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Methanation of carbon monoxide and carbon dioxide over nickel catalyst under the transient state (1987)

Fujita, S. ; Terunuma, H. ; Kobayashi, H. ; [et al.]

Springer

Reaction kinetics and catalysis letters 33 (1987), S. 179-184

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ISSN: 1588-2837

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Description / Table of Contents: Abstract Кинетики метанирования CO и CO2 значительно различаются в промежуточном состоянии. Гидрирование поверхностных углеродных частиц сильно ингибировано CO, обратимо адсорбированным в реакции метанирования, а CO2 не ингибирует последнюю реакцию и H2O образуется на двух различных ступенях.

Notes: Abstract The kinetics of methanation of CO and CO2 were markedly different in the transient state. The hydrogenation of surface carbon species was strongly inhibited by reversibly adsorbed CO in the former reaction. CO2 did not inhibit the latter reaction and H2O was found to form by two distinct steps.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF02066720

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