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  • Polymer and Materials Science  (6)
  • Fluorimetry  (3)
  • X-ray diffraction  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Comparative study of Kalman filtering, synchronous excitation and numerical derivative techniques in fluorimetry
    Amsterdam : Elsevier
    Analytica Chimica Acta 279 (1993), S. 281-286 
    Details
    ISSN: 0003-2670
    Keywords: Derivative techniques ; Fluorimetry ; Kalman filter ; Peak resolution ; Synchronous excitation
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/0003-2670(93)80327-H
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  • 2
    Electronic Resource
    Electronic Resource
    Fiber-optic-based immunosensors for haptens
    Amsterdam : Elsevier
    Analytica Chimica Acta 246 (1991), S. 55-63 
    Details
    ISSN: 0003-2670
    Keywords: Fibre-optic sensor ; Fluorimetry ; Haptens ; Immunosensors
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1016/S0003-2670(00)80664-9
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  • 3
    Electronic Resource
    Electronic Resource
    Fiber-optic-based immunosensors for haptens
    Amsterdam : Elsevier
    Analytica Chimica Acta 246 (1991), S. 55-63 
    Details
    ISSN: 0003-2670
    Keywords: Fibre-optic sensor ; Fluorimetry ; Haptens ; Immunosensors
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://linkinghub.elsevier.com/retrieve/pii/S0003-2670(00)80664-9
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    Thermal equation of state of iron and Fe0.91Si0.09 (1999)
    Springer
    Physics and chemistry of minerals 26 (1999), S. 206-211 
    Details
    ISSN: 1432-2021
    Keywords: Key words Iron ; Fe ; Si alloy ; X-ray diffraction ; Equation of state ; Thermoelasticity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract  We have carried out an in situ synchrotron X-ray diffraction study on iron and an iron-silicon alloy Fe0.91Si0.09 at simultaneously high pressure and temperature. Unit-cell volumes, measured up to 8.9 GPa and 773 K on the bcc phases of iron and Fe0.91Si0.09, are analyzed using the Birch-Murnaghan equation of state and thermal pressure approach of Anderson. Equation of state parameters on iron are found to be in agreement with results of previous studies. For both iron and Fe0.91Si0.09, thermal pressures show strong dependence on volume; the (∂KT/∂T)V values are considerably larger than those previously reported for other solids. The present results, in combination with our previous results on ɛ-FeSi, suggest a small dependency of the room-temperature bulk modulus upon the silicon content, less than 0.3 GPa for 1 wt.% silicon. We also find that substitution of silicon in iron would not appreciably change the thermoelastic properties of iron-rich Fe−Si alloys. If this behavior persists over large pressure and temperature ranges, the relative density contrast between iron and iron-rich Fe−Si alloys at conditions of the outer core of the Earth could be close to that measured at ambient conditions, i.e., 0.6% for 1 wt.% Si.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s002690050178
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  • 5
    Electronic Resource
    Electronic Resource
    Experimental study of the bcc-fcc phase transformations in the Fe-rich system Fe-Si at high pressures (1999)
    Springer
    Physics and chemistry of minerals 26 (1999), S. 419-424 
    Details
    ISSN: 1432-2021
    Keywords: Key words Iron ; Fe-Si alloys ; X-ray diffraction ; Phase transformation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract In situ X-ray diffraction experiments at high pressure were carried out up to 8.9 GPa and 1100 °C to study phase transformations of iron and two iron-silicon alloys Fe0.91Si0.09 and Fe0.83Si0.17. For iron, the transformation from the bcc phase to the fcc phase was observed at pressures 3.8–8.2 GPa and temperatures that are consistent with previous in situ X-ray diffraction studies. Reversal of the transformation of iron was found to be sensitive to temperature; hysteresis of the transformation increased from 25 °C at 3.8 GPa to 100 °C at 7.0 GPa, primarily because the bcc-fcc phase boundary has a negative Clayperon slope. In the binary system Fe-Si, the observations of the present study indicate that the ferrite (bcc phase)-stabilizing behavior of silicon persists at high pressures and that the maximum solubility of silicon in the fcc phase increases with increasing pressure: (1) the transformation from the bcc phase to the fcc phase was observed in Fe0.91Si0.09 at 6.0, 7.4 and 8.9 GPa and the temperatures measured at the onset of the transformations were 300 °C higher than those in iron at similar pressures, (2) the transformation rate in Fe0.91Si0.09 was extremely sluggish compared to that of iron, and (3) the bcc-fcc phase transformation was not observed in Fe0.91Si0.09 at 4.7 GPa up to 1000 °C and in Fe0.83Si0.17 at 8.2 GPa and 1100 °C.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s002690050203
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  • 6
    Electronic Resource
    Electronic Resource
    Effect of pressure on the thermal expansion of MgO up to 8.2 GPa (2000)
    Springer
    Physics and chemistry of minerals 27 (2000), S. 145-148 
    Details
    ISSN: 1432-2021
    Keywords: Key words MgO ; X-ray diffraction ; Thermal expansion ; Equation of state
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract Isobaric volume measurements for MgO were carried out at 2.6, 5.4, and 8.2 GPa in the temperature range 300–1073 K using a DIA-type, large-volume apparatus in conjunction with synchrotron X-ray powder diffraction. Linear fit of the thermal expansion data over the experimental pressure range yields the pressure derivative, (∂α/∂P) T , of −1.04(8) × 10−6 GPa−1 K−1 and the mean zero-pressure thermal expansion α0, T  = 4.09(6) × 10−5 K−1. The α0, T value is in good agreement with results of Suzuki (1975) and Utsumi et al. (1998) over the same temperature range, whereas (∂α/∂P) T is determined for the first time on MgO by direct measurements. The cross-derivative (∂α2/∂P∂T) cannot be resolved because of large uncertainties associated with the temperature derivative of α at all pressures. The temperature derivative of the bulk modulus, (∂K T/∂T) P , of −0.025(3) GPa K−1, obtained from the measured (∂α/∂P) T value, is in accord with previous findings.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s002690050001
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  • 7
    Electronic Resource
    Electronic Resource
    Optical activity based on macromolecular asymmetryPart XXVI of Haloaldehyde Polymers; Part XXV : E.G. Brame, A. M. Raevsky, G. K. Semin, G. D. Jaycox, and O. Vogl, Polymer Bulletin 10(11/12), 521 (1983) (1985)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 13 (1985), S. 1-12 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Optically active isotactic polychloral was prepared in which the optical activity comes exclusively from molecular asymmetry (i.e., helical conformation). Molecular asymmetry requires a high conformational energy barrier for the polymer backbone, and an asymmetric initiator to induce a predominance of one helical screw-sense. Polychloral meets the criteria. Asymmetric initiators used to obtain optically active polychloral include tetramethyl ammonium (+)- or (-)-0-acetylmandelate, tetramethylammonium (+)- or (-)-0-methylmandelate, the lithiumalkoxides of methyl (+)- or (-)-mandelate, lithium cholesten-3β-oxide, lithium cholestan-3β-oxide, and lithium (+)- or (-)-2-octanoxide. Using the above initiators at 0.5 mol %, a maximum specific rotation of [α] D25 = 5000 was obtained for polychloral. Errors in specific rotation were typically ±7%.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1985.020131985102
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  • 8
    Electronic Resource
    Electronic Resource
    Mechanisms of carbon dioxide laser stereolithography in epoxy-based materials (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 491-500 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We present in this article the use of infrared laser radiation to achieve localized curing in thermosensitive epoxy resin compounds. In stereolithography, the objective is to cure a localized region in a material by precisely confining the laser energy to the area that is to be cured. Industry already uses ultraviolet laser radiation at 352 nm to fabricate three-dimensional structures. Via infrared laser curing, we demonstrate the viability of a completely thermal localized curing process. In our experiment, we have focused the beam from a carbon dioxide (CO2) laser onto a sample composed of epoxy resin, diethylene triamine, and silica powder. Such resins typically cure, or solidify, when heated to moderately high temperatures, and our results show that we can confine the heating of the material, and, therefore, its curing in all three dimensions. We present a physical and a chemical model to describe the process and measure the curing rate as a function of temperature. In order to model the flow of heat in our sample as a result of infrared laser irradiation, we solved the time-dependent heat equation in cylindrical coordinates using the Crank-Nicholson finite-difference method. The results allow us to predict the curing behavior of the sample as a function of laser irradiation conditions, and we find good agreement with our preliminary experimental observations. © 1996 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    In situ studies of epitaxial silicon growth by gas source molecular beam epitaxy (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Advanced Materials for Optics and Electronics 7 (1997), S. 215-224 
    Details
    ISSN: 1057-9257
    Keywords: silicon ; epitaxy ; kinetics ; dynamics ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: The value of in situ monitoring to study growth dynamics and surface reaction kinetics in a gas source molecular beam epitaxy process is illustrated with reference to the growth of Si films on Si(001) substrates using a beam of disilane (Si2H6). By using a combination of reflection high-energy electron diffraction (RHEED) and reflection anisotropy spectroscopy (RAS), we show first how morphological (long-range order) and local electronic structure effects can be separated in the evaluation of growth dynamics. This involves the measurement of step density changes by RHEED concomitantly with the variation in domain coverage on the Si(001) (2×1)+(1×2) reconstructed surface by RAS. This approach is then extended to investigate the kinetics of hydrogen desorption, which is the rate-limiting step in Si growth from Si2H6. It is shown that over a significant temperature range, zeroth-order kinetics are obeyed and this is explained on the basis of a step-mediated desorption process. Finally we show how this influences the growth rate on substrates of differing degrees of vicinality. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Matrix-size interactions in epoxy-glass fibers composites in relation to mechanical relaxations and effects of thermal aging (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 55 (1995), S. 1771-1777 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study was carried out to examine the effect of removing the size from the surface of glass fibers in order to determine its role with respect to thermoxidative aging. Dynamic mechanical relaxation data have revealed that mechanical losses were always greater than the calculated upper bound values. The effects of removing the size from the surface glass fibers for epoxy matrix composites were found to be completely different when a fluoroligomer was used to modify the resin. Contrary to the case of the conventional epoxy resin, the characteristics of the composites containing fluoroligomer-modified resin were found to be insensitive to the removal of the size from the glass fibers surface. The presence of the size on the surface of the fibers provides an interlayer that degrades through the formation of more lightly crosslinked products than the matrix, thereby providing a large increase in dynamic mechanical losses after thermal aging. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1995.070551307
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