generating procedures, processing techniques, and equipment and other considerations for the present and the near and more distant term future.
    Additional Material: 11 Ill.
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  • 23
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 695-701 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A semicontinuous pH parametric pump for separating proteins was experimentally investigated using the model system haemoglobin and albumin on a Sephadex ion exchanger. The pump considered had a center feed between an enriching column and a stripping column and was operated batchwise during upflow and continuously during downflow. Various factors affecting separations were examined. It was shown that parametric pumping is capable of separating proteins with high separation factors.
    Additional Material: 8 Ill.
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  • 24
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 722-725 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The collapse of a single spherical gas bubble within a large body of fluid creates a uniaxial elongational flow in the surrounding fluid. Collapse under constant bubble pressure is observed to produce nearly constant strain rate kinematics. If the steady state stress at the bubble/fluid boundary could be measured, it would be possible to estimate the elongational viscosity of the fluid.Unfortunatley the experiment does not yield the desired stress data, except in the special case of the Newtonian fluid. We are led to define an apparent elongational viscosity, and for specific constitutive models we can evaluate the deviation between the apparent and true viscosity. The experimental and theoretical work indicate that the apparent elongational viscosity provides a good estimate of true elongational viscosity for the tow viscoelastic solutions studied so far.
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  • 25
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 765-768 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 26
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 772-772 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 774-776 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 28
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 794-804 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Models have been formulated and analyzed for photosynthesis by algae in turbulent, channel flow. Analytical and computational for results for different stochastic, kinematic models of algal motion have been obtained for two different rate mechanisms. The results indicate that turbulent mixing can achieve an increase in the rates and efficiencies of photosynthesis by realizing the intermittency effects. Optimum levels of turbulence are shown to exist in turbulent channel flow for the mass cultivation of algae. The methodology of this paper is relevant to photochemical reactions in general.
    Additional Material: 18 Ill.
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  • 29
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 493-500 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Completely developed and entry region mass transfer rates in turbulent pipe flow of drag reducing polymer solutions were studied experimentally using electrochemical techniques. The percent change in the fully developed mass transfer rate at a given volumetric flow was found to be greater than the percent change in the pressure gradient. The data are interpreted by using the law of the wall, valid for Newtonian fluids at large Schmidt numbers, whereby K+ is related to Sc-0.74. The proportionality constant is correlated with percent drag reduction and is found to decrease with increasing drag reduction. The use of an analogy between momentum and mass transfer predicts a somewhat greater mass transfer reduction than was observed.
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  • 30
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    AIChE Journal 23 (1977), S. 538-544 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rates of absorption of pure sulfur dioxide into aqueous sodium bisulfite, sodium hydroxide, and sodium sulfite solutions with and without a surface active agent were measured at 25°C using a liquid jet column. For the sulfur dioxide-sodium hydroxide system, the rate of absorption into the solution without surface active agent was higher than that into the solution with surface active agent, indicating the existence of the interfacial turbulence. The absorption rates obtained for the present system under the conditions of no interfacial turbulence were in good agreement with the theoretical predictions based on the penetration theory.
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  • 31
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    AIChE Journal 23 (1977), S. 558-567 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general flow model is developed which is discrete both in time and space. The stirred-tank network model (continuous time compartmental model) is summarized and compared with the discrete flow model. Efficient methods for model fitting are given and demonstrated with numerical examples.
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  • 32
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    AIChE Journal 23 (1977), S. 816-822 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Process synthesis involves manipulation of the process arrangement, while studying the variables of each arrangement, to arrive at the optimal process. If each process arrangement is treated as a discrete variable, process synthesis becomes a mixed integer optimization problem. This paper examines the synthesis of heat exchanger networks using the adaptive random search procedure, which can be used to search continuous and discrete independent variables simultaneously. The means of handling the heat exchanger arrangement as a discrete variable is discussed, and the incorporation of various synthesis heuristics is presented. The results of synthesis of 2 × 2, 2 × 3, and 3 × 3 networks are presented and compared with other methods of synthesis.
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  • 33
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    AIChE Journal 23 (1977), S. 851-859 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The cross flow/electrifiltration process combines migration of particles in the presence of electrical and shear fields to increase filtration rates. A mathematical model and the experimental data are presented for both a kaolin clay suspension and an oil in water chemically stabilized emulsion. When the filter is operated in a regime above the critical voltage, filtration rate-electric field strength dependence becomes linear, and both electroosmosis in the filtration medium and electrophoresis in the liquid film are the controlling mechanisms of transport. Both experimental data and the mathematical model indicate that the fluid circulation rate tangential to the filtration media does not necessarily increase filtration rate depending on the regime of operation. The model is used in conjunction with the experimental data to separate the liquid film resistance adjacent to the filter cake which is determined by fluid shear and electric field from the cake and filter medium resistances which are influenced by electroosmosis.
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  • 34
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    AIChE Journal 23 (1977), S. 658-666 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The plex data structure is proposed for use in an advanced computing system to model chemical processes. The plex is shown to permit increased modularity and flexibility over systems with dimensioned array structures. Two methods are suggested to create and operate upon the plex: the problem oriented language and the problem oriented calling programs. The concept of a routing plex is introduced as a means for specifying the path of calculations when building block routines call upon other routines and choices exist at each level.
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  • 35
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    AIChE Journal 23 (1977), S. 958-958 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 36
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    AIChE Journal 23 (1977), S. 948-951 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A class of dynamic model approximation techniques based on a frequency domain Taylor series expansion is presented. These methods yield low-order models and are analytical rather than computational in nature; that is, one can retain important parameters (which may be time varying) from the original model in functional form in the low-order model. This feature is very attractive for on-line updating of the simplified model and subsequent control of the process. An example for a tenth-order original model has shown that the analytical low-order models provide excellent approximations to the step response of the original system.
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  • 37
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    AIChE Journal 23 (1977), S. 137-144 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper shows how the rigorous critical state criterion enunciated by Willard Gibbs can be used with a recently formulated two-parameter equation of state to obtain an analytical solution to the problem of predicting the critical properties of defined multicomponent mixtures. Comparisons are made between predicted and experimental values for several systems containing paraffin hydrocarbons and related materials.
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  • 38
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    AIChE Journal 23 (1977), S. 185-191 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The geometrical parameters of injection devices are shown to have almost no effect on the resulting two-phase flow, while they influence the pressure drop owing to its formation. The predominant hydrodynamic parameter is the ratio of the mean superficial velocities. A simplified analysis leads to good agreement with experimental results. The different causes of pressure drops are quantified.
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  • 39
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977) 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 40
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    AIChE Journal 23 (1977), S. 232-243 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pressure drop correlations for flow of slurries in pipelines were developed for each of the following four flow regimes: flow with a stationary bed, saltation flow, heterogeneous flow, and homogeneous flow. A total number of 2 848 data points, comprised of 1 912 collected from the published literature together with 936 taken using our own test pipelines and relating to ranges of the pertinent variables extensive enough to span all four flow regimes were used as the basis of these correlations. Also, these data were used in developing an associated quantitative regime delineation scheme. The correlations provide an improved predictive capability over previously available procedures and are also broader in scope. The delineation procedure developed here permits straightforward classification of the data according to the flow regime prevailing, and it is moreover inclusive of all the data and is self-consistent.
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  • 41
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    AIChE Journal 23 (1977), S. 275-285 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Necessary and sufficient conditions for intrinsically stable equilibrium in a multiphase, multicomponent body are developed with interfacial effects taken into full account. There is a limiting criterion for intrinsic stability that must be satisfied within every phase, and there is another limiting criterion that must be satisfied on every phase interface. The limits of intrinsic stability for a multiphase, multicomponent body are defined by the failure either of the first criterion within one of the phases or of the second criterion on one of the phase interfaces.
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  • 42
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    AIChE Journal 23 (1977), S. 294-303 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: New and extensive experimental data on the rate of growth of ice crystals in the a axis direction in quiescent and slow flowing subcooled pure water show conclusively that thermal natural convection is an important heat transfer mechanism controlling the growth rate. At zero and low forced velocities, steady growth is observed only when the crystals grow horizontally or upward. Steady downward growth does not occur in quiescent water. This is consistent with the physical properties of water and the phenomenon of thermal natural convection.Growth rates at high water flow rates vary as the square root of the forced velocity and the 3/2 power of the subcooling and follow the theory of Fernandez and Barduhn (1967) with the ice-water interfacial energy set at 52 mJ/m2 (52 erg/cm2).
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  • 43
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    AIChE Journal 23 (1977), S. 342-346 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrodesulfurization of gas oil is treated as a sum of parallel reactions taking place in narrow boiling range fractions. The component reactions are approximately first order for fractions with boiling ranges of 20°C and mid boiling points between 250° and 350°C. The experimental procedure involves desulfurization of the gas oil, fractionation of samples of feed and products at various residence times, and determination of sulfur concentration in the fractions. The effect of the particle size of the catalyst and of the viscosity of the oil on the reaction rate can be assessed from Thiele's equation.
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  • 44
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    AIChE Journal 23 (1977), S. 128-131 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 45
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    AIChE Journal 23 (1977), S. 131-133 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 46
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    AIChE Journal 23 (1977), S. 135-135 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 47
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    AIChE Journal 23 (1977), S. 160-169 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Measurements are presented on the influence of Schmidt number on the frequency of the mass transfer fluctuations at a solid boundary. The shape of the spectral function is similar at all Schmidt numbers. A relation between the mass transfer fluctuations and the fluctuating velocity field can be obtained only at high frequencies. A comparison of the scale and the frequency of the mass transfer fluctuations and the velocity fluctuations suggests that the rate of mass transfer is controlled by convective motions in the flow oriented eddies described by a number of previous investigators. However, the concentration fluctuations caused by these convective motions are greatly dampened close to the wall by molecular diffusion. Thus the mass transfer fluctuations reflect only the scale and not the frequency of the convective motions in the flow oriented eddies.
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  • 48
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    AIChE Journal 23 (1977), S. 213-213 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 49
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    AIChE Journal 23 (1977), S. i 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 50
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    AIChE Journal 23 (1977), S. 243-254 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Trajectories have been computed for two equal sized spherical particles in simple laminar shearing and in uniaxial extensional flows. Effects of interparticle attraction, electrostatic repulsion, and hydrodynamics were included.The results are pertinent to questions of colloidal stability under various conditions of flow. Particulate dispersions can react in several different ways as the intensity of shearing is increased from zero: the dispersion can remain stable; it can be redispersed, if it had been initially flocculated into a weak secondary minimum in the interparticle potential curve; it can be flocculated into a strong primary minimum in the potential curve; or, in extreme cases, it can be redispersed from the primary minimum. Results are presented which illustrate criteria for flocculation or stability to both laminar shearing and extensional flow. It is shown that hydrodynamic effects can significantly alter the criteria developed for stability of dispersions to Brownian coagulation.
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    AIChE Journal 23 (1977), S. 285-288 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 52
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    AIChE Journal 23 (1977), S. 601-602 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 53
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    AIChE Journal 23 (1977), S. 602-604 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 54
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    AIChE Journal 23 (1977), S. 651-658 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A novel distillation scheme which makes use of secondary reflux and vaporization to enhance thermal efficiency is presented. Low operating temperatures, close boiling mixture, and tight product specifications appear to favor this scheme over the conventional distillation. Computer simulation indicates a potential utility reduction of 50 to 75%.
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  • 55
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    AIChE Journal 23 (1977), S. 378-380 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Additional Material: 3 Ill.
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  • 56
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    AIChE Journal 23 (1977), S. 632-642 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Stable isothermal multiplicities were observed during carbon monoxide oxidation in an integral reactor, filled with alumina supported platinum catalysts. The multiplicities were investigated in the conversion-temperature, conversion-inlet carbon monoxide concentration and conversion-mass flow rate domains.The region of multiplicities was found to widen significantly upon catalyst aging which enhanced the pellets' diffusive resistances.Several intermediate stable steady states were found between the highest and lowest steady states, both experimentally and theoretically.All the above phenomena could be well interpreted by the interactions of the kinetics of carbon monoxide oxidation with intrapellet diffusion resistances.
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  • 57
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    AIChE Journal 23 (1977), S. 673-679 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental data on vacuum-spray stripping of sparingly soluble gases from aqueous solution using hydraulic nozzles were presented in part I of this communication. Mass transfer was shown to occur primarily from the thin liquid sheet issuing from the nozzle tip in semiquantitative accordance with an analytical model based on laminar flow behavior.Jet impingement hydraulic nozzles offer the advantages of simplicity and low operating cost in vacuum-spray stripping. An empirical model for the turbulent flow regime has been developed to facilitate incorporating jet impingement nozzles into a vacuum stripper design. The results of an economic analysis comparing other types of industrial vacuum strippers with the proposed design of a jet impingement vacuum stripper show the latter process to compare very favorably in terms of estimated equipment size and cost and in expected operating cost.
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  • 58
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    AIChE Journal 23 (1977), S. 701-714 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A recent design procedure for perforated plate extraction columns requires extension to include jetting conditions at each perforation. For this purpose, correlations are obtained for jet length, jet contraction, drop size, and mass transfer coefficients in disperse phase controlled liquid-liquid systems. Experimental variables include nozzle size, flow velocity, and physical properties.
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  • 59
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    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A state space model is developed for an existing nonadiabatic packed-bed reactor which experiences axial and radial concentration and temperature gradients resulting from highly exothermic reactions involving several chemical species. The set of partial differential equations is reduced from three to two dimensions using orthogonal collocation. Further use of orthogonal collocation on the quasi steady state version of the differential equations results in a set of coupled algebraic and differential equations from which a linearized low-order state space model is obtained. The model parameters are estimated from reactor data, and the fitted model is used for design and implementation of a multivariable stochastic control schemes on the reactor. These applications are described in parts II and III of this paper.
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  • 60
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A linear low-order state space dynamic model for a catalytic butane hydrogenolysis reactor which has been fitted to reactor dynamic data is used to develop a multivariable linear quadratic feedback control algorithm for regulatory control of the reactor exit concentrations using temperature measurements only. Kalman filter theory is used to obtain state estimates for the system. The control algorithm developed is implemented on the pilot plant reactor in a series of DDC control studies. The controller is shown to perform very well and considerably better than a single loop PI controller with a feedback on the hot spot temperature. Performance is evaluated both under the normal stochastic disturbances in the system and under a severe deterministic load disturbance. Exit concentrations predicted by the model and used in the performance index are shown to compare very favorably with actual concentrations obtained from a process gas chromatograph.
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  • 61
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  • 62
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    AIChE Journal 23 (1977), S. 879-889 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two concepts concerning the deposition of particles from suspension onto a collector, the shadow effect due to deposited particles and the singular and random behavior of approaching particles, are presented and discussed. Based on these concepts, a new theory of particle deposition is proposed and procedures for the simulation of deposition process outlined. The simulation results give the rate of deposition and the deposit morphology. Potential applications of this model to a number of technical problems are outlined.
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  • 63
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    AIChE Journal 23 (1977), S. 889-896 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Prandtl's eddy diffusion model was successfully extended to turbulent momentum, energy, and mass transfer in nonisothermal free jets by taking into account the effect of change in volume of traveling eddies. The present model was experimentally confirmed for the high temperature, low velocity, turbulent free jets produced by combustion of methane gas.
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  • 64
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    AIChE Journal 23 (1977), S. 931-935 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 65
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    AIChE Journal 23 (1977), S. 938-940 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 66
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    AIChE Journal 23 (1977), S. 10-16 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A correlating equation for assisting convection was developed by combining correlating equations for pure free and pure forced convection. These component equations are based on laminar boundary-layer theory for an isothermal, vertical plate. Theoretical values for assisting convection indicate that the third root of the sum of the third powers gives the best representation, as contrasted with the choice and rationalization of the second or fourth power by prior investigators.This expression was modified by the addition of a limiting value Nuo to obtain a better representation below the domain of boundary-layer theory and was generalized for uniform heating and for spheres and horizontal cylinders by the appropriate choice of the characteristic length.
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    AIChE Journal 23 (1977), S. 17-23 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The film theory for gas absorption with chemical reaction has been extended to take into account the release of heat due to solution and reaction. The analysis is applied to the industrially significant sulfur trioxide-dodecylbenzene system, and large increases in interface temperature are predicted during absorption. The enhancement factor behavior is correspondingly complex owing to the interaction of solubility reduction and rate constant enlargement. Some initial experimental measurements with the laminar jet technique confirm the need for and the basic soundness of the theory.
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  • 68
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    AIChE Journal 23 (1977), S. 40-48 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The response of a fixed bed of porous particles through which fluid flows to a pulse of tracer gas has been analyzed by a number of methods. It is found that analysis of the Fourier transformed and the Laplace transformed response curves for small values of the parameters of the integrals provides accurate estimates of intraparticle diffusivity and Peclet group for axial dispersion when additional information provided by the experiments is used to resolve interaction between the process coefficients in the dynamic response.
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    AIChE Journal 23 (1977), S. 62-68 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The solubility of sulfur dioxide in seawater in the range 10° to 25°C and 10-5 to 1 molal is predicted based on a simplified chemical model. Estimates are also given of the resulting pH and the attendant distribution of sulfur and carbon dioxide species. Sulfur dioxide is considerably more soluble in seawater or other naturally alkaline waters than in pure water.
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    AIChE Journal 23 (1977), S. 106-115 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experimental assessment of theory on the convective dispersion of blood gases by vortices in a curved channel exchanger has demonstrated the impracticality of the proposed design. A nonlinear stability analysis of the fluid dynamics provided an amplitude factor an order of magnitude less than that previously assumed for the system secondary circulations.
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    AIChE Journal 23 (1977), S. 93-106 
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    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics and product distributions of the thermal cracking of binary and ternary mixtures of ethane, propane, n- and i-butane were determined in a pilot plant under conditions of residence time, temperature, total pressure, and dilution as close as possible to those prevailing in industrial operation. The kinetics and yields observed with ternary mixtures were compared with those obtained with binary mixtures and with pure components. The experimental selectivities were compared with those which would be obtained from separate cracking and subsequent addition of the product streams. The deviations between the two can be predicted by means of the so-called global kinetics selectivities, which are based upon the selectivities obtained from the pure components cracking and upon the global rates of cracking of the feed components in the mixture.
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    AIChE Journal 23 (1977), S. 125-128 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Additional Material: 5 Ill.
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    AIChE Journal 23 (1977) 
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    AIChE Journal 23 (1977), S. 169-176 
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    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A compartmental dispersion model of longitudinal mixing in tube networks has been developed. The ability of this model to predict the impulse response of helium, benzene vapor, and sulfur hexafluride tracer gases in two and in five generation symmetric network models of the large airway system of the lung has been tested over an air flow range of 1 to 400 ml/s.The results imply that velocity profile distortion and secondary flows in branching regions have only a small effect upon the overall longitudinal mixing when flow is directed toward the higher-order generations. On the other hand, accurate prediction of the data requires adequate treatment of the finite rate of evolution of the Taylor dispersion occurring in these tube networks.
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    AIChE Journal 23 (1977), S. 205-207 
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    AIChE Journal 23 (1977), S. 212-212 
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    AIChE Journal 23 (1977), S. 213-213 
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    AIChE Journal 23 (1977), S. 255-263 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An isotropic, homogeneous packed-bed reactor is modeled as an array of sinusoidal periodically constricted tubes (PCT). The effective asymptotic bed-Sherwood number has been calculated for mass transfer at large Péclet number with a constant wall concentration and creeping flow hydrodynamics. The bed friction factor has also been calculated. The results for these macroscopic bed quantities depend upon two ratios of the microscopic PCT period length, average radius, and sinusoidal amptitude.
    Additional Material: 11 Ill.
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  • 79
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 288-294 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An analysis is performed to obtain an exact solution to the problem of thermal entry region heat transfer in a circular tube with an arbitrary circumferential wall heat flux for pseudoplastic fluids using the power law constitutive model. The solution is expanded in a power series form, with expansion coefficients and related constants obtained numerically. A simple result is presented for a cosine heat flux distribution around the periphery of the tube which illustrates the simultaneous influence of circumferential wall heat flux variation and non-Newtonian fluid behavior on heat transfer.
    Additional Material: 6 Ill.
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  • 80
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 326-335 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simplified model of nitrate ion transport (and other nonadsorbing solutes) in unsteady, unsaturated flow in porous media has been developed. The model represents nitrate flow in infiltration and drainage in sand quite well and can be applied to unsaturated flow in other homogeneous media with only minimum extra experimental data needed to describe the medium.
    Additional Material: 8 Ill.
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  • 81
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 347-352 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model is proposed for the hopping mechanism of surface diffusing molecules, adsorbed on porous solids, which allows a simple calculation of the mean hopping distance as a function of surface coverage.Surface permeabilities calculated with this model are compared to new experimental data. A satisfactory agreement is obtained, and the values of the parameters involved turn out to be very reasonable.
    Additional Material: 8 Ill.
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  • 82
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 387-389 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 83
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 395-398 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 84
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 403-404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 85
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 406-406 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 86
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 409-415 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The number of overall liquid transfer units as a function of the total pressure, flow rate, and nozzle height has been measured for the removal of butane and F-22 refrigerants from water for a flat spray nozzle in a vacuum spray chamber. The number of transfer units increases with the flow rate and with the total pressure with the increase proportional to 0.2 power of the Weber number in which the gas density is used. NOL also increases linearly with length, but more than two-thirds of the mass transfer always takes place in liquid sheet attached to the nozzle. Because the rate of mass transfer in a spray chamber is much greater than in a packed column, vacuum spray stripping is recommended for the removal of refrigerants from water and brine in the freezing and hydrate processes for desalination and other slightly soluble gases from aqueous solution in other processes.
    Additional Material: 8 Ill.
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  • 87
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 440-448 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model of combustion in a utility type of pulverized, coal fired furnace is developed by dividing the furnace into a number of isothermal zones. The method dovetails the combustion rate data available for single char particles with a gas flow pattern to predict local combustion heat release rates and local radiation absorption coefficients, which are used as input to a zoned heat transfer model.The furnace heat transfer is shown to be insensitive to combustion related parameters such as coal rank and coal fineness. For carbon in ash, local gas temperature, and to a lesser extent local heat flux, significant variations are predicted. It is concluded that for calculation of radiative heat transfer, combustion data are adequate. Further research activity on ignition and combustion stability, together with the radiative properties of fly ash, is recommended.
    Additional Material: 6 Ill.
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  • 88
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 487-492 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of the addition of drag reducing polymers and fibers on two transport processes in mechanically agitated liquid systems is examined. The first one concerns the determination of mixing times, which were found to be insignificantly to moderately increased in the drag reducing systems. The second one concerns the determination of the critical RPM at which complete suspension of solid particles occurs. It was shown that this was unaffected in the drag reducing systems. The results of this work can be applied to fermentation processes, biological reactors with flocs, and metallurgical processes. The theoretical implications of this work are to be seen in the association of polymeric and fibrous drag reducing additives with different parts of the turbulent spectrum.
    Additional Material: 8 Ill.
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  • 89
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 510-520 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Control of sustained limit-cycle instability in crystal size distribution (CSD) was simulated for a class II (high yield) crystallizer equipped with a fines destruction system and product classifier. Control was simulated by proportional control of nuclei density using fines destruction rate as the manipulated variable. The control constant necessary to eliminate instability was theoretically predicted and agreed with the constant found via simulation. Poorer control of CSD (inability to completely eliminate limit cycles) was predicted using slurry density and slurry withdrawal rate as the measured and manipulated variables, respectively. Development of techniques for fine crystal population measurements to estimate nuclei density are necessary for implementation of the former control scheme. The suggested nuclei density control scheme is effective both in minimizing CSD transients and for elimination of instability.
    Additional Material: 10 Ill.
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  • 90
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 544-553 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A plausible spill mechanism is proposed and idealized dissolution modes are developed for the prediction of lifetime and downstream cup-mixing concentration of spilled liquids. Four models are developed which reveal that detailed knowledge of the quantity and distribution of geometric shapes that make up the bottom residing interface between the spillage and the overlaying water are the independent variables of primary importance.
    Additional Material: 4 Ill.
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  • 91
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 567-578 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The permeation of oxygen, nitrogen, argon, and synthetic air through hollow silicon rubber fibers was studied between 0° and 40°C and at gauge pressures of up to 3.45 × 105 N/m2 (50 lb/in.2 abs). The study was conducted in a permeator module in which the hollow fibers were pressurized externally. Strain measurements with single fibers showed this mode of operation to be preferable to internal pressurization. The gas permeation rates were markedly affected by dimensional changes of the hollow fibers under external pressure. These changes were predicted satisfactorily by a modification of Varga's (1966) deformation analysis of thick-walled elastic tubes. The extent of air separation achieved in the permeator was in agreement with that calculated from theoretical models. It is conjectured that the performance of such a permeator may be improved in certain cases if the fibers are under suitable initial tension.
    Additional Material: 12 Ill.
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  • 92
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 596-599 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 93
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 610-612 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 94
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 612-613 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 95
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 613-615 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 96
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 617-631 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is widely recognized that chemical engineering has important roles to play in the development of national and worldwide energy resources through optimal utilization of fossil fuel reserves. It is much less appreciated that there are crucial chemical engineering problems in the development of energy production from other sources. In particular, the successful development of nuclear fusion power generating systems will require the solution of many problems that are uniquely suited to chemical engineers.This paper presents a brief overview of the fusion development program for magnetically confined fusion power reactors and an identification of the major technological problems remaining to be solved.
    Additional Material: 7 Ill.
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  • 97
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Carbon dioxide, oxygen, Freon 114, and butane were stripped from deionized water, sodium chloride solutions, and freshly acidified seawater in a vacuum-spray chamber using three types of hydraulic nozzle. Purely physical desorption was found for each gas/liquid system.For both conical-spray and fan-jet nozzles, the bulk of the gas was shown to desorb from the thin liquid sheet issuing from the nozzle, that is, before droplet formation occurs. Behavior was explained semiquantitatively by a mathematical model of the diffusion in the sheet. This model was also shown to predict well the desorption from the laminar liquid sheets formed by jet impingement nozzles. For turbulent flow in jet impingement nozzles, the fit of the model was again semiquantitative.
    Additional Material: 8 Ill.
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  • 98
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 685-695 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An improved four-parameter corresponding states method that includes polar fluids has been developed. The four parameters are the critical temperature, the critical pressure, the radius of gyration, and a newly developed polarity factor based on the second virial coefficient. These parameters have been used to empirically correlate pure and interaction second virial coefficients of a variety of fluids.
    Additional Material: 4 Ill.
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  • 99
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 726-732 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Legendre transform theory is used to develop two general critical point criteria for a classical thermodynamic system. The problem of indeterminacy is discussed, as is the option of employing mole fractions (rather than mole numbers).
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  • 100
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    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 23 (1977), S. 758-764 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: We have used recent ethylene/low-density polyethylene gas sorption data to calculate phase equilibria for ethylene/polyethylene mixtures from 0 to 30.3 MN/m2 (0 to 300 atm), the pressure range normally used in the flash separation step in low-density polyethylene manufacture. The computations show significant differences from results obtained by extrapolation of the results of a previous study to the relatively low pressure range considered here.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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