ISSN:
0268-2605
Keywords:
Condensation
;
Polymerization
;
Silyladamantane
;
Thermal stability
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1,3-bis(Dimethylhydroxysilyl)adamantane(I) has been prepared. Thermal condensation polymerization of this monomer yields poly-1,3-adamantyl-1,1,3,3-tetramethyldisiloxane. Condensation of I with bis(dimethylamino)dimethylsilane or 1,3-bis(dimethylamino)-1,1,3,3-tetramethyldisiloxane gave the expected 1,3-adamantyl dimethylsiloxane copolymers (II and III) respectively. These polymers have been characterized by 1H,13C, and 29SiNMR as well as GPC and TGA. They have unusually high thermal stability.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590010208
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