ISSN:
1089-7550
Source:
AIP Digital Archive
Topics:
Physics
Notes:
Temperature-dependent optical absorption of cerium-doped gadolinium oxyorthosilicate (Gd2SiO5:Ce) has been measured and analyzed for impurity-ion-lattice coupling parameters and oscillator strengths. Although the spectrum consists of overlapping Ce3+ bands and Gd3+ lines, two well-resolved Ce3+ bands with 10 K maxima at 3.32 eV (peak a) and 3.61 eV (peak b) are amenable to spectral analysis. These bands, previously assigned to Ce3+ ions occupying crystallographically inequivalent substitutional sites, are characterized by Gaussian line shapes and temperature-dependent half widths that are well described by the linear model of impurity-ion-lattice coupling. Huang–Rhys [Proc. R. Soc. A 204, 404 (1950)] parameters of peaks a and b are 22.7 and 5.7, respectively, indicating strong ion-lattice coupling, with vibrational frequencies 1.83×1013 s−1 (peak a) and 5.07×1013 s−1 (peak b). Peak b centroid is approximately temperature independent, but peak a centroid shifts to higher energy with increasing temperature. This dependence is adequately described by including higher-order coupling terms in the ion-lattice interaction, although crystal-field contributions cannot be excluded. Absorption band oscillator strengths, f, are calculated from Smakula's [Z. Phys. 59, 603 (1930)] formula and knowledge of cerium concentration for the two inequivalent sites. In the interval 10–300 K, peak a f values range from (9.8 to 26.8)×10−4 and peak b f values vary from (7.8 to 5.8)×10−3. From the known correlation between oscillator strength and metal-ion-ligand separation, we identify peaks a and b as the seven- and nine-oxygen-coordinated sites, respectively. © 2000 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.373456
