Digitale Medien
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
93 (1990), S. 6065-6069
ISSN:
1089-7690
Quelle:
AIP Digital Archive
Thema:
Physik
,
Chemie und Pharmazie
Notizen:
A microscopic theory of field adsorption is used to study the adsorption and reaction of NO on a Pt(111) surface in high electrostatic fields. We find that below 0.4 V/A(ring) only NO is adsorbed stably. Above this value dissociation sets in that leads around 1.2 V/A(ring) to the formation of N2O. A molecular orbital analysis is given of the reaction pathway and to identify the stabilization mechanism.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1063/1.459494
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