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  • Polymer and Materials Science  (17)
  • 27.60+j  (2)
  • 33.90.+h  (2)
  • Endogenous depression  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Oxidation-state-specific detection of uranium in aqueous solution by photoacoustic spectroscopy (1983)
    Springer
    Applied physics 32 (1983), S. 207-209 
    Details
    ISSN: 1432-0649
    Keywords: 78.20.Hp ; 33.90.+h
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract By means of photoacoustic spectroscopy it has been possible to detect U(IV) and U(VI) in aqueous solution in the 10−6 M/L range. Piezoelectric transducer detection, pulsed laser radiation and a differential method to reduce solvent and window absorption has been used. Photoacoustic spectroscopy seems to be a suitable method for the low level detection of actinide elements.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00688289
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  • 2
    Electronic Resource
    Electronic Resource
    Speciation of actinide ions in aqueous solution by laser-induced pulsed photoacoustic spectroscopy (1984)
    Springer
    Applied physics 34 (1984), S. 203-206 
    Details
    ISSN: 1432-0649
    Keywords: 78.20. Hp ; 33.90.+h
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The oxidation-state specific detection of actinide ions, U(VI), Pu(IV), Pu(VI), and Am(III), was investigated by pulsed laser photoacoustic spectroscopy. With a single-beam differential technique, the solvent effect is compensated and thus the detection sensitivity substantially increased. The observed detection sensitivities are 8×10−7M/L for U(VI) 7×10−8M/L for Pu(IV) 3×10−8M/L for PU(VI) 2×10−8M/L for Am(III) The present method facilitates the study of complexation and polymerization of actinide ions in the submicromole concentration range.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00697636
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  • 3
    Electronic Resource
    Electronic Resource
    Increased serum glutamate in depressed patients (1982)
    Springer
    European archives of psychiatry and clinical neuroscience 232 (1982), S. 299-304 
    Details
    ISSN: 1433-8491
    Keywords: Serum glutamate ; Endogenous depression ; Neurotic depression ; Antidepressants ; Serum-Glutamat ; endogene Depression ; neurotische Depression ; Antidepressiva
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Description / Table of Contents: Zusammenfassung Der Serum-Glutamatgehalt wurde bei endogen depressiven, neurotisch depressiven, schizophrenen und schizoaffektiven Patienten sowie gesunden Kontrollpersonen bestimmt. Hierbei zeigte sich, daß die Serumglutamatspiegel bei endogen und neurotisch Depressiven signifikant höher waren als bei den anderen Gruppen. Zwischen schizophrenen und schizoaffektiven Patienten sowie Kontrollen zeigten sich dagegen keine signifikanten Unterschiede. Die weitere Analyse der Daten erbrachte die Hypothese, daß die erhöhten Serum-Glutamat-Konzentrationen bei endogen und neurotisch Depressiven eine Folge der antidepressiven Medikation sind. Diese Ergebnisse werden im Hinblick auf die Wirkung der Antidepressiva auf das Serum-Glutamat bei affektiven Störungen diskutiert.
    Notes: Summary Glutamate concentration was determined in serum from endogenous and neurotic depressive patients, in persons with schizophrenia or schizoaffective disorder, and in normal subjects. The mean serum glutamate level in the endogenous and neurotic depressive patients was found to be significantly higher than in any of the other groups. No other statistically significant differences were found. Statistical analysis revealed that the elevated serum glutamate concentration in the endogenous and neurotic depressive patients was probably caused by medication. These results are discussed in view of the effect of antidepressants upon the serum glutamate in the affective disorders.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00345492
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  • 4
    Electronic Resource
    Electronic Resource
    Levels of total and free tryptophan in the plasma of endogenous and neurotic depressives (1981)
    Springer
    European archives of psychiatry and clinical neuroscience 231 (1981), S. 35-39 
    Details
    ISSN: 1433-8491
    Keywords: Total tryptophan ; Free tryptophan ; Endogenous depression ; Neurotic depression ; Gesamt- und freies Tryptophan ; Endogene Depression ; Neurotische Depression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Description / Table of Contents: Zusammenfassung Gesamt- und freies Tryptophan wurde im Plasma von 34 endogen Depressiven, 20 neurotisch Depressiven und 25 gesunden Kontrollpersonen bestimmt. Während beim Gesamttryptophan kein Unterschied zwischen den drei Gruppen festgestellt werden konnte, war das freie Tryptophan bei endogen Depressiven und neurotisch Depressiven signifikant erniedrigt. Zwischen endogen und neurotisch Depressiven fand sich kein Unterschied.
    Notes: Summary The levels of total and free tryptophan were determined in the plasma of 34 endogenous depressives, 20 neurotic depressives and 25 healthy volunteers. Whilst the levels of total tryptophan were not different in the three groups, the level of free tryptophan was reduced in both endogenous and neurotic depressives. No difference could be found between endogenous and neurotic depressives.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00342828
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  • 5
    Electronic Resource
    Electronic Resource
    Band structure of118Xe (1988)
    Springer
    The European physical journal 331 (1988), S. 111-112 
    Details
    ISSN: 1434-601X
    Keywords: 21.10.Re ; 23.20.Lv ; 27.60+j
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract High spin states of118Xe have been investigated by means of γ ray spectroscopy using the92Mo(29Si,2pn) at a bombarding energy of 110 MeV. Several new side bands as well as the yrast band were established. A band crossing between the ground state and super bands was observed at ħωc = 0.39 MeV. A negative parity band with two quasi particle excitation, and a quasi γ band were also identified.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01289443
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  • 6
    Electronic Resource
    Electronic Resource
    High spin states in115Te (1994)
    Springer
    The European physical journal 349 (1994), S. 1-2 
    Details
    ISSN: 1434-601X
    Keywords: 23.20.Lv ; 27.60+j
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract High spin states in115Te have been studied using the89Y (29Si, p2n) reaction at a beam energy of 108 MeV.γ-γ coincidence, Eγ, Iγ and excitation functions have been measured. The level scheme has been extended to 82 MeV excitation energy relative to the 11/2 state and several new states are established. The systematical behaviour in odd- N Te isotopes is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01296323
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  • 7
    Electronic Resource
    Electronic Resource
    Ionically crosslinked poly(acrylic acid) membranes. IV. Composite reverse osmosis membranesPaper presented at the American Chemical Society Biennial Polymer Symposium, San Juan, Puerto Rico, November 20-24, 1982. (1983)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3063-3073 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Composite reverse osmosis membranes of ionically crosslinked poly(acrylic acid) (PAA) have been prepared. The process consists of coating a porous polysulfone membrane with a thin layer of dilute solution of PAA, drying the thin liquid layer, and ionically crosslinking the PAA in solutions of different salts. The influence of some important preparation parameters on the properties of these membranes was investigated. It was found that all these membranes possessed ion exchange properties and could be ion exchanged; some of them have been found to be suitable for the desalination of low concentration salt solutions. By comparison to cellulose acetate (CA) membranes, higher rejection of phenols may be an interesting property of these membranes.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1983.070281006
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  • 8
    Electronic Resource
    Electronic Resource
    Synthesis and transport properties of thin film composite membranes. I. Synthesis of poly(phenylene oxide) polymer and its sulfonation (1984)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 4017-4027 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The synthesis of sulfonated poly(phenylene oxide) polymer was investigated. The poly(phenylene oxide) was synthesized through oxidative coupling from 2,6-dimethyl-phenol with copper (I) chloride-pyridine catalyst and sulfonated using chlorosulfonic acid. The effects of catalyst concentration, solvent, and other experimental variables on the kinetics of the polymerization of poly(phenylene oxide) and its subsequent sulfonation are reported in detail.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1984.070291234
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  • 9
    Electronic Resource
    Electronic Resource
    Sulfonated latex particle as acid catalysts for the continuous inversion of sucrose (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 35 (1988), S. 2117-2131 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Sulfonated polystyrene latex particles were used as acid catalysts in the continuous inversion of sucrose at 50-70°C. The particles (surface charge 168 μeq/g) were confined in a stirred reactor with a semipermeable membrane; sucrose solution was pumped in, and product solution was pumped out. The catalytic activity of the particles was unchanged after 20 days continuous use. Variation of particle size (0.13 and 0.42 μm) and stirring rate showed that internal and external mass transfer was not a controlling factor. The kinetics were pseudo-first-order; the rate constant at 70°C was 2.30/N min as compared with 0.07/N min for macroporous sulfonated ion-exchange resin; the apparent activation energy was 111 kJ/mol as compared with 121 kJ/mol for the homogeneous acid-catalyzed reaction. The faster rate was attributed to the very great surface area, high charge density, and lack of internal diffusional resistance of the latex particles. The proposed mechanism comprised adsorption of sucrose on the particle surface, followed by inversion and desorption of product.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1988.070350812
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  • 10
    Electronic Resource
    Electronic Resource
    Preparation of highly sulfonated polystyrene model colloids (1989)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3187-3199 
    Details
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Previous attempts to prepare monodisperse styrene/sodium styrene sulfonate copolymer latexes by batch, seeded, and semicontinuous emulsion polymerization were unsuccessful at high concentrations of the functional comonomer. Broad, and sometimes bimodal, size distributions, and large amounts of water soluble homopolymer were obtained. After removal of free monomer, solute and adsorbed homopolymer and copolymer, the overall incorporation of the functional comonomer was found to be low. To overcome these problems, a two stage “shot-growth” or in situ seeding technique was developed. A first stage copolymerization was carried out with a low concentration of sodium styrene sulfonate: the purpose of the functional comonomer was to enhance the stability and regulate the size of the seed particles. When this reaction had reached high conversion (〉 90%), a second stage monomer mixture was added. The ratio of styrene to sodium styrene sulfonate in this mixture determined the final surface charge density. The mechanism by which the NaSS is incorporated in the polymer particles is considered to be by solution copolymerization with solute styrene monomer to form surface active oligoradicals. These radicals adsorb on the particle surface, initiate polymerization and become inextricably bound, preventing their transfer back to the aqueous phase. By this means, it was possible to vary independently the particle size and surface charge density. High concentrations of functional comonomer could be polymerized without undue wastage (incorporations were only slightly less than 100%) or loss of monodispersity. In extreme cases, the area per functional group fell below the theoretical minimum, indicating considerable hydration of the surface layers.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1989.080271001
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