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  • 1960-1964  (7)
  • 1910-1914
  • 1890-1899
  • Dyes/Pigments  (7)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 3 (1964), S. 408-416 
    ISSN: 0570-0833
    Keywords: Reactive dyes ; Dyes/Pigments ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Two new groups of reactive dyestuffs have been developed. One group (Levafix® dyes) comprises compounds which contain —SO2NH—CH2—CH2—OSO3H or —CH2—N(alkyl)-CH2—CH2—OSO3H as reactive groups. The dyes of this group react with cellulose fibers to form cellulose ethers, e.g. R—SO2NH—CH2—CH2—O—cellulose. The substances in the second group (Levafix-E® dyes) consist of the amides formed from 2,3-dichloroquinoxaline-6-carboxylic acid and dyestuffs containing primary or secondary amino groups.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 2 (1963), S. 20-23 
    ISSN: 0570-0833
    Keywords: Reactive dyes ; Dyes/Pigments ; Reactive dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Compounds and dyes containing vinylsulfonyl groups or groupings which readily yield vinylsulfonyl groups possess a marked ability to add onto many compounds containing active hydrogen under alkaline conditions. They also react with natural substances of high molecular weight, e.g. wool and cellulose, which contain amino- or hydroxyl groups. These reactions lead to the formation of strong covalent bonds between the reactants. As a result of this finding, reactive dyes for nitrogenous and cellulose fibers have been developed.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0570-0833
    Keywords: Polycondensation ; Dyes/Pigments ; Bunte salts ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Dyes which contain only thiosulfate residues as water-solubilizing groups are readily polycondensed on cellulose under mild conditions in the presence of condensing agents such as sodium sulfide to give insoluble, high molecular-weight dyes. This type of fixation leads to wash-fast dyeings and, in contrast to reactive dyes, involves no reaction with the fiber. The preparation and application of the dyes are described.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 41-45 
    ISSN: 0570-0833
    Keywords: Dyes/Pigments ; Rutile structure ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Until the present time, new color pigments have been developed by isotypic and homotypic mixed-phase formation. This paper deals primarily with heterotypic mixed-phase formation for the preparation of new colored and white pigments with the rutile structure. Dioxides and difluorides crystallizing in the rutile lattice-form were chosen as host-lattices for the mixed-phase formation. Hosts of the general formula AB2 can accommodate, as guests, in the form of solid solutions, oxides and/or fluorides with different structures. Characteristically, the mean statistical cation-radius lies between 0.55 and 0.98 Å, with single radii between 0.46 and 0.98 Å. Relative quantities are so chosen that the cation to anion ratio of 1:2 prescribed by the host lattice, as well as electroneutrality, is maintained.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 532-537 
    ISSN: 0570-0833
    Keywords: Polyacrylonitrile ; Fibers ; Azatrimethinecyanines ; Dyes/Pigments ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Like all basic dyes, azatrimethinecyanines possess a good dyeing affinity for acrylic fibers. Compounds with isolated nitrogen atoms in the trimethine chain show insufficient light fastness, whereas good to excellent fastness to light is displayed by compounds having neighboring nitrogen atoms in the chain. Thus, a working hypothesis stating that the light fastness of trimethinecyanines on acrylic fibers is improved by progressive replacement of methine groups by nitrogen atoms has been partially confirmed.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 1 (1962), S. 568-572 
    ISSN: 0570-0833
    Keywords: Trichloropyrimidyl dyes ; Dyes/Pigments ; Dichloropyrimidyl dyes ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several examples are used to show that the reactivity of dichloro- and trichloropyrimidyl dyes and the sensitivity of their dyeings to hydrolysis are determined by the nature of the bridge unit between the chromophore and the reactive system. The tendency of the dyeings to hydrolyze in acid and, more particularly, in alkaline media increases with increasing reactivity of the dyes. In alkaline media, dyeings made with dyes containing oxygen bridges are cleaved mainly between the reactive system and the chromophore, while in dyeings made with dyes containing imino or methylimino bridges, the linkage between the reactive system and the cellulose is hydrolyzed.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0570-0833
    Keywords: Azo dyes ; Dyes/Pigments ; Oxidative coupling ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: New findings in the field of oxidative coupling reactions are reported. These involve: extension of this type of reaction to amidrazone system displaying (vinylogous) tautomerism and to unsymmetrical diarylhydrazines; elucidation of the coupling mechanism for these arylhydrazines and for the amidrazone systems previously described; the properties of some dyes, complexed with heavy metals, and the synthesis of tetraazapentamethine and penta-azapentamethine dyes.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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