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  • 1995-1999  (1,123)
  • 1997  (1,123)
  • Engineering  (683)
  • Industrial Chemistry and Chemical Engineering  (228)
  • Analytical Chemistry and Spectroscopy  (212)
  • Nuclear reactions
Material
Years
  • 1995-1999  (1,123)
Year
Keywords
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 245-264 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: This paper deals with absorbing boundary conditions for the finite difference time domain (FDTD) method applied to homogeneous lossless waveguide structures. A theoretical formulation of the so-called ‘modal absorption’ (MA) is developed. On the basis of this theory different implementations available in the literature have been derived and compared. Then, some techniques to enhance the efficiency of the method have been proposed and tested. It is demonstrated that, with the proposed methods, the high level of accuracy of the original formulations is retained, while the computational cost is strongly reduced. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 285-301 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: A new approach for the time-domain simulation of power electronic circuits is developed. The methodology is based on stepwise identification of circuit topology. The simulation process automatically looks for a valid topology in every step. At each simulation instant, the circuit topology is transformed into a resistive network, giving another superior feature of this method: the avoidance of solving complicated s-domain or differential formulas. No small-signal approximation is assumed. Parasitic resistance of the reactive element is included in the circuit model. Several examples illustrating the generality and computational efficiency of this new method are presented. The simulated results are favourably verified with experimental measurements and available literature. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 19 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 205-207 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: A hybrid representation formulation approach is presented. It avoids some numerical inconveniences and was successfully used as an intermediate step to obtain the differential algebraic equations of PWL modelled VLSI circuits. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 193-204 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: An analysis of arbitrary thin-wire loop antennas and scatterers using periodic orthogonal wavelets is presented. The periodic orthogonal wavelet expansion is applied to solve the thin-wire version of the electric-field integral equation (EFIE). The curved solution domains are mapped into the definition domain [0, 1] of the periodic wavelets. The unknown current over each loop wire is expanded in terms of a basis derived from a periodic orthogonal wavelet through the maps between the curved integration domains and the interval [0,1]. The integral equation under study is converted into a sparse matrix equation by this technique. Numerical examples are provided for a variety of thin-wire loop antennas and scatterers. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 8 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 47-56 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: In this paper, a finite element method for solving ionized fields is developed based on a novel solution philosophy. Employing the Galerkin finite element method, the solution problem of an ionized field has been formulated as an optimization problem, i.e. as a problem of minimizing an objective function whose minimum gives the solution. The effect of wind is taken into account by introducing a scalar potential of its velocity. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 35-46 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: The circuit and coupling properties of a dipole grid array placed inside a rectangular cross-section waveguide are analysed when also a rectangular aperture is used to couple the resonator energy into a semi-infinite waveguide. A Green function approach is employed to determine the current distribution on the dipole elements by solving an integral equation and taking into account the boundary conditions on the rectangular cavity walls. Both mutual and self-impedance terms are calculated for the dipole grid array, and the effects of the rectangular coupling aperture are also examined. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 1-2 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: No Abstract
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 101-105 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Recurrence relations are developed to determine the weighting coefficients used in the simulation of random signals and rough surfaces with given statistical characteristics. These results can provide (in real time) straightforward, accurate solutions to the system of non-linear, algebraic equations associated with the method of moving summations. Three possible numerical methods have been reported to obtain approximate solutions to the system of non-linear, algebraic equations. However, none of them is straightforward, and they all require a large amount of computing time. This work can be applied to the numerical solution of the generalized telegraphist's equations used to analyze vertically and horizontally polarized radio wave scattering problems from permeable media with random rough interfaces. © 1997 by John Wiley & Sons, Ltd.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 121-136 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: This paper presents a multigrid method for numerically solving the coupled Poisson-Schrödinger equations in one dimension for a multilayered HEMT device structure. It is shown that this method produces a good speed-up factor over the non-multigrid approach. This should make it suitable for incorporating into the two-dimensional HEMT model involving coupled Poisson, Schrödinger, current continuity and energy transport equations, with the Schrödinger equation being solved in slices perpendicular to the layer structure. The time taken to produce a multigrid solution depends on the size of the coarse grid and on the number of grids used. A method of predicting the time taken for any combination of these values is presented. The method is demonstrated for a 4-layer device. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 7 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 169-176 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: This paper describes a modelling strategy and a software tool for simulating the dynamical behaviour of an active antenna array. The array consists of active radiating elements placed in a chain, i.e. a collinear array arrangement. To assist modelling of the active antenna array a macro model has been used to represent each of the radiating elements in the array. This simplifies analysis and allows dynamical performance to be efficiently computed, the resulting dynamical behaviour of the array being presented as an animated visualization. A computer program is presented which can simulate the active array in the time domain so that various characteristics, such as mode formation and spacial coupling effects, can be observed. Experimental validation is given in order to justify the mode formation predictions of the simulator. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 5 Ill.
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  • 11
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 265-265 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: No Abstract
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 17-22 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer with chemical reaction by liquid/liquid phase tranfer catalysis (LLPTC) for an isothermal batch reactor was analyzed. The results for the phase transfer catalyzed reaction system can be generally described by a pseudo first-order hypothesis, whereas the reaction system can be controlled by simultaneous mass transfer of the catalysts between two liquid phases and chemical reaction in the organic phase. The mass transfer limitation is mainly from the mass transfer step of QX from the organic phase to the aqueous phase. The concept of catalyst-effectiveness vs. physically meaningful parameters in a liquid/liquid phase transfer catalyzed reaction is introduced. The catalyst effectiveness is increased as the mass transfer factors increase, the ratio of reaction rate coefficients of aqueous forward reaction to organic increases, and the equilibrium constant in the aqueous solution increases.
    Additional Material: 7 Ill.
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  • 14
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 40-42 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The use of ozone and hydrogen peroxide for the simultaneous oxidation of nitrogen and sulfur oxides was studied in experiments carried out in a stirred cell. It was found that in a gas mixture, containing both nitrogen and sulfur oxides, only the nitrogen oxides are oxidized by ozone. Contrary to earlier results, sulfur dioxide does not disturb the oxidation of nitrogen oxides under dry conditions. The consumption of ozone in the oxidation of nitric oxide was slightly below the stoichiometric level because the ozone was introduced into the reactor in the oxygen flow. When the molar ratio between ozone and nitric oxide was more than 0.4, some of the nitric oxide was oxidized to higher oxides of nitrogen, the final product being a solid mixture of N2O5 and (NO)2S2O7. Some nitrosyl sulfuric acid was formed in the aqueous solution of hydrogen peroxide in addition to sulfuric acid under wet conditions. Some white solid was found on the walls of the reactor. This solid is said it the literature to consist of H2SO4, HNOSO4 and (NO)2S2O7.
    Additional Material: 4 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 85-89 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A comparative study of reported theoretical and experimental investigations evaluating the numbers and sizes of bubbles emerging from submerged orifices reveals that the lack of consistency can be attributed largely to faulty experimental techniques. Errors are attributed to an inadequate knowledge of the influence of the surface properties of the solid and liquid media on the emission process and to the lack of standardization of the equipment geometries especially regarding the pressure chambers and orifice plates. The analyses provide guidance to designing standardized equipment to produce reproducible bubbles.
    Additional Material: 1 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 429-433 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When in contact with water, organoalkoxysilanes and other alkoxy metal compounds react to organofunctionalized polysiloxanes or heteropolysiloxanes. A new method for the continuous preparation of porous organopolysiloxane spheres was developed. Droplets of the precursor mixture are injected into the vertical reactor column. Movement of the gelating droplets is controlled by flow of the aqueous reaction medium. Advantages are adjustable residence time, minimized coalescence and low reactor height. An example shows typical product characteristics like narrow particle size distribution and macroporosity.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 533-537 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Airlift loop reactors are useful in many chemical and biotechnological processes where three phase reaction systems are required. One example is biological waste water treatment. In order to enhance biological reaction rates it is often useful to immobilize the bacteria on carrier particles. Knowledge of solid distribution and local gas holdup in those systems is important for calculation of mass and energy transfer or reaction kinetics. For this reason a method has been developed which enables to measure such local phase holdups. The measuring system consists of a time-domain-reflectometry (TDR)-instrument in combination with a pressure difference meter. The method has successfully been applied to determine local axial gas and solid distribution in internal airlift loop reactors, filled with a three phase system consisting of water, air, and polymer particles.
    Additional Material: 6 Ill.
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  • 19
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 538-549 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: New data of gas-liquid mass transfer for cocurrent downflow through packed beds of porous and non-porous particles are presented. Mass transfer parameters for air/carbon dioxide/water, air/carbon dioxide/carboxymethylcellulose solution and air/carbon dioxide/sodium hydroxide systems were evaluated by least square fit of the calculated CO2 concentration profiles in gas phase to the experimental values. The volumetric liquid-side mass transfer coefficient increases with the increase of the flow consistency index of the liquid. A comparison of the volumetric liquid-side mass transfer coefficient values evaluated with and without taking into account the axial dispersion shows that the influence of the liquid axial dispersion is significant at low liquid velocity and high CMC concentrations, and the influence of the gas axial dispersion is insignificant.
    Additional Material: 14 Ill.
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  • 20
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 342-347 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two types of solid adsorbents, activated carbon and zeolite 13X, were used at 80°C to remove sulfur compounds from naphtha solutions. Adsorption isotherms have been determined in a pressure vessel. This investigation indicated that activated carbon is superior to zeolite 13X at such high temperatures. A new formula based on the Langmuir model has been found to fit the experimental data satisfactorily. Comparison of the findings of this study with those of a previous one conducted at ambient temperatures in this department indicates that such treatment generally gives better results at low temperature where almost complete recovery of the sulfur compounds can be performed by using zeolite 13X.
    Additional Material: 3 Ill.
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  • 21
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 22
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 371-377 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Fluctuation solution theory relates thermodynamics partial derivatives to integrals of molecular direct correlation functions from statistical mechanics. This paper describes an application of that theory for correlating and predicting solubilities of light gases in heavy n-paraffins. Two of the solvents are complex waxes. Equations from the theory represent the liquid phase, and additional hypothesis are adopted to build a model for the high pressure vapor-liquid equilibrium. In the correlation mode, the model, based in the fluctuation solution theory, produces a molar fraction of the gas in the liquid phase with an average absolute relative deviation under 3% in a large number of cases. In the prediction mode, when binary parameters are used, errors are on the order of 10%. Overall for n-paraffins solvents, the model presented in this paper shows a good capacity to correlate experimental solubility and an adequate power to extrapolate lower pressure data when a binary parameter value has been chosen.
    Additional Material: 6 Ill.
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  • 23
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The following deliberations are concerned with the application of economy criteria to the optimization of process-engineering plants. We are therefore not concerned here with criteria for investment decisions, i.e., decisions on the implementation orabandonment of an investment project, nor with criteria for the selection of the most profitable investment options from a series of alternatives. Instead, we are interested here in the question of how a plant, while at the planning stage, can best be designed, i.e., the most rational method of selecting process parameters, such as throughputs, pressures, temperatures, concentrations, etc. The problem of plant optimization only occurs, however, when there are design parameters which can be selected at will or can, at least, be varied within certain limits. This is however, virtually always the case. There is then a need for an optimization strategy in the form of an objective function which is either reduced to a minimum, where lowest possible production costs are the target, for instance, or advanced to a maximum, where high profitability is the aim. The inclusion of engineering economy functions, in the form, namely, of the net present value function and the internal rate of return function for definition of such objective functions, provides better defined information on the best possible choice of process parameters than was possible with methods previosly used, such as the annuity method, for instance. One obtains different values for the process parameters to be optimized, depending on the objective functionused, and therefore different investment costs and utility consumptions. These differences are delineated and quantified using a process-engineering example in the course of the following discussion. The example selected is a gas scrubber, the function of which is to remove and recover useful components from a flow of gas. The specific problem examined is one of heat recovery.
    Additional Material: 9 Ill.
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  • 24
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 90-92 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of sodium lauryl sulphate (anionic) and Triton X-100 (nonionic) on the solid-liquid mass transfer at a gas-sparged fixed bed of copper Raschig rings was studied by measuring the diffusion-controlled dissolution of copper rings in acidified chromate solution. The variables studied were the nitrogen flow rate, the type of surfactant, and the surfactant concentration. It was found that an increase occurs in the solid-liquid mass transfer coefficient with increasing the nitrogen flow rate. Increasing the surfactant concentration was found to decrease the mass transfer coefficient. For a given surfactant concentration, it was found that Triton X-100 reduces the mass transfer coefficient more than sodium lauryl sulphate.
    Additional Material: 5 Ill.
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  • 25
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 571-575 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: For a specific combustion problem involving calculations of several species at equilibrium, it is much simpler to write a special computer program and calculate the concentrations, rather than to use a generalized computer program. To calculate these concentrations, one must solve a set of non-linear algebraic equations. This work describes a procedure in which the Newton-Raphson method and the successive substitution method are combined. It is was found that for these types of problems the value of unknowns and the nature of the equations are such that by adopting the two procedures simultaneously a much faster and reliable convergence is achieved. This study also shows what possible species should be considered for these calculations.
    Additional Material: 4 Ill.
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  • 26
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 27
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 582-588 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The shape-selective transalkylation of biphenyl with pentamethylbenzene over ultrastable Y-faujasites to produce para-methylated biphenyls was studied in the liquid slurry phase. The reaction was carried out in a discontinuously operated stainless steel autoclave using n-heptane as the solvent with a temperature range of 513 to 533 K and a pressure of 3 MPa. As for the progress of the reaction the presence of strong Brønsted acid sites was essential, an ultrastable faujasite treated with aqueous hydrochloric acid having a high content of those sites was used as the catalyst. Thus, a yield of the target product 4,4′-dimethylbiphenyl of above 11% referring to biphenyl could be achieved. The effect of the operating conditions on the formation of the target product was investigated. The decisive influence was acted out by the molar ratio of biphenyl to alkylating agent, in so far as a surplus of pentamethylbenzene of 7:1 referring to biphenyl enhanced the yield of the target product to 14%. The kinetics of the reaction could be successfully descibed with a lumped reaction scheme, introducing pseudo components, summarizing structural isomers, and pseudo reactions, such as the formation of coke.
    Additional Material: 7 Ill.
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  • 28
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 624-632 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxidation of sulfide in oxygen-saturated aqueous solutions is accelerated by dissolved or silica-bonded cobalt phthalocyanines. On the basis of thermodynamical considerations it is postulated that the catalyst enhances the formation of disulfide as the initial elementary reaction step. The following reaction steps are largely unaffected by the catalyst, as indicated by a product ratio sulfate/thiosulfate=0.86, comparable to that of the uncatalyzed autoxidation. A Langmuir-Hinshelwood formalism is developed for the catalytic reaction step and is demonstrated to fit best with the kinetics. In addition, from the kinetic data free enthalpies for the adsorption of HS- (i) at the dissolved phthalocyanine (ΔG = -17.6 kJ/mole) and (ii) at the immobilized complex (ΔG = -20.0 kJ/mole) are calculated.
    Additional Material: 8 Ill.
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  • 29
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 641-645 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An In-HZSM 5 honeycomb catalyst is used for the experimental investigations of the NO reduction with methane. The catalyst is prepared by the ion-exchange method. The influence of temperature and concentration of oxygen and methane is studied. In addition to methane, natural gas is used as reductant for the reduction of nitric oxide. The results are compared with those of other authors who use zeolithe pellets.
    Additional Material: 7 Ill.
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  • 30
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 290-294 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A compact and commercial aerosol generator capable of generating narrowly size-distributed aerosols with high mass concentrations was designed, fabricated and tested. The aerosol generator, consisting of a Delavan simplex nozzle (Model 30610-4), an L-shaped settling chamber and a virtual impactor with a clean air core, was modified and improved from Chein and Lundgren's work [20] to be more compact and readily commercial. The performance of the aerosol generator was evaluated using corn-oil, sodium chloride and uranine solutions. The results indicated that the cornoil droplets produced by the generator had a mass medium aerodynamic diameter (MMAD) of 7.20 ± 0.32 μm with a geometric standard deviation (GSD) of 1.48 ± 0.01 and the aerosol generation rate was 13.8 ± 1.3 mg/min. Solid aerosols generated from NaCl solution were found to have an MMAD in the range 1.39-4.88 μm with a GSD of 1.34-1.47 with the volumetric solution concentration varying from 0.1% to 9%. At the same time, the aerosol generation rate varied from 0.27 ± 0.05 to 15.8 ± 1.8 mg/min. depending on the solution concentration and the particle size produced. In addition, a 0.01% uraniane solution was tested to generate a submicron aerosol with an MMAD of 0.93 μm and a GSD of 1.48.
    Additional Material: 8 Ill.
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  • 31
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 313-313 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: No Abstract
    Type of Medium: Electronic Resource
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  • 32
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 209-216 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: In this paper, a generalized approach for the analysis of multistrip multidielectric layer transmission line structures based on the Method of Lines (MoL) is presented. The proposed algorithm is not limited either by the number of dielectric layers or by the number of metallic strips that can be positioned at different interfaces. The program we have written has been successfully tested on various structures and the obtained results are compared with those published by other authors. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 9 Ill.
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  • 33
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 231-243 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: The suitability of the transmission line modelling method for studying field-particle interaction devices is assessed through an example of a simple two-cavity klystron amplifier. Two separate numerical studies are presented, covering both beam bunching in the buncher cavity and field generation in the catcher cavity. Also addressed are the possibility of modelling the effect of the finite thickness of the cavity wall and beam coupling. The modelling of these practical aspects has not only resulted in some important insights into the field-particle interaction problem, but also demonstrated that the computer code developed is a powerful and versatile design tool. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 13 Ill.
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  • 34
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 217-229 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: We present an analysis of thin microstrip superconducting structures in which the effects of the superconducting material, of finite complex conductivity and finite thickness, are taken into account through the concept of sheet impedance coupled with an extension of the Spectral Domain Immittance Approach. The effect of the magnetic field on the penetration depth in the superconductor is included by solving the Ginzburg-Landau equations within the thin-film approximation (t/λ0 ≪ 1). The state of the material is determined self-consistently in such a way that when the critical field is exceeded, the material systematically shifts from the superconducting to the normal state. Special attention is paid to the behaviour of the system in the neighbourhood of the critical temperature, T/Tc ≃ 1. We report that, in some cases, the propagation constant of a superconducting microstrip line attains a maximum when the real and imaginary parts of the conductivity are approximately equal. Numerical results for a microstrip line and a patch resonator are presented and compared with available data to document the validity of the approach. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 11 Ill.
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  • 35
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 371-371 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: No Abstract
    Type of Medium: Electronic Resource
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  • 36
    Electronic Resource
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 303-312 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Monte Carlo methods are generally known for solving field problems one point at a time, unlike other numerical methods such as the finite difference and finite element methods which provide the solution at all the grid nodes simultaneously. This paper provides a Monte Carlo technique for obtaining the solution everywhere at once. The technique uses absorbing Markov chains to obtain the transition probabilities for all of the grid nodes at once. The procedure is illustrated with some examples for homogeneous and inhomogeneous, rectangular and axisymmetric solution regions, and is found to be accurate. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 7 Ill.
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  • 37
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    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 315-328 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: A strategy is proposed to enhance the performance of some numerical methods used in the solution of electromagnetic problems. The strategy can be extended to any numerical method based on the partitioning of the spatial domain into elementary cells. Two different implementations of the strategy are compared: modified-reversed Cuthill-McKee and tabu search. While the former is well known, the latter is here applied for the first time to such problems. Their application is shown in conjunction with three different numerical methods: mode matching of complex MW circuits, finite difference solution of PDE and FEM analysis of microstrip lines. The efficiency and versatility of the approach is proved for each of the three numerical methods, reaching a reduction in the working times of up to 20 times. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 8 Ill.
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  • 38
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The oxidative coupling of methane (OCM) was carried out in a polytropic fixed-bed reactor applying a Zr/La/Sr catalyst developed by the Neste company. Over this catalyst the OCM reaction follows a complex reaction scheme which includes primary parallel reaction steps to CO, CO2 and C2H6 and consecutive reactions of ethane to ethylene or COx. Yield of higher hydrocarbons C2+ obtained with this catalyst strongly depended on reaction conditions, i.e. low partial pressures of methane and oxygen obtained by diluting the feed gas with nitrogen and high reaction temperatures promoted C2+ selectivity and yield. The maximum yield amounted to 21.4% (20 Vol.-% CH4, 9 Vol.-% O2, 71 Vol.-% N2, T = 860°C; XCH4 = 41.8%, SC2+ = 52.5%). This result belongs to the highest yields reported in the open literature.
    Additional Material: 5 Ill.
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  • 39
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 47-52 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An ultrasonic transmission technique is under development to determine the concentration of solids in a three-phase slurry reactor by measuring the velocity of ultrasound in slurries. Preliminary measurements have been made on slurries consisting of water, glass beads, and air bubbles. The data show that both the sound speed and attenuation are well-defined functions of both the solid and gas concentrations in the slurries. A simple model is proposed to correlate the concentration of solids with the measured ultrasonic signals.
    Additional Material: 5 Ill.
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  • 40
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Chemical engineering is taught at German universities in three different types of curricula: chemical engineering proper, process engineering (“Verfahrenstechnik”), and industrial chemistry (“Technische Chemie”). Independent departments resp. faculties of chemical engineering exist at four universities. At other universities process engineering is offered as a complete curriculum with a smaller amount of chemistry than chemical engineering curricula, mostly by the departments of mechanical engineering. Industrial chemistry is an essential component of chemistry courses at most technical universities and optional subject at several classical universities. The cause of this diversity of approaches to chemical engineering can be traced back to the beginning of the production of high-value organics (dyes, pharmaceuticals) in Germany in the second half of the 19th century.
    Additional Material: 6 Ill.
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  • 41
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 485-490 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A dynamic model of the liquid fluidized bed containing two or more solid particle species of different size and density is presented. The model incorporates the particle mass transport mechanisms of the convection and the dispersion. The movement of the upper interface of the bed subject to a change in the liquid velocity is specified using the mass balance constraint. The particle velocities and dispersion coefficients are evaluated using correlations. The model is capable of describing the bed expansion, concentration profiles of the individual particle species, the bulk density profile, and the occurrence of layer inversion.
    Additional Material: 7 Ill.
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  • 42
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    Chemical Engineering & Technology - CET 20 (1997), S. 495-501 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An algorithm for the computation of design variables in layer crystallisation processes is presented, based on an algebraic solution of the moving boundary equation for heat transfer, as well as on an expression for the concentration profile. The algorithm was applied to the discontinuous crystallisation of a NaCl-H2O solution around the wall of an internally cooled cylindrical tube. Good agreement between simulation results and laboratory experiments was observed. After input of experimentally measurable values of the distribution coefficient, the algorithm enables the prediction of the following process variables along the crystallisation time: layer thickness, temperature, and composition profiles across the layer, as well as the end-values of solid and liquid mass and concentrations. Multistage processes can be studied by the series association of crystallisation cycles, enabling the determination of the optimal number of stages that meets a specific design criterion.
    Additional Material: 9 Ill.
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  • 43
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 522-532 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The intermixing of fluidizing gas between the compartments of a compartmented circulating gas fluidized bed fitted with a V-valve and riser combination has been experimentally studied. The intermixing of fluidizing gas that flows co-current (cross flow) as well as counter-current (back flow) to the circulating solids has been investigated. At low aerations, gas cross flow increased proportionally with the increase in solid circulation rate. But at high aerations, gas cross flow increased with aeration even when solid circulation decreased. Studies on back flow of gas revealed some interesting observations. At high fluidizing bed height on upstream side back flow of V-valve, gas has been negligible. But at low upstream bed heights and low aeration in V-valve and riser back flow of V-valve, gas has been substantial.
    Additional Material: 21 Ill.
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  • 44
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    Chemical Engineering & Technology - CET 20 (1997), S. 511-521 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: When working with disperse solid matter systems, one uses the effect of vibration in numerous processes. Solid matter mixing with vibration has only occurred in very simple units up to now. By means of the 3D-vibrational mixer from the company Kuston, Kleve, the influence of vibration on bulk materials and new mixing techniques are demonstrated. The 3D-vibrational mixer is suitable for liquids and solids, does not require mixing tools that need to be cleaned, and does not carry out rotary motions which would hinder incoming lines. It is used for mixing small amounts, where the mixing tank can be used simultaneously as the transportation container, so that a transfer is unnecessary.With the aid of 4 linear motors, the vibrational amplitudes and the frequencies can be varied within wide boundaries in all three spatial directions. By analyzing the vibrational system by means of Lissajous figures, it can be demonstrated that the optimal mixing effect occurs in the case of small frequency differences between the three axes. For freeflowing bulk materials, the best possible mixing state, the uniform coincidence mixing, is achieved after 2 min.
    Additional Material: 11 Ill.
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  • 45
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 23-28 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In the present study, a mass transfer model for Type-1 facilitated transport in liquid surfactant membrane is developed by taking into consideration a size distribution of emulsion drops, and analytical solution of the model equations has been presented. The model takes into account the continuous phase and outer liquid membrane phase resistances along with diffusion through composite emulsion drop. Effort has been made to highlight the effect of the various system parameters on the extraction rate including computation of reaction front position. The results of this work are found to be in good agreement with the published experimental results on batch extraction of phenol using NaOH as internal reagent. The model would thus provide an insight of the separation mechanism involved in the mass transfer processes in this type of system.
    Additional Material: 7 Ill.
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  • 46
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 419-423 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: By applying the macroscopic conservation laws to a simplified jet downstream from a sudden enlargement, a new correlation of the two-phase subcritical pressure recovery is obtained. Comparisons with the set of existing data (air-water and steam-water subcritical flows) show that the predictions obtained by means of this formula are more accurate than the ones given by available analytical models. The proposed correlation presents an important improvement of the pressure recovery predictions in the case of small mass velocities. However, it can not be applied in the conditions of quality too close to one.
    Additional Material: 6 Ill.
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  • 47
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997), S. 435-444 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This paper describes how gain scheduling control is applied to a continuous stirred tank reactor model. The CSTR process, equipped with a cooling system, is modelled. Based on the resulting nonlinear model, a gain scheduling controller is designed. The gain scheduling follows a scheme denoted bias compensation. Compared to earlier reported gain scheduling schemes, the proposed scheme results in a controller that is less complex, which is advantageous in the controller implementation stage. Numerous simulations are performed, using the gain scheduling controller and two choices of control input to the reactor model. The simulation results indicate that a gain scheduling controller performs better than a linear controller. Simulations using different choices of control input to the reactor model indicate that proper process design is crucial for the controlled process performance.
    Additional Material: 9 Ill.
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  • 48
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    Chemical Engineering & Technology - CET 20 (1997), S. 475-477 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A simple and new model for the prediction of drop velocity as a function of dispersed phase volume fraction has been proposed on the basis of experimental knowledge of onset time of complete separation between two phases as function of the initial hold-up.
    Additional Material: 1 Ill.
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  • 49
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    Chemical Engineering & Technology - CET 20 (1997), S. 478-484 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two important structural factors that affect distillation efficiencies, the outlet weir heigh and the liquid flowpath length, are investigated. Performance and efficiency data of an industrial scale i-butane/n-butane distillation column equipped with two-pass trays are used as a basis for the calculations. A mathematical development for a new method for predicting the numbers of vapor and liquid phase transfer units is given. This method together with some other NTU calculation methods is used to assess the effect of the outlet weir height on efficiencies. The effect of outlet weir height on the Murphree tray efficiencies is investigated using the observed point efficiencies and different point efficiency to the Murphree tray efficiency relation methods. The effect of varying liquid flowpath lengths on efficiencies is studied by calculating the Murphree tray efficiencies for one-pass and two-pass trays. The results obtained using the NTU calculation method presented in this study show that a certain outlet weir height point efficiency reaches its maximum. Most of the other methods give opposite results giving a minimum for point efficiency at a certain outlet weir length. The results also show that the Murphree tray efficiencies for one-pass trays are higher than for two-pass trays. Obviously, this is caused by the longer liquid flowpath length of one-pass trays. The Murphree tray efficiencies are also calculated for an industrial-scale MTBE purification column. The column is equipped with two-pass trays in the stripping section and with one-pass trays in the rectifying section. The Murphree tray efficiencies of one-pass trays are considerably higher than the two-pass tray Murphree tray efficiencies.
    Additional Material: 5 Ill.
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  • 50
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 51
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    Chemical Engineering & Technology - CET 20 (1997), S. 118-130 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A dynamic model is developed for a fluid catalytic cracking (FCC) unit to describe the dynamic behavior of both the riser and the regenerator reactors and their interactions. The cracking reactions are simulated by the four-lumped kinetic model [1]. The reactions in the riser occur in a transported bed with the fluid and the solids in ideal plug flow. The two-phase nature of the regenerator-fluidized bed is considered and the kinetic model for the coke combustion on the cracking catalyst [2,3] is incorporated. The proposed model is validated using steady-state plant data from an industrial unit and the results are found to be in good agreement. One of the main advantages of the model is that it does not include any partial differential equations. This facilitates the solution of the equations and makes the model particularly suitable for control studies. Simulation studies are performed to investigate the effect of changing various process variables, such as catalyst circulation rate, gas oil feed rate, and oxygen feed concentration.
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  • 52
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    Weinheim : Wiley-Blackwell
    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 53
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    Chemical Engineering & Technology - CET 20 (1997), S. 182-191 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The uncatalyzed esterification of acetic acid is described in the literature as a typical example of reactive distillation. Many rigorous models were validated using this esterification as an example. Process proposals for the production of pure ethyl acetate from ethanol and acetic acid have been determined using short-cut methods with the assumption of chemical equilibrium only. In this publication, the limitations of this esterification are clarified, using a rigorous model that was developed. The reasons why reactive distillation appears to be unfavorable for this esterification are explained. It is, however, theoretically possible to obtain ethyl acetate in high purity with different variants of the process. Different process variants are examined in this work. Construction variables that are important for the design of reactive columns, such as the number of reactive separation stages and the holdup in the column, are analyzed. Furthermore, the influence of variables dependent on the component system, such as the phase equilibrium of the reactive system and the reaction kinetics on the conversion in the column, are described. It can be shown that the short-cut methods published so far for reactive distillation, which assume chemical equilibrium, are inadequate.
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  • 54
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    Chemical Engineering & Technology - CET 20 (1997), S. 203-207 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Transient heat transfer in a mechanically agitated vessel is studied in the case of an anchor and an helical ribbon impeller using Newtonian and shear thinning fluids. Temperature stratification is found more pronounced with the anchor, making this impeller clearly inadequate for heat transfer. The impact of natural convection is evaluated first using the classical Gr/Re2 ratio. It is shown that the use of this criterion in viscous mixing is somewhat misleading. A new Grashof number is then proposed to assess the significance of the viscous and buoyancy effects in non-isothermal, non-Newtonian mixing applications. It is shown that the interpretation of this new number is strongly related to the concept of process viscosity.
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  • 55
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    Chemical Engineering & Technology - CET 20 (1997), S. 240-246 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate of the homogenous exothermic hydrolysis reaction of acetic anhydride catalyzed by sulfric acid in solvent acetic acid was estimated from nonisothermal experimental batch reactor transient temperature data. Rate equations based on three different reaction mechanisms of hydrolysis published in the literature were fitted to the experimental rate data. The experimental results on runaway and limit cycle behavior obtained with this reaction were explained by using the mechanism-based rate equations for hydrolysis in the reactor dynamic models, and good agreement was obtained between the predicted and the experimental dynamic data.
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  • 56
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    Chemical Engineering & Technology - CET 20 (1997), S. 282-284 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
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  • 57
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    Chemical Engineering & Technology - CET 20 (1997), S. 268-276 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: As an alternative to the existing bioheat transfer models a new system of two energy equations is proposed by considering the human body as a deformable porous medium. One equation is developed for the blood and the other for the peripheral skeletal tissue. It includes such significant factors as the vascular geometry and size, the blood flow and direction, thermal diffusion and the local thermal nonequilibrium between the blood and peripheral tissue. Discussion and application of both equations are given.
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  • 58
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    Chemical Engineering & Technology - CET 20 (1997), S. 285-286 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An ortho-experiment design and the analysis method of mathematical statistics are adopted to study the conversion of gypsum and potassium chloride to potassium sulfate in the system of K+, Ca2+, NH4+ ‖ Cl-, SO42- in H2O. Optimal reaction parameters and engineering mean are acquired to attain a conversion yield of potassium chloride of 94.52%.
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  • 59
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    Chemical Engineering & Technology - CET 20 (1997), S. 297-303 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Electrochemical gas absorption or biotechnical purification processes using structured packing as electrode or as biological support, respectively, may operate in bubble columns in presence of suspended solids. In both systems the knowledge of mass transfer rates from the liquid to the packing is important for the design of equipment. In the present investigation, the fluid dynamic behavior of a simple bubble column and a bubble column containing small size particles, both in presence of structured packing, was studied. Furthermore, mass transfer coefficients between the liquid and the structured packing were obtained by the electrochemical method. The influence of physical properties of the liquid phase, gas flow rate, kind and concentration of the suspended particles on both gas holdup and mass transfer was investigated. Correlations of the experimental data of mass transfer using dimensionless groups were derived and compared to previous correlations. Similarity with a heat transfer expression already used in two-phase systems was found.
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  • 60
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    Chemical Engineering & Technology - CET 20 (1997), S. 333-337 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The reaction of anisole hydroxylation with hydrogen peroxide to form methoxyphenols over TS-1 was studied. Four C1-C3 alcohols and the two aprotonic solvents acetone and acetonitrile were used. Product conversion was almost proportional to the titanium content of the catalyst sample. The highest conversion and p-selectivity were observed in ethanol. Some speculations, based on the formation of substrate-solvent or titanium-solvent-oxidant complexes, about the role of the solvent are presented. It was found that in all the solvents studied the p/o ratio increased with time.
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  • 61
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    Chemical Engineering & Technology - CET 20 (1997), S. 445-454 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two different layouts for the liquid-liquid extraction section of an industrial caprolactam process are evaluated. Laboratory mass transfer measurements on streams obtained from an industrial and a demonstration plant with different extraction sections are interpreted by a model describing the effect of surface contaminants on mass transfer coefficients. Indications of the impact of these layouts on the complexity of the extraction section, quality of products and efficiency of the extraction processes are given.
    Additional Material: 14 Ill.
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  • 62
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    Chemical Engineering & Technology - CET 20 (1997), S. 469-474 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Bubble columns are commonly used in industry for polluted gas treatment. Based on the same principle, the droplet column which is not widely known in the literature, uses much higher gas velocities, up to 14 m/s. This study concerns the hydrodynamics and mass transfer in this apparatus, in presence or absence of solid particles. Our results have demonstrated the impact of dusts on mass transfer performance giving rise to an increase in the kL aL coefficient with decreasing particle size. However, no influence of dust on the hydrodynamics of the column has been demonstrated within the studied particle size range.A study of liquid holdups obtained by three different methods is also carried out. Our results are comparable, thus validating the methods used.
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  • 63
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    Chemical Engineering & Technology - CET 20 (1997), S. 491-494 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Experiments were carried out in a conventional circulating fluidised bed to measure the axial pressure profile and total pressure drop, which covered a wide range of operating conditions. Material belonging to the Geldart A (fine material) as well as the Geldart B (course material) categories have been used in the present work. Slip velocity is determined from the total pressure drop and noticed that the slip velocity is much higher than the free fall velocity of single particle for Geldart A type material, while it is approximately equal to the free fall velocity of single particle for the Geldart B type materials.A model is developed for slip velocity taking into account all the hindrance effects: particle-particle, and particle-wall, and particle agglomeration. Predictions of the present model are validated with the data due to present study and the data reported in the literature.
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  • 64
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    Chemical Engineering & Technology - CET 20 (1997), S. 502-509 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dust explosion hazard exists in plants and facilities wherever combustible dusts are hardled. Minimum explosible concentration of dust clouds is an important factor requiring special attention for hazard evaluation if any technological equipment is to be protected by inertisation. The mathematical models available for prediction of this parameter have been analysed for their application to organic dust clouds. Solution of the most general mode for determination of minimum explosible concentration of dust clouds proposed by Mitsui and Tanaka is presented, together with the comparison with experimental data. It has been found that the model is not successful in predicting the minimum explosible concentration for organic dusts. Recommendations on requirement of development of a new model for prediction of minimum explosible concentration of an organic dust such as polyethylen have been given.
    Additional Material: 6 Ill.
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  • 65
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    Chemical Engineering & Technology - CET 20 (1997), S. 557-563 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Capillary viscometry is used to characterize viscosity, entrance pressure loss and apparent wall slip of paper coating colors at high shear rates. Special emphasis is laid on the dependence of these phenomena on solids content in order to account for changes in the rheology due to the dewatering of the color during the coating process. Coating colors with substantially different runnability have been investigated. Differences in apparent wall slip and high shear viscoelasticity (manifesting itself in extremely high entrance pressure losses) are observed at increased concentration, even if these phenomena do not show up at the initial solids content. Poor runnability is observed when viscosity, entrance pressure loss and wall slip increase strongly with increasing solids content. But all rheological features change simultaneously with the coating color recipe and it is not possible to separate out the contribution of the particular rheological features on the runnability of the coating colors or to correlate the runnability to a single rheological prorameter. Future work will have to focus on a numerical analysis of the blade coating process taking into account all the rheological features described here. First simulations including slip at the color/blade interface indicate that wall slip may cause severe runnability problems, at least when the apparent slip velocity exceeds the web velocity.
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  • 66
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    Chemical Engineering & Technology - CET 20 (1997), S. 581-581 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 67
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    Chemical Engineering & Technology - CET 20 (1997), S. 10-16 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The performance of an upflow packed-bed biofilm reactor has been analyzed under dual substrate limitation conditions. The numerical solution of the proposed equations defining the system has been obtained for a wide range of operating conditions for a case of practical significance involving glucose and oxygen as dual substrates. The results show that the inlet glucose concentration defines the limiting substrate at a position near the inlet of the reactor. For inlet glucose concentrations up to 300 mg/l, glucose acts as the limiting substrate. However, for inlet concentrations of 400 mg/l of glucose or higher, oxygen assumes the role of the limiting substrate at that position. For all other positions in the reactor, glucose acts as the limiting substrate, irrespective of its inlet concentration. Extensive computations were performed in order to define regions where glucose, oxygen or both are limiting. The predicted results have been found to be in agreement with the theoretical criteria, proposed in the literature, of determining the limiting substrate.
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  • 68
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    Chemical Engineering & Technology - CET 20 (1997), S. 36-39 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In order to reduce the B2O3 content in sintered magnesium oxide as much as possible, in precipitation with 80% of the stoichiometric quantity of dolomite lime, the effect of the pH of the agent used for rinsing the magnesium hydroxide precipitate was examined, as well as the effect of mannitol in sea water before precipitation. Mannitol binds orthoboric acid present in sea water into a weakly dissociated complex acid HB(OC)4. Experiments have shown that the B2O3 content in the sintered magnesium oxide samples is satisfactorily low. The lowest B2O3 content is obtained when mannitol is added; no B2O3 was found in these samples after sintering. Magnesium oxide samples were sintered at 1500°C; duration of isothemal sintering was one hour. Values for density and porosity of individually sintered samples are listed. The ratio CaO/SiO2 indicates that forsterite (Mg2SiO4), monticellite (CaMgSiO4) and mervinite (Ca3MgSi2O8) are formed during sintering of the samples.
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  • 69
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    Chemical Engineering & Technology - CET 20 (1997), S. 53-62 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The minimum ignition temperature of dust clouds is one of the important factors required for the design of preventive measures against dust explosion. The mathematical models available to predict this parameter have been analyzed for thier application to organic dust clouds. A solution of the most general model proposed by Mitsui and Tanaka is presented, together with its comparision with experimental data. It has been found to be quite successful in predicting the minimum ignition temperature for metal dusts but not for organic dusts. Recommendations for the development of a new model to predict the minimum ignition temperature of an organic dust, such as polyethylene, have been given.
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  • 70
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    Chemical Engineering & Technology - CET 20 (1997), S. 76-84 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: During recent years in chemical engineering processes for instance with aerated stirred tanks containing surface-active components foams and their mechanical control have become very important. However, there are still no rules for calculating mechanical foam breakers. As a contribution to foam control the present paper discusses the fundamentals of foam breaking by means of foam densities and gives a physical model for the mechanisms of a mechanical foam breaker when the main breaking effect is based on impact. The mechanisms were proved by measuring pressures in a foam breaker box. Diameters of secondary foam bubbles produced by foam breakers are calculated and discussed. Experimental investigations were made with different surfactants in aqueous solutions. The paper points out their influence on the process of foam breaking.
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  • 71
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    Chemical Engineering & Technology - CET 20 (1997), S. 101-107 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A vapor pressure calculation procedure based on a lattice equation is applied to several compounds. Originally, the method was used to predict low vapor pressures of heavy hydrocarbons. In this work, the method is used at low vapor pressure for nonhydrocarbons, and a modified version is employed at high vapor pressure for n-alkanes. As the procedures require the knowledge of one vapor pressure datum only, they work in a predictive mode. Prediction for hydrocarbons is good and for nonhydrocarbons is poor. Prediction of n-alkanes high vapor pressure is good with an overall average relative absolute deviation under 6 percent.
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  • 72
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    Chemical Engineering & Technology - CET 20 (1997), S. 144-148 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The kinetics of the liquid phase hydrogenation of 4-tert-butylphenol to form cis- and trans- 4-tert-butylcyclohexanol at 1.0-10.0 MPa and 40°C in isopropanol over a Rh catalyst has been studied. The kinetic behavior of this parallel system is described by a proposed reaction network. Keto-enol tautomeric transformation of adsorbed 4-tert-butyltetrahydrophenol and 4-tert-butylcyclohexanone is thought to be a key step, which governs the stereoselectivity of the overall complex reaction of alkylphenol hydrogenation.
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  • 73
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    Chemical Engineering & Technology - CET 20 (1997), S. 162-170 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The performance of an upflow packed-bed biofilm reactor has been analyzed under multisubstrate limitation by considering simultaneous carbon oxidation and nitrification reactions. The fasting shock load of inlet methanol concentration has a much more pronounced effect on the response of the system compared to that of inlet NH4+ -nitrogen concentration. The exit concentration of NH4+ -nitrogen drops very close to zero, thereby showing essentially complete nitrification during methanol fasting condition. Further, the concentration profiles of oxygen within the biofilm show significant variation during methanol fasting and nonfasting conditions whereas during NH4+ -nitrogen fasting conditions the oxygen concentration profile in the biofilm remains essentially unaffected.
    Additional Material: 6 Ill.
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  • 74
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    Chemical Engineering & Technology - CET 20 (1997), S. 199-202 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An electrochemical technique which involved measuring the limiting current of the cathodic reduction of potassium ferricyanide was used to study the rate of mass transfer inside a cubical cavity machined in the wall of a vertical rectangular duct. Variables studied were side length, physical properties of the solution and flow rate of the solution. The mass transfer coefficient was found to decrease with increasing cavity size; in all cases, the mass transfer coefficient inside the cavity was less than that at the duct wall. Mass transfer data inside the cavity were correlated by the equation Shc = 0.525 (Sc Re de/L)0.33. Comparison of the present results with the results obtained using other cavity geometries shows that cavity geometry plays an important role in determining the rate of mass transfer inside the cavity.
    Additional Material: 6 Ill.
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  • 75
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    Chemical Engineering & Technology - CET 20 (1997), S. 212-219 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The Subnetwork Corollary provides some sufficient conditions for which a complex reaction network could be determined to have capacity of admitting multiple positive steady-states, if it contains a subnetwork that also admit multiple positive steady-states. A family of reaction networks, involving catalytic reactions in an isothermal continuous flow stirred tank reactor (CFSTR), is determined to have the capacity to exhibit steady-state multiplicity by implementation of the Deficiency One Algorithm and the Subnetwork Corollary. A set of rate constants and two corresponding positive steady-states are constructed for several cases.
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  • 76
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    Chemical Engineering & Technology - CET 20 (1997), S. 247-258 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: New uses of artificial selective membranes, particularly ion-exchange membranes, improve on traditional methods of treating liquid mixtures before, during or after chemical or biochemical reactions. With the correct choice of ion-exchange membrane in a membrane reactor, reactions can be performed in such a way that the main product is not contaminated by undesired byproducts. Recent examples, mainly in organic chemistry, are given for eight typical ion-exchange membrane reactors: electrodialysis (ED), electrometathesis (EMT), electro-ion substitution (EIS), electro-ion injection-extraction (EIIE), coupled counter-transport (CCT), electro-electrodialysis (EED), electrohydrolysis with bipolar membranes (EHBM), and catalysis with ion-exchange membrane (IEMC).
    Additional Material: 25 Ill.
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  • 77
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    Chemical Engineering & Technology - CET 20 (1997), S. 277-281 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method for cleaning inner surfaces of pipes was studied both theoretically and experimentally. The method is based on the phenomenon of a sphere rotating in a pipe (levitation), when the translational movement of the sphere is restricted and the sphere is subjected to fluid flow in the pipe. The high rotation velocity causes a vibration process, which may be exploited for cleaning sediments or rust from the inner surfaces of pipes. A simplified theoretical model for the determination of the relationships among the dimensionless parameters governing the rotation phenomenon was developed. The model was validated with experimental data and found to be appropriate for engineering design of the system. Application of the cleaning method was demonstrated by cleaning the sediments and rust off the inner surface of a one-inch nominal diameter pipe.
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  • 78
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    Chemical Engineering & Technology - CET 20 (1997), S. 287-292 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The development and optimization of the synthesis of an analogue of sperm whale oil have been carried out. The product is an ester with characteristics similar to those of natural sperm whale oil. A central composite design was applied in the synthesis of this fine chemical. The variables selected for the present study are reaction temperature, initial concentration of catalyst and working pressure. Temperature is the most significant factor in the esterification process, and its influence is positive. Pressure influence can be neglected, and the catalyst concentration has a positive influence on the process. Depending on the temperature value, the influence of the interactions can be more important than that of the other two main effects, pressure and catalyst concentration. Response surface models have been found adequate to represent the yield of ester. The commercial quality of the synthesized product is very similar to that of natural spermaceti. Because of its low cost, this synthesis process is considered, from an economical point of view, very attractive.
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  • 79
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    Chemical Engineering & Technology - CET 20 (1997), S. 313-316 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: From the group statistical theory, a new universal equation is proposed for calculating the surface tension of solution with surface thermodynamics of solution. The simple form of the equation makes it convenient to use and its parameters have obvious physical meanings. With this model, we have explained the experimental phenomenan and empirical rules in cited works. Tested for 302 kinds of binary system, the overall absolute average deviation for 3230 data sets is 0.49%, making the model more accurate than those found in the literature. It also accounts for systems unsuitable for reference models because the phase states of the pure components are different under solution condition.
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  • 80
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The catalytic properties of extra-large pore aluminosilicate MCM-41, silicon containing VPI-5 and aluminium containing ETS-10 were investigated by MAT (Micro Activity Test) using n-hexadecane and 1,3,5-triisopropylbenzene as the model feeds and were then compared with the results obtained from Y zeolite in the H-form and a commercial FCC (Fluid Catalytic Cracking) catalyst. It could be demonstrated that not only the acidic properties of the investigated materials, but also the accessibility to the internal active sites of the investigated materials have a significant influence on activity and selectivity. It can be assumed that, by optimising structural and chemical properties, the mesoporously organised MCM-41 and related materials are suitable as active components in cracking catalysts for “deeper” cracking of high boiling hydrocarbons.
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  • 81
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    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two new constructed strains of X. campestris XLM1521 and XMT1, either alone or in mixed cultures were used for the production of xanthan gum in batch fermentations from whey. Fermentations were carried out at three different pH levels of 6.0, 7.0 and 8.0 and the results were compared with those previously reported for fermentations in Erlenmeyer flasks without controlling the pH. The kinetics of cultures of the strain X. campestris XLM1521 were studied in a batch reactor at constant pH values. A mathematical model, based on the Luedeking-Piret equation, was used and experimental design was employed in order to correlate model's parameters with pH variation. The highest xanthan gum concentration, 17.3 g/l, was observed at pH 8.0. This is the largest amount of xanthan gum reported so far.
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  • 82
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    Chemical Engineering & Technology - CET 20 (1997), S. 384-390 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The heterogeneously catalyzed oxidative dehydrogenation of isobutyric acid in a fixed bed reactor using molybdenum (Mo) heteropoly acids as catalysts shows a loss of Mo into the gas phase due to the formation of volatile Mo-complexes under reaction conditions. To avoid this loss of catalyst and to keep the catalytic material in the fixed bed and thus increase the catalyst's lifetime, the process has been performed under periodic flow reversal within the reactor. In this work, periodic flow reversal is tried in a semi-pilot test reactor as a method to fix the Mo-compounds in the catalyst bed. The influence of this mode of operation on the temperature profile in the reactor, on conversion, selectivity and yield of the product methacrylic acid is investigated in comparison with the process without periodic flow reversal.
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  • 83
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    Chemical Engineering & Technology - CET 20 (1997) 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
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  • 84
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    Chemical Engineering & Technology - CET 20 (1997), S. 455-461 
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A time- and space-dependent model based on the piston-dispersion-exchange model for liquid flow was developed to analyze the performance of two-phase upflow and downflow fixed bed reactors and was applied to the catalytic SO2 oxidation. The hydrodynamic parameters were determined from residence time distribution measurements, using an imperfect pulse method for time-domain analysis of nonideal pulse tracer response. A transient diffusion model of the tracer in the porous particle coupled with the PDE model was used to interpret the obtained RTD curves. Gas-liquid mass transfer parameters were determined by a stationary method based on the least square fit of the calculated concentration profiles in gas phase to the experimental values. It is shown that two-phase downflow fixed bed reactor performs better at low liquid flow rates, while two-phase downflow fixed bed reactor performs better at low liquid flow rates, while two-phase upflow performs better at high liquid flow rates.
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  • 85
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    Particle and Particle Systems Characterization 14 (1997) 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
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  • 86
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    Particle and Particle Systems Characterization 14 (1997), S. 272-277 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Two descriptors based on mathematical morphology are described which permit discrimination between convex and concave polygonal shapes which often characterize crystalline particles. Their computation is based on the comparison between the silhouette of the particle and a reference shape. Three reference shapes are discussed: the convex hull, the circle circumscribed to the particle and the equivalent circle.
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  • 87
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    Particle and Particle Systems Characterization 14 (1997), S. 267-271 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A method called “image-sedimentation”, based on the application of Stokes' law to suspension and image techniques, is proposed for the rapid analysis of particle size distributions. A parallel beam of optical light, after passing through a cell containing particles, is measured with a linear image sensor with 2048 photodetectors to determine the attenuated light intensity displayed on a monitor screen. The settling height between any given point and the liquid surface can be measured accurately by use of this image technique without any additional mechanical device to move either the light beam or the glass cell containing the suspension. Consequently, the total time required for the determination of the particle size distribution, typically of a carborundum powder having a median diameter of 5 μm, takes only 5 min as compared with more than 20 min by using other instruments based on the sedimentation principle.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 88
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    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 278-282 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In previous work, the relative performance of various methods used to characterize the particle size distribution of powders composed of fine irregularly shaped particles was assessed. It was found that methods employing Fraunhofer diffraction theory were inferior with respect to particle counting methods. Furthermore, calculated particle size distributions varied considerably between manufactures of Fraunhofer devices. It is well known that the Mie optical model can also be used to analyze the data collected by laser diffraction instruments. Here, we have compared particle size distributions collected using two Laser diffraction instruments to those determined by the Aerosizer. In our earlier work the Aerosizer was shown to produce results nearly identical to those determined by image analysis. The results of this study indicate that the use of the Mie optical model does not correct for deficiencies previously noted for laser diffraction methods. Considerable variation exists between the results obtained on laser diffraction instruments manufactured by different companies. Our earlier recommendation to use extreme caution when employing laser diffraction instruments to characterize fine powders continues to be supported in the present work.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 89
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 283-289 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The influence of the surface roughness of solid conducting spheres on the response of a phase-Doppler anemometer (PDA) is described by using a ray theory model. A rough particle surface is modeled as an ensemble of distorted spheres. First- and second-order reflection and diffraction are considered for far-field calculations of the PDA phase difference. The numerical simulations are accompanied and supported by experimental results. Single rough Sn spheres are captured inside an electro-dynamic trap and investigated with a standard phase-Doppler system.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 90
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 14 (1997), S. 295-303 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new method is introduced to analyze the accuracy of phase-Doppler anemometry (PDA) for sizing large particles in two-phase flows. The method is based on Fourier optics theory (FOT) and geometrical optics theory (GOT) to calculate the intensity ratio of refractive and reflective light scattered by a sphere under a slit constraint. To examine the accuracy in calculating the light intensity, the results from the GOT method were compared with those of the direct simulation based on the generalized Lorenz-Mie theory (GLMT). This newly developed FOT/GOT method also predicts the results of phase jump due to the slit constraint. The performance of dual-mode phase-Doppler anemometry can also be simulated by this method.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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  • 91
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 269-284 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: A simple, approximate, but very rapid and accurate image method is proposed for the analysis of arbitrary wire antennas above a lossy half-space. The reflected field from vertical and horizontal Hertzian dipoles is approximated by the field of a few ‘optimally’ positioned simple elementary sources. The field of images is incorported into the Hallén-type equations for the current distribution, resulting in equations of essentially the same form as those for an isolated antenna. The equations are solved by the point-matching method and polynomial approximation of current along the antenna segments. The results for the impedance and admittance of antennas assembled of vertical, horizontal and/or oblique segments are in excellent agreement with the exact results (obtained from the Sommerfeld theory). The proposed method is conceptually very simple and on average 25 times faster than the exact method, although in some cases it was found to be faster for even two orders of magnitude. This makes it particularly suitable for numerical optimization and CAD of relatively complicated antennas and other wire structures above a lossy half-space. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 12 Ill.
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  • 92
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 343-353 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: When we solve the wave equation by the finite element method, the order of convergence and the accuracy of the solution are reduced by the presence of sharp edges. The employment of singular elements improves the solution and allows us to reduce the cost of computation.In this paper, three types of scalar singular finite elements with the capacity to handle singularities in the derivative, and which have previously been applied to mechanical problems, are examined, together with standard elements, in the context of homogeneous waveguide analysis.We solve two examples of homogeneous waveguides showing the different behaviour of the singular elements and obtaining information on the order of convergence and the approximation of the gradient of the unknown function. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
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  • 93
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 329-341 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: The dynamic analysis of discontinuities in printed circuits has been performed using the mode matching technique. This study concerns the open end of microstrip lines and suspended microstrip lines. The fields on either side of the discontinuity are described by means of the continuous (radiated and evanescent) and guided modes of the structure.The conditions of continuity of the electromagnetic fields are then applied in the plane of the discontinuity. By taking into account the relations of orthogonality of the modes of the same region, a system of coupled Fredholm integral equations is obtained and solved by the iterative method of Neumann's series.The study calls for the use of the continuous spectrum of microstrip lines, which can be obtained analytically only after a great amount of calculation and CPU time. Thus, the first approach consists in neglecting this continuous spectrum. This gives accurate results for the reflection coefficient but it is not sufficient for the derivation of the radiation pattern. So, two simple models for the continuous spectrum, both based on the physical behaviour of such discontinuities, are considered and discussed. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 8 Ill.
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  • 94
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 13-34 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Specifying electromagnetic compatibility (EMC) is a crucial step in the performance evaluation of electrical and electronic systems. This paper describes a circuit formulation for the EMC assessment of large and complex systems.The proposed method is based on breaking the actual structure down into an aggregation of multiport devices: lumped-parameter circuits and distributed-parameter multiports. The multiconductor transmission line (MTL) model is used for the description of signal propagation along system interconnects: uniform, twisted and shielded lines are considered. Accurate prediction models (including line losses and dispersion) are utilized for the quantitative evaluation of both intrasystem compatibility and susceptibility to radiated interference.The description of the network topology makes use of the concept of an incidence matrix which is widely used in lumped-circuit theory. It is extended here to the more general case of distributed networks. The entire analysis is carried out in the frequency domain and a transient response is obtained by using inverse Fourier and Laplace transforms.Noteworthy characteristics of the method can be seen in the simplicity and effectiveness of the prediction models and in the minimal effort required for system description. The proposed method is especially significant for complex systems, where the number of connecting structures can be quite large. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 12 Ill.
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  • 95
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 57-69 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: The modified Gaussian algorithm is introduced for solving the ionized fields of unipolar HVDC lines including the effect of wind. Specific techniques of incorporating in the algorithm the special structure of the optimization problem of the ionized field have been developed to economize the requirements for the computer memory and CPU time. Numerical tests are carried out on a coaxial cylindrical geometry and on a line-plane geometry both in the absence and in the presence of wind. Comparison with available experimental data shows good agreement. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 21 Ill.
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  • 96
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 107-119 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: A self-consistent numerical transport model based on the hydrodynamic equations obtained from Boltzmann's transport equation (BTE) is presented. The model includes both the temporal and spatial variation in electron velocity. A parallel implementation of the solution method, using FDTD techniques, is illustrated. Numerical results for a GaAs MESFET device are generated using this complete hydrodynamic model (CHM) and compared with results obtained from the more commonly used energy or simplified hydrodynamic model (SHM). The results indicate that for short gate-lengths (less than 0⋅5 μm) the two models lead to different DC steady-state results which in turn lead to different microwave small-signal models for the device. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 97
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 139-151 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: The response of a p-i-n photodetector made from gallium arsenide to both steady-state and transient illumination has been modelled. Both an ensemble Monte-Carlo model and a drift-diffusion model were used, the latter with the choice of two different mobility models. The effects of high intensity steady-state illumination on the field and carrier distributions in the photodetector were calculated, and a comparative study of the models made. The transient response to pulsed illumination has also been calculated and the different results obtained from the models explained. The effect of high illumination on the response speed of the detector has been demonstrated. In addition, an expression for obtaining the photocurrent from the Monte-Carlo simulation, with much reduced statistical noise over the conventional estimate, has been derived and successfully tested. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 11 Ill.
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  • 98
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    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 177-192 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: When compared with commonly used subdomain moment-method analysis, entire-domain analysis of 3D dielectric scatterers results in a greatly reduced number of unknowns. Unfortunately, the expressions for matrix elements tend to be quite complicated and their calculation extremely time-consuming if evaluated directly. It is shown in the paper that, in a Galerkin-type solution with large trilinear hexahedral basic volume elements and three-dimensional polynomial approximation of volume current inside them, these expressions can be manipulated analytically for optimized rapid non-redundant integration. Consequently, a method for the analysis of 3D dielectric scatterers is obtained that is efficient, rapidly converging with increasing degree of approximation for current, remarkably accurate and very moderate in computer memory requirements. The applicability of the method of moments is thereby extended to bodies of electrical sizes greatly exceeding those that can be dealt with by subdomain methods. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
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  • 99
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 1-1 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: No Abstract
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal of Numerical Modelling: Electronic Networks, Devices and Fields 10 (1997), S. 71-82 
    ISSN: 0894-3370
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: In this paper we present an efficient method for numerical solution of the transport equation of photogenerated carriers in MSM photodetectors. The method is based on conformal mapping of both the MSM photodetector structure and the system of transport equations into a new space. The mapping enables analytical calculation of the electric field, allowing one to take one of the co-ordinates as a parameter and thus reducing the problem to quasi-one-dimensional. In addition, the method of conformal mapping enables calculation of the normalized current response of a photodetector in the new space. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 5 Ill.
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