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  • 1980-1984  (22,840)
  • Polymer and Materials Science  (15,115)
  • Analytical Chemistry and Spectroscopy  (4,318)
  • Organic Chemistry  (3,406)
  • Nuclear reactions
Material
Years
Year
Keywords
  • 101
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 161-164 
    ISSN: 0935-6304
    Keywords: High-performance-thin layer chromatography, HPTLC ; Zirconium oxychloride ; Backside fluorodensitometric detection on TLC plate ; Content uniformity test for lanatoside C tablets ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 102
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 172-184 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 103
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 215-217 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, fused silica ; Coupled columns ; Halogenated organic pollutants ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 104
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 225-226 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 105
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 211-212 
    ISSN: 0935-6304
    Keywords: Thin layer chromatography, TLC ; Alkylchlorosilanes ; Phosphatidylcholines ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 106
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 218-219 
    ISSN: 0935-6304
    Keywords: High-speed micro-HPLC ; Rapid Identification ; Polycyclic aromatic hydrocarbons ; Environmental sample ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 107
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 222-224 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Interface ; Partition ; Adsorption ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 108
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 232-244 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 109
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 252-257 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: After having witnessed, over a period of more than 20 years, the extremely difficult early development of capillary gas chromatography, the growth of scientific understandign, and finally its sudden blossoming into a commonly accepted technique, the author is confronted with a dichotomy. On the one hand, there are the dramatic advances in the fields of column preparation, and of sampling techniques. Implementation of these advances should logically result in correspondingly drastic progress in the average quality of application work in drastic progress in the average quality of application work in capillary gas chromatography. On the other hand, however, such progress is lacking. The greater the practical potential, the smaller the fractionm of that potential which is practically exploited. The reason is that most users interpret te recent advances as exempting them from their obligation to know and think about the many details of practical work, and to attempt standardized work with standard columns and techniques. Standardization of routine work is beneficial, provided the standards are optimized-a condition which all too often remains unfulfilled. Research work, performed in a realm of ever new and unknown conditions, is of poor quality when done by standardized means. Since the most critical part of optimization is column selection, the capillary column must be mastered as a familiar tool in the hands of the investigator. This is hardly possible in the absence of any direct contact with column technology.
    Type of Medium: Electronic Resource
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  • 110
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 258-264 
    ISSN: 0935-6304
    Keywords: Gas-liquid chromatography ; Packed and capillary columns ; Plasma anaysis ; Pharmacokinetic studies ; Benzodiazepines ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A sensitive gas-liquid chromatographic assay was developed for plasma determinations of flurazepam (F), N1-desalkylflurazepam (DF), and N1-hydroxyethylflurazepam (HF). The internal standards used were delorazepam for F and DF and 1 ã-hydroxymidazolam for HF. Following extraction and derivatization for HF, these compounds were analyzed by ECD-GLC, using either glass packed columns (poly A 103 for F and DF, OV 225 for HF) or CP-Sil 5 capillary columns for DF and HF. The detection limit of the packed-column assay was approximately 3ng/ml for HF and DF, and 5ng/ml for F; with capillary GLC analysis, the sensitivity limit for HF and DF was lower than 1 ng/ml. These methods were used for pharmacokinetic investigations after i. v. administration of these compunds.
    Additional Material: 4 Ill.
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  • 111
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 276-278 
    ISSN: 0935-6304
    Keywords: HPLC, Packed microbore columns ; Band broadening and flow rate ; Calculated van Deemter plot ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 112
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 282-283 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Gas analysis ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 113
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 286-288 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 114
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 296-300 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 9 Tab.
    Type of Medium: Electronic Resource
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  • 115
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 306-311 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary columns ; Thermodesorption ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A commercial thermodesorption and cold trap unit can be used as a large sample volume injection device in high resolution gas chromatography. Volumes of more than 100 μl can be injected. More than 97% of solvents, such as hexane, can be removed by a Tenax TA precolumn without any loss of compounds with volatilities comparable to naphthalene. Experimental conditions, recovery rates of polycyclic aromatic hydrocarbons, and the reproducibility of the method are described in detail. The method was successfully applied for the determination of PAH in air particulate matter extracts.
    Additional Material: 3 Ill.
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  • 116
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 333-333 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 117
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 334-335 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Fused-Silica columns ; Thermal stability ; Dibenzothiophene oxides ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 118
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 411-413 
    ISSN: 0935-6304
    Keywords: Packed capillary columns ; Miniaturized gradient elution ; Polynuclear aromatic hydrocarbons ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A miniaturized continuous gradient elution system was designed for work with packed capillary columns. The retention reproducibility achieved is adequate for many practical applications.
    Additional Material: 4 Ill.
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  • 119
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 461-465 
    ISSN: 0935-6304
    Keywords: Gas chromatography, GC ; Capillary columns ; Retention gaps ; Peak broadening ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A simple formula is derived which allows estimation of the band broadening due to longitudinal diffusion in retention gaps for isothermal runs with the column held at the injection temperature. The broadening is strongly dependent on the linear gas velocity in the retention gap. If the internal diameters of the retention gap and the separation column are similar, the retention gap may have a length exceeding 100 m, even if the separation column is only 10 m long. A 0.5 mm I.D. retention gap attached to a 0.3 mm I.D. separation column (of interest for automatic on-column injection) may be several meters long. Retention gaps of 0.3 mm I.D. may be used for on-column injections into separation columns with I.D's. down to about 0.1 mm.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 120
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 477-479 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Glass capillary column ; Adsorbent ; Cold trapping ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 121
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 414-422 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary columns ; Steroid analysis ; Sample pretreatment ; Sample introduction ; Separation speed ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Quantitative analysis of steroids and their metabolites in urine samples calls for increased speed of sample clean-up, of the derivatization procedure, and of separation. A fast procedure for sample pretreatment, which can be performed within 8 hours, is introduced and evaluated. It is shown that use of fast pretreatment in combination with narrow bore columns, which are compatible with existing instrumentation, can considerably increase, laboratory throughput. The effect of different sample introduction techniques (e.g. splitless, on-column, and moving needle) on column efficiency and resolution is demonstrated and discussed.
    Additional Material: 7 Ill.
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  • 122
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 435-435 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 123
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; General methods of nucleotide HPLC ; Molecular and ionic basis of separation ; Two-dimensional separation ; Stationary phase; selectivity to nucleotide size and composition, selectivity control ; Mobile phase (solvent, salt, pH), influence on retention and selectivity ; Guard-column functions ; Column loadability and packing, consolidation of bed particles ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In order to develop efficient separation methods for nucleotides according to their size and heterocyclic composition, the application of ion-exchange, reverse-phase, and normal-phase adsorption HPLC has been studied. The comparative investigation of retention power and selectivity of various packings (non-polar bonded-phase and amino silicas) in relation to nucleotide length and composition yields data which enable suitable packings to be selected and a method of preparing the new packing for a particular separation problem to be formulated. Thus a new anion exchanger with high selectivity and dynamic mass transfer has been prepared for fractionation of large oligonucleotides. The effect of the eluent pH and composition (organic modifier, salt) on retention, selectivity, and resolution in ion-exchange and reverse-phase HPLC has been studied. The optimum separation conditions comprise elution with oppositely directed gradients of the salt and the modifier, use of a precolumn packing that provides the best protection for the main column without loss of its efficiency, and the optimum gradient program for the desired retention of the component of interest. The relation between loading and sample concentration has been studied and the system for gradient elution improved. Our work shows that two-dimensional separation is the most reliable and informative method for preparation of homogeneous oligonucleotides. The hydrophobic-pair ion-exchange mechanism is proposed for ion-pair chromatography. Protected and partially deblocked oligonucleotides, chemically synthesized for genetic engineering studies, have been separated with high selectivity by adsorption (normal-phase) HPLC which is efficient for gradient elution with isohydric eluents. The analysis of a monomeric composition of nano-(pico-) molar amounts of oligonucleotides has been developed; the procedure involves microcolumn digestion of the oligonucleotides with immobilized enzymes followed by microcolumn separation of the nucleoside-mononucleotide mixture. Also, a new slurry method for packing stable HPLC columns with a tightly consolidated, nonshrinkable bed of particles has been developed.
    Additional Material: 31 Ill.
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  • 124
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 492-494 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Closed loop stripping analysis ; Filter extraction ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 125
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 587-589 
    ISSN: 0935-6304
    Keywords: Gas chromatography, GC ; Packed glass columns ; Solvent extraction ; Plastics ; Ethylene oxide ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 126
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 597-598 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 127
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 538-539 
    ISSN: 0935-6304
    Keywords: Thin-layer chromatography, TLC ; Alkylchlorosilanes ; Prostaglandins ; Hydroxyelcosatetraenoic acids ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 128
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 549-552 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 129
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 566-569 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Electrochemical detection ; Serum ; Tetraiodothyronine ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tetraiodo-L-thyronine (T4) in human serum was determined by HPLC using a nonphysiological internal standard. For sample preparation, a cation exchange resin, RP-chromatography on C-18 or phenylphase, and electrochemical detection (Metrohm 656 or BAS-LC 4 A) were employed. The mobile phase (0.8 ml/min) was 10 mM H3PO4/CH3OH (40/60 v/v) or 10 mM H3PO4/CH3CN (70/30 v/v, 1.5 ml/min), the voltage applied 800 mV. The coefficient of variation (day to day) was 6.8% (N = 40); concentrations of T4 found were 11 to 20% lower than those obtained by two different commercially available immunoassays.
    Additional Material: 2 Ill.
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  • 130
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 578-579 
    ISSN: 0935-6304
    Keywords: Gas chromatography, GC ; Capillary columns ; Effluent splitter, all glass type ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 131
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 590-592 
    ISSN: 0935-6304
    Keywords: Pressurized gas ; Supercritical fluid ; Elution and resolution behavior ; n-Pentane ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 132
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 599-599 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 133
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 660-670 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 6 Ill.
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  • 134
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 697-699 
    ISSN: 0935-6304
    Keywords: Gas chromatography, GC ; Capillary columns, 100 μm I.D. ; On-column injector ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
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  • 135
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 707-709 
    ISSN: 0935-6304
    Keywords: Supercritical fluid chromatography, SFC ; Diffuse reflectance infrared spectrometry ; Fourier transform infrared spectrometry ; Spectrometry/chromatography interface ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 136
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 577-577 
    ISSN: 0935-6304
    Keywords: Multidimensional gas chromatography, MGC ; Deans System ; Temperature programming ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 137
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 584-586 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Normal and reversed phases ; Steroid esters ; Long-acting contraceptive ; Injectable contraceptives ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 138
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 714-715 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Bonded phases ; Charge-transfer interaction ; n-Propyl picryl ether ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
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  • 139
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    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 7 (1984), S. 709-711 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Electrochemical detection ; Phenylenediamines ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 140
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 24-34 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Evaluation of Recent Models for Short Fatigue CracksIn the present study some new procedures for the evaluation of the propagation behavior of small cracks at notches which were originally proposed by T. H. Topper et al. and by K. J. Miller et al. are considered. They are presented in a manner that they can immediately be used for practical applications. The basis of the procedures and their ranges in application are considered and they are compared to conventional fracture mechanics analyses.In a second part of the study still existing limitations in the physical basis of the procedures are outlined and some aspects regarding the extension of the range in application of the procedures to variable amplitude loading histories are given.
    Notes: In der vorliegenden Arbeit werden neuere im Schrifttum mitgeteilte Methoden (Verfahren nach T. H. Topper u. Mitarbeiter und nach K. J. Miller und Mitarbeiter) zur Beschreibung des Ausbreitungsverhaltens kleiner Risse an Kerben betrachtet und in der Weise aufbereitet, daß sie unmittelbar in der Praxis anwendbar sind. Es erfolgt eine ausführliche Darstellung der Grundlagen und des Anwendungsbereichs der Methoden, ferner ein Vergleich mit konventionellen Lösungsansätzen auf der Grundlage der linear-elastischen Bruchmechanik (LEFM).Anschließend werden die derzeit noch bestehenden Beschränkungen in den physikalischen Grundlagen der betrachteten Methoden angegeben. Es werden Weiterentwicklungsschwerpunkte im Hinblick auf die allgemeine Anwendung der Methoden auf Betriebsfestigkeitsprobleme aufgezeigt.
    Additional Material: 16 Ill.
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  • 141
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    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 124-132 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 34 Ill.
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  • 142
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. A30 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 143
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    Materialwissenschaft und Werkstofftechnik 15 (1984) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 144
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 172-176 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Long Term Creep Tests of Polypropylene at 120 °CThe mechanism of damage in the pipe wall during the internal pressure creep test of polypropylene-pipes at a test temperature of 120° is described. The resulting consequences from the investigations relating to the test method are shown and a test station with automatic recording of the time of damage is presented.Further on solutions are explained to eliminate the security risks during the tests of big pipes. A practical performance is described. On the basis of the time-temperature-correlation of the long term behavior of polypropylene the mathematical basis to interpolate minimum requirements for quality control are presented.
    Notes: Die Schädigungsmechanismen in der Rohrwand bei der Zeitstand-Innendruckprüfung von Rohren aus Polypropylen und einer Prüftem-peratur von 120 °C werden beschrieben. Die sich daraus ergebenden Konsequenzen hinsichtlich der Prüftechnik werden aufgezeigt und ein Prüfstand mit selbsttätiger Erfassung des Versagenszeitpunkts für die Serienprüfung vorgestellt. Desweiteren werden Lösungsmöglichkeiten zur Beseitigung des Sicherheitsrisikos bei der Prüfung von Großrohren erläutert und eine praktische Ausführung beschrieben.Auf der Basis der Zeit-Temperatur-Korrelation des Festigkeitsverhaltens von Polypropylen werden die mathematischen Grundlagen zur Interpolation von Mindestanforderungen für die Qualitätskontrolle angegeben.
    Additional Material: 9 Ill.
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  • 145
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. A38 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 146
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Resistance of Various Steel Types and Nickel-Base Alloys Under the Influence of Nitriding Gases in Ammonia Syntheses PlantsThe paper describes test results obtained during 5 years of practical trials with heat-resisting steels, steels for hydrogen service, austenitic steels and nickel-base alloys under the nitriding operation conditions found in an ammonia plant at temperatures of more than about 400°C. During the test, nitriding rates and depths at high temperatures and under stresses were established, as well as changes in the mechanical properties as a result of nitriding.Based on the test results and the knowledge of the subject matter, recommendations and service condition limits for material selection are given.The superior behaviour of austenitic materials, especially with increasing nickel contents, could be confirmed.An attempt is made to find an explanation for the reduced resistance to hydrogen attack under the influence of nitridation.
    Notes: Beschrieben werden Versuchsergebnisse einer 5jährigen praktischen Erprobung an warmfesten, druckwasserstoffbeständigen und austenitischen Stählen sowie Nickelbasiswerkstoffen unter den aufnitrierend wirkenden Betriebsbedingungen einer Ammoniak-Synthese oberhalb etwa 400°C.Ermittelt wurden Nitriergeschwindigkeiten und -tiefen unter Temperatur- und Spannungseinflüssen sowie die Veränderungen der mechanischen Eigenschaften durch Nitrierung.Aufgrund der Versuchsergebnisse und gleichartiger Kenntnisse werden Empfehlungen und Grenzbedingungen zur Werkstoffauswahl gegeben.Das bessere Verhalten austenitischer Werkstoffe, insbesondere mit steigenden Nickelgehalten, konnte bestätigt werden.Es wird versucht, eine Deutung der Verschlechterung der Druckwasserstoffbeständigkeit unter dem Einfluß der Aufnitrierung zu geben.
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  • 147
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 214-221 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Die geschilderten Oberflachenschutzverfahren wurden entwickelt, um im Maschinen- und Apparatebau mit billigeren Grundwerkstoffen weiterzuarbeiten, aber bei hohem Verschleiß und Korrosionsbeanspruchungen noch eine technische und wirtschaftliche Nutzungsdauer zu erreichen. Durch die laufende Verknappung und damit Verteuerung der Rohstoffe werden die einzelnen Verfahren in Zukunft noch eine wesentliche Steigerung erfahren.
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  • 148
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 222-222 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 149
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 230-237 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Pickling of Steel Tanks for Use in Biological Water Purification Plants as a Pretreatment to the Application of an Organic CoatingHigh-level tanks made from structural steel, so called BIOHOCH®-Reaktoren for biological purification of chemical waste water, had to be protected against corrosion by an organic coating. After the usual pretreatment, which means cleaning of the steel surface by sand or furnaceslag blasting, pittinglike corrosion was observed in two cases. Therefore, the required grade of surface preparation was not available. Nevertheless, to get good preconditions for a sufficient service life, both tanks with a volume of about 20 000 m3 were pickled in such a manner, that the final furnace blasting operation furnished the presumed white metal state.The problematic nature of organic coatings, which has recommended the pickling of the steel surface, is discussed. The selection, realization and controlling of this treatment are specified.
    Notes: Stählerne Hochbehälter zur biologischen Reinigung von Chemieabwässern sollten mit einer Beschichtung gegen Korrosion geschützt werden. Bei der dazu notwendigen Vorbehandlung mittels Strahlen zeigte der Stahl in zwei Fällen eine lochförmige Vorkorrosion, die es verhinderte, daß sich auf diesem Wege die gewünschte Oberflächengüte erreichen ließ. Um dennoch gute Voraussetzungen für eine hinreichende Lebensdauer der Beschichtung zu schaffen, wurden die beiden Reaktoren mit jeweils etwa 20 000 m3 Inhalt so gebeizt, daß eine anschließende Strahlbehandlung den geforderten metallisch blanken Zustand erbrachte.Es wird auf die Problematik von Beschichtungen eingegangen, die es im vorliegenden Fall nahelegte, eine Beizung vorzunehmen. Die Auswahl, Ausführung und Überwachung dieser Behandlung werden beschrieben.
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  • 150
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 59-64 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Comparison of the Material Damage Progression by Intercristalline Stress Corrosion Cracking in the Laboratory and during Service ConditionsSimulation of the stress corrosion attack on structural steel in nitrate containing elektrolytes under practical service conditions. Description of the material damage process and definition of the different corrosion rates which can be deduced therefrom. The laboratory results permit the statement of a minimum and a maximum destruction rate by stress corrosion cracks.The results of measurements during service confirm the findings in the laboratory while the comparable damage pictures during laboratory testings and during service attribute to the understanding of not clarified phenomena of the damage process during service.
    Notes: Simulation des Spannungsrißkorrosionsangriffs von Baustählen in nitrathaltigen Elektrolyten unter praxisgerechten Prüfbedingungen. Beschreibung des Verlaufs der Werkstoffschädigung und Definition der unterschiedlichen Zerstörungsgeschwindigkeiten, die sich daraus ableiten lassen. Die Laborergebnisse erlauben die Angabe einer minimalen und maximalen Zerstörungsgeschwindigkeit durch Spannungsrißkorrosion.Die Ergebnisse von Betriebsmessungen bestätigen die im Labor ermittelten Befunde, wobei die vergleichbaren Schadensbilder bei der Laborprüfung und im Betriebseinsatz zum Verständnis von nicht geklärten Phänomenen des Schadensablaufs im Betrieb beitragen.
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  • 151
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    Materialwissenschaft und Werkstofftechnik 15 (1984) 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 152
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 88-94 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Hardfacing-Methods and their Application in the Materials-Technology and TribologyDuring the last few years more and more efforts have been made to reduce or even avoid material losses, caused either by mechanical or corrosive attack, by the means of protecting metal surface protection. In fact, the expenses needed in the Plastic-Technology for the disposition of wear-spares in West Germany amount to half a billion DM a year [1]. If all the damages by wear and corrosion are included, the losses world-wide rise to more than 80 billion DM/year. Thus not only technical but most of all economical reasons promote the rapid development of different hardfacing methods. The various methods are presented with ascending temperature of the working materials (s. Fig. 1).
    Additional Material: 17 Ill.
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  • 153
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 96-102 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Influence of Oxygen Traces on the Properties of Tungsten Heavy MetalsInvestigation carried out with differently sintered W heavy metals showed that careful pre-reduction before liquid phase sintering is essential for obtaining satisfactory mechanical properties; otherwise oxide layers at the phase boundaries deteriorate the interface strength and thus cause premature fracture. Understandably, the water vapour content of the furnace atmosphere is of considerable importance. Appropriate sintering anticipated, even severely oxidized green compacts result in highly ductile heavy metals. Addition of scavengers, e.g. Cr or V, instead of the pre-reduction improves the interface strength, the mechanical properties however remain unsatisfactory.
    Notes: Untersuchungen an nach verschiedenen Zyklen gesinterten Schwermetallen zeigten, daß sorgfältige Reduktion vor dem Flüssigphasensintern notwendig ist, um die beträchtlichen Ausgangsmengen an Sauerstoff zu entfernen; andernfalls werden aufgrund der durch Oxidbelegung verschlechterten Haftfestigkeit zwischen W-Körnern und Binderphase nur sehr schlechte mechanische Eigenschaften erhalten. Der Wassergehalt der Ofenatmosphäre spielt naturgemäß eine bedeutende Rolle; bei richtiger Führung der Sinterung werden auch von stark oxidierten Grünlingen ausgezeichnete Schwermetalle erhalten. Zusatz von Scavengern, wie Cr oder V, anstatt der Vorreduktion verbessert zwar die Haftung der Phasen, die Eigenschaften bleiben aber unbefriedigend.
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  • 154
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. I 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 155
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 132-140 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Investigations of the Local Composition of Glass Fibers with the Help of the Scanning Electron MicroanalysisVarious glass-fiber types show different chemical resistance in the surrounding of aggressive media. Through the influence of inorganic acid or alkali media certain elementary glass fibres can be leached. This effect can be seen optically in some kinds of glass-fibers. Other glass-fiber types show no optical change in the surface, although there is an aggressive attack Now it is possible to understand the leaching process in glass-fibers with the help of the scanning electron microanalysis. In that way corrosion procedures of various glass-fiber types can be better described.
    Notes: Verschiedene Glasfasertypen weisen gegenüber aggressiven Umgebungsmedien eine unterschiedliche Chemikalienresistenz auf. Durch die Einwirkung saurer oder alkalischer Medien können einige Elementarglasfasern ausgelaugt werden, was sich optisch verfolgen lassen kann, andere Glasfasern wiederum zeigen kaum optische Veränderungen. Mit Hilfe der Röntgenmikroanalyse besteht nun die Möglichkeit die durch den Auslaugprozeß hervorgerufene chemische Veränderung der Glasfaserzusammensetzung verschiedener Typen quantitativ bzw. semiquantitativ zu erfassen. Dadurch lassen sich Korrosionsvorgänge an einzelnen Elementarglasfasern besser beschreiben als bisher.
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  • 156
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 177-183 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Application of Metallographic Replica Technique on Material Examination and Failure AnalysesFor evaluation of technical facilities with regard to their safety and availability often informations on the microstructure of the components are required without having the possibility for taking a sample. In such cases a non-destructive metallographic examination by application of the replica technique on site has proved useful and indispensable. Although this technique is adequatly known today its evidence is sometimes still discussed amongst experts. As a contribution to this subject performance and interpretation of this special form of metallographic investigation are described below and the application advantages are pointed out by examples from chemical plants.
    Notes: Für die Beurteilung technischer Anlagen hinsichtlich ihrer Sicherheit und Verwendbarkeit werden oft Aussagen über den Gefügezustand der Bauteile verlangt, ohne daß eine Probenahme zur metallographischen Untersuchung möglich ist. In solchen Fällen hat sich eine zerstörungsfreie mikroskopische Untersuchung vor Ort mittels Gefügeabdrücken als nützlich und unentbehrlich erwiesen. Über die Aussagefähigkeit dieses Prüfverfahrens kommt es in der betrieblichen Praxis nach wie vor zu Diskussionen. In vorliegender Arbeit wird über Durchführung und Auswertung dieser Sonderform metallographischer Untersuchungen berichtet und die Anwendbarkeit an Beispielen aufgezeigt.
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  • 157
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 277-287 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Theoretical Foundations for the Application of Fracture Mechanics to Fibre Reinforced CompositesThis work gives a survey of the theoretical problems arising from the application of fracture mechanical concepts to fibre-reinforced composite materials.A classification of existing models into macro- and micromechanical is proposed, the derivation of essential equations outlined and some graphical illustrations of the resulting formulae are shown.
    Notes: Diese Arbeit gibt einen Überblick über die theoretischen Probleme, die sich bei der Anwendung bruchmechanischer Konzepte auf faserverstärkte Verbundwerkstoffe ergeben.Eine Einteilung der existierenden Modelle in macro- und micro-mechanische wird vorgeschlagen, die Herleitung der wichtigsten Gleichungen skizziert und graphische Illustrationen zu den resultierenden Formeln werden gezeigt.
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 315-323 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Mit Hilfe experimenteller und numerischer, sowie zeichnerischer Verfahren wurden Wege aufgezeigt, die Eigenspannungen bei Verbundkörpern unter Berücksichtigung des nichtlinearen elastoplastischen Material-Verhaltens zu berechnen bzw. zu konstruieren. Es besteht somit die Möglichkeit, das Verhalten der Verbundkörper vorauszubestimmen, insbesonders die Kennwerte der statischen und der dynamischen Beanspruchungen zu berechnen. Die erzielte gute Überein- stimmung von experimentellen und errechneten Werten der Verbundkörper aus Stahl- und Aluminiummaterial ist auf Verbundkombinationen mit anderen Materialien übertragbar. Weiterführungen der zeichnerischen Schnittgrößenermittlung könnten die Konstruktion des Spannungs-Dehnungs-Diagrammes eines Verbundkörpers zum Ziel haben. Hierbei ist von gleichen Überlegungen wie bei der Bestimmung des inneren Gleichgewichtes auszugehen.
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. A75 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 46-49 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Gewichtsfunktionen und Spannungsintensitätsvergrößerungsfaktoren für elliptische und halbelliptische Fehler unter beliebiger Normalspannung - Teil IIOberflächenfehler unter Spitzenspannungen werden untersucht. Das Berechnungsverfahren basiert auf der allgemeinen Form der Gewichtsfunktion für einen elliptischen Fehler in einem unendlichen Körper. Zwei Punkte auf der Ellipsenkontur werden untersucht. Ein neues, für alle a/t-Werte gültiges Korrekturverfahren für die Übertragung vom eingebetteten auf den Oberflächenfehler wird vorgestellt. Gewichtsfunktionen für beide Punkte mit dem Halbachsenverhältnis a/c als Parameter werden gefunden. Im Falle des Endpunktes der kleineren Achse sind alle Gewichtsfunktionen durch eine Gleichung beschreibbar (Lambda-Funktion von Heuman). Die Spannungsintensitätsvergrößerungsfaktoren für verschiedene a/c-Werte des Oberflächenfehlers werden bei verschiedenen Spannungsverteilungen angegeben.
    Notes: Surface cracks under peak stresses are investigated. The calculational procedure is based on the general form of the weight function for an elliptical crack embedded in an infinite solid. Two points on the contour of the ellipse are investigated. A new correction procedure for transfer from the embedded crack to surface crack configurations is presented, which is valid for all a/t-values. Weight functions for both points have been found with the crack aspect ratio a/c as parameter. For the point at the end of the minor axis all weight functions for embedded cracks are describable by one equation only (using Heuman's lambda function). For various a/c-ratios of the surface crack under different stress distributions the stress intensity magnification factors are given.
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. A15 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 163
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 83-87 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Spannungsintensitätsfaktoren für schlanke OberflächenfehlerEs wird ein Berechnungsverfahren für zug- und biegebelastete Platten mit Oberflächenfehler von Halbachsenverhältnissen a/c ≤ 0,2 und verschiedenen relativen Fehlertiefen a/t vorgestellt. Hierbei wird ein weiterentwickeltes “Line-Spring”-Modell verwendet. Die K1-Werte werden entlang der Fehlerkontur berechnet.Die K1-Werte für den tiefsten Punkt eines Oberflächenfehlers werden durch zwei bekannte Grenzkurven eingehüllt: Die obere Grenzkurve ist identisch mit der Lösung für den Randriß (a/c = 0). Die untere Grenzkurve wird nach den Ergebnissen von Newman und Raju für a/c = 0,2 beschrieben. Die ermittelten K1-Werte korrespondieren gut mit beiden Kurven.Bei großen relativen Fehlertiefen a/t liegen die Maxima von K1 zwischen dem tiefsten Punkt Q′ und dem Oberflächendurchstoßpunkt Q″ des Fehlers. Dieses Ergebnis vermag neben anderen Gründen zu erklären, daß beim Wachstum von Oberflächenfehlern die halb-elliptische Form mitunter nicht erhalten bleibt.
    Notes: A calculation procedure for plates with semi-elliptical surface cracks under tension and bending with aspect ratios of a/c ≤ 0.2 and arbitrary relative crack depths a/t is presented. For the computation an improved line spring model is used. K1-values are calculated along the crack contour.For the deepest point of a surface crack the K1-values are terminated by two well known threshold curves: The upper bound curve is identical with the solution for the edge crack (a/c = 0). The lower bound is described by the results after Newman and Raju for a/c = 0.2. The present K1-values are in good agreement with both curves.For high a/t-ratios the maximum K1-value is found between the deepest and the surface edge point (Q′ and Q″) of the crack. This result could explain among others that crack growth does not conserve the semi-elliptical shape sometimes.
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 107-107 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. A18 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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    Materialwissenschaft und Werkstofftechnik 15 (1984) 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 167
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 386-393 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Applicability of Different Etching Methods for Metals - Comparing Investigation of Metallographic Etching ProceduresThe feasibility of different etching techniques in laboratory practice is mainly appointed by the reproducibility of the metallographic micro-structure, which is dependent on the etching method, the etching time and a practical handling of the etching procedure. Comparing investigations concerning the applicability of chemical, electrolytic and ionic etching methods for metals and alloys in electrotechnical industry - with the aim to estimate efficiency and reproducibility of the micro-structure resulting from the different techniques - have been done. Micro-structure estimation will be done by different methods of light-microscopy.In any case physical ion-etching turns out to be the less problematic etching method - in comparison with chemical and electrolytic techniques. Ion etching shows a good reproducibility and allows the simultaneous etching of different materials. The summarizing valuation of the different etching methods includes a list of optimum etching parameters for copper, brass copper-tin and copper-beryllium alloys.
    Notes: Die Einsatzmöglichkeiten unterschiedlicher Ätzverfahren in der Laborpraxis werden im wesentlichen bestimmt durch die Reproduziorbarkeit der ausgebildeten Gefügestrukturen - als Funktion einer bestimmten Ätzmethode, der Ätzzeit und der problemlosen Handhabung der Ätzprozedur. Zur Anwendbarkeit des chemischen und elektrolytischen Ätzens, sowie des Ionenätzens bei Metallen und Legierungen der Elektrotechnik wurden vergleichende Untersuchungen mit dem Ziel durchgeführt, eine Beurteilung von Güte und Reproduzierbarkeit der nach den verschiedenen Ätzprozessen entstandenen Gefügebilder zu ermöglichen.Die Abbildung der Gefügestrukturen geschieht mit Hilfe unterschiedlicher lichtmikroskopischer Beobachtungsverfahren.Das physikalische Ionenätzen erweist sich gegenüber chemischen und elektrolytischen Ätzverfahren in allen Fällen als die problemlosere Ätzmethode, die neben einer guten Reproduzierbarkeit zudem ein gleichzeitiges Ätzen unterschiedlicher Materialien in einem Werkstoff ermöglicht.Eine zusammenfassende Wertung der verschiedenen Ätzverfahren umfaßt die Angabe optimaler Ätzparameter für die Werkstoffe Kupfer, Messing, CuSn 8 und Kupfer-Beryllium.
    Additional Material: 10 Ill.
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  • 168
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 169
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    Journal of High Resolution Chromatography 7 (1984), S. 137-139 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Deactivated fused silica tubing ; Zero dead volume union ; Capillary column GC/MS interface ; Test mixture for non-polar columns ; Test mixture of phenols ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 170
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    Journal of High Resolution Chromatography 7 (1984), S. 144-146 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary column ; Cyclopentolate ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 171
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    Journal of High Resolution Chromatography 7 (1984), S. 165-166 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 172
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    Journal of High Resolution Chromatography 7 (1984), S. 185-190 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary columns ; Mass spectrometry ; Dynamic headspace ; Deans switching ; Cold trap ; Reinjection ; Polymers ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An experimental method for the analysis of volatile organic compounds in polymers is described. The technique involves dynamic headspace sampling, collection, and concentration of the volatiles in a cold trap, followed by capillary column gas chromatography/mass spectometry. Flow switching is carried out by the Deans switching technique. Four technical polymers used as pharmaceutical packaging materials have been analyzed in order to demonstrate the method.
    Additional Material: 6 Ill.
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  • 173
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    Journal of High Resolution Chromatography 7 (1984), S. 196-202 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; LC/MS ; Mass spectrometry ; Field desorption ; Chemical ionization ; Gossypol ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Conditions are reported for the reverse-phase HPLC analysis of gossypol and of some of its derivatives, including anhydrogossypol, gossypolone, gossypol hexaacetate, and Schiff's base derivatives. It is shown that field desorption (FD) and chemical ionization (CI) mass spectrometry have advantages over electron impact (EI) mass spectrometry for the characterization of these compounds and that combined high-performance liquid chromatography/mass spectrometry (LC/MS), especially when used in the CI mode, is particularly effective.
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  • 174
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    Journal of High Resolution Chromatography 7 (1984), S. 212-214 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Trace analysis ; Solvent effect in GC ; Parts per trillion ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 175
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    Journal of High Resolution Chromatography 7 (1984), S. 220-221 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Packed microbore capillaries ; Miniaturization of components ; Estimation of dead volumes ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
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  • 176
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    Journal of High Resolution Chromatography 7 (1984), S. 227-228 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 177
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    Journal of High Resolution Chromatography 7 (1984), S. 245-251 
    ISSN: 0935-6304
    Keywords: Chromatography ; Temperature programming ; Efficiency ; Resolution ; Solute mobility ; Threshold temperature ; Emergence temperature ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The threshold temperature for solute mobility is defined as that temperature at which a solute band, which was initially cold trapped at the head of the column, begins moving through the column. It is shown that the separation of compounds by programmed temperature gas Chromatography (PTGC) occurs primarily at the head of the column as a result of differences in threshold temperatures. Additional column length beyoud that needed to trap the compounds improves resolution, primarily by delaying emergence (while maintaining the temperature and time spacing) thus allowing the column temperature to rise, the solute terminal velocities to increase, and narrower peak widths to be recorded. For maximum resolution in minimum analysis time, the initial temperature must be at or below the threshold temperature of the most volatile compound in the mixture to be separated.Three methods for determining threshold temperatures are presented.
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  • 178
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    Journal of High Resolution Chromatography 7 (1984), S. 270-273 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary column ; Temperature-programmed analysis ; Retention indices ; Polychclic aromatic hydrocarbons (PAH) ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
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  • 179
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    Journal of High Resolution Chromatography 7 (1984), S. 279-280 
    ISSN: 0935-6304
    Keywords: Liquid chromatography ; Open tubular liquid chromatography ; Capillary chromatography columns ; High pressure in micro-HPLC ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
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  • 180
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
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  • 181
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    Journal of High Resolution Chromatography 7 (1984) 
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    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
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  • 182
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    Journal of High Resolution Chromatography 7 (1984), S. 345-350 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 183
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    Journal of High Resolution Chromatography 7 (1984), S. 355-355 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 184
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    Journal of High Resolution Chromatography 7 (1984), S. 340-342 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Sample preparation ; Closed loop stripping analysis ; Charcoal adsorbent filter ; Overcoming contamination ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 185
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    Journal of High Resolution Chromatography 7 (1984), S. 352-352 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 186
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    Journal of High Resolution Chromatography 7 (1984), S. 356-357 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 187
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    Journal of High Resolution Chromatography 7 (1984), S. 375-381 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Reverse phase columns ; Window diagrams ; Aromatic carboxylic acids ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The optimization of the separation of eight aromatic carboxylic acids, using Hypersil SAS and MOS reverse phase columns, with respect to eluent (methanol : water) composition, pH, and temperature, is described. Window diagram techniques are used and the pH of the aqueous buffer and elution temperature are shown to be more critical than eluent composition.
    Additional Material: 11 Ill.
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  • 188
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    Journal of High Resolution Chromatography 7 (1984), S. 398-403 
    ISSN: 0935-6304
    Keywords: Capillary gas chromatography ; Enantiomeric separation ; Racemization ; Halocarboxylic acids ; Amide derivatives ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The direct determination of the enantiomeric purity of halocarboxylic acids is described. The method used involves gas chromatographic separation of the corresponding tert-butylamides on deactivated glass or fused-silica capillaries coated with Chirasil-Val. Both the influence of the amide moiety on enantiomeric resolution and tailing, and the racemization during formation of the amide derivatives were studied.
    Additional Material: 2 Ill.
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  • 189
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    Journal of High Resolution Chromatography 7 (1984), S. 546-547 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 190
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    Journal of High Resolution Chromatography 7 (1984), S. 487-489 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary column ; Multi-dimensional technique ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
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  • 191
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    Journal of High Resolution Chromatography 7 (1984), S. 497-498 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 192
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    Journal of High Resolution Chromatography 7 (1984), S. 494-496 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Phenyl-bonded stationary phase ; Acetonitrile/water mobile phase ; 190 nm UV Detection ; Water soluble polymers ; Polyethylene glycol oligomers ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
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  • 193
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    Journal of High Resolution Chromatography 7 (1984), S. 515-519 
    ISSN: 0935-6304
    Keywords: Ion chromatography ; ODS phases ; Indirect UV detection ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Several ODS phases have been dynamically modified to act as ion exchangers. Their ability to separate inorganic ions has been evaluated. The different properties of these materials are demonstrated and a method for eliminating the appearance of the system peak is described.
    Additional Material: 4 Ill.
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  • 194
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    Journal of High Resolution Chromatography 7 (1984), S. 520-524 
    ISSN: 0935-6304
    Keywords: Thin-layer chromatography, TLC ; Prechromatographic reduction ; Fluorescence stabilization ; Diesel exhaust particulate ; 1-Nitropyrene ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method is described for the determination of 1-nitropyrene in a diesel exhaust particulate extract by thin-layer chromatography. 1-Nitropyrene is determined as 1-aminopyrene after prechromatographic reduction and isolation by solvent partition. The fluorescence response of 1-aminopyrene is approximately 1000-fold greater than that of 1-nitropyrene. The poor fluorescence stability of 1-aminopyrene on silica gel plates prevents in situ detection by scanning densitometry unless the plates are impregnated with a mixture of 2,6-di-tert-butyl-4-methylphenol and Fomblin H-Vac. A linear response from 1 to 150 ng of 1-aminopyrene and a detection limit of 1.0 ng were obtained using the impregnated plates. For fourteen samples of a diesel exhaust particulate extract the concentration of 1-nitropyrene was determined to be 165 μg/g with an RSD = 9.0%. No significant interferences were observed from other nitro- or aminopolycyclic aromatic compounds present in the extract.
    Additional Material: 4 Ill.
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  • 195
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    Journal of High Resolution Chromatography 7 (1984), S. 533-536 
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary columns ; Fungicides and insecticides ; Sensitivity limits ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 4 Ill.
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    Journal of High Resolution Chromatography 7 (1984), S. 712-713 
    ISSN: 0935-6304
    Keywords: Liquid chromatography, HPLC ; Ion-Pair, reverse phase ; Sulfate analysis ; Lead acid batteries ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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    Journal of High Resolution Chromatography 7 (1984), S. 719-720 
    ISSN: 0935-6304
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
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  • 198
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. A59 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 199
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. 268-276 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Residual Stresses in Continual, Unidirectional Reinforced Fibre-Composites and Composite-ConstructionsInternal stresses in composite are determining the static or dynamic properties of these elements. These inbuilt stresses are extending or shortening the failure of the individual materials. If the internal stresses in a composite are known the mechanical characters of the composite can be calculated.With aid of experimental, numerical or graphical methods it is shown to calculate or construct the internal stresses of unidirectional, continual reinforced fibrecomposites. The nonlinear material-characteristics of the individual composite-materials are taken account of.The good agreement between experiment and calculation of the residual stresses can be demonstrated with examined stealwire-aluminium-composites. The method how to calculate the residual stresses may be transfered to other combinations of composite by the same way.
    Notes: Eigenspannungen in Verbundkörpern bestimmen deren statisches und dynamisches Festigkeitsverhalten. Innere Spannungen verkürzen oder verlängern die Beanspruchbarkeiten der Einzelkomponenten. Bei Kenntnis der inneren Spannungen lassen sich die Festigkeitskennwerte exakt errechnen.Mit Hilfe experimenteller und numerischer sowie zeichnerischer Verfahren werden Wege aufgezeigt, die Eigenspannungen von unidirektional mit kontinuierlichen Fasern verstärkten Verbundkörpern zu berechnen bzw. zu konstruieren. Hierbei wird das nichtlineare elastoplastische Materialverhalten der Verbundkomponenten berücksichtigt.Die erzielte gute Übereinstimmung von experimentellen und errechneten Werten der exemplarisch untersuchten Verbundkörper aus Stahldrähten und Aluminiummaterial, ist auf Verbundkombinationen anderer Materialien bei gleicher Vorgehensweise übertragbar.
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    Materialwissenschaft und Werkstofftechnik 15 (1984), S. A62 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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