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  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Inorganica Chimica Acta 35 (1979), S. L341-L342 
    ISSN: 0020-1693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 441 (1978), S. 86-92 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tin(II) Halide Complexes with Tri-tert-butylphosphine and Tris(dimethylamino)-phosphineTIn(II) chloride and tin(II) bromide react with tri-tert-butylphosphine and with tris(dimethylamino)phosphine to give stable 1:1 adducts. Infrared and raman data as well as1H-n.m.r., 31P-n.m.r., and 119mSn-Mössbauer spectra of the novel phosphine dihalogennostannylenes are discussed in terms of an ylidic type of bonding.
    Notes: Zinndichlorid und Zinndibromid reagieren mit Tri-tert-butylphosphin und mit Tris(dimethylamino)phosphin zu stabilen 1:1-Addukten. Die Bindungsverhältnisse dieser neuen ylidartigen Phosphindihalogenstannylene werden anhand von IR-, Raman-, 1H-NMR-, 31P-NMR- und 119mSn-Mößbauerspektren diskutiert.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 418 (1975), S. 259-262 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transsilylation Reaction with Di-tert-butyl(trimethylsilyl)phosphineDi-tert-butyl(trimethylsilyl)phosphine reacts with Dichlordimethylsilane, Trichlor(methyl)silane and silicon tetrachloride with elimination of Chlortrimethylsilane and formation of the new Silylphosphines [( CH3)3C]2PSi(CH3)3-nCln (n = 1, 2, 3). Only the compounds with n = 2 and 3 can be isolated in a pure state. The ir, raman, 1H-n.m.r. and 31P-n.m.r. spectroscopic data of the new compounds are discussed.
    Notes: Di-tert-butyl(trimethylsilyl)phosphin reagiert mit Dichlordimethylsilan, Trichlor(methyl)silan sowie mit Siliciumtetrachlorid unter Freisetzung von Chlortrimethylsilan und Bildung der neuen Silylphosphine [(CH3)3C]2PSi(CH3)3-nCln (n = 1, 2, 3), wobei nur die Derivate mit n = 2 und 3 rein isoliert werden können. Die IR-, Raman-, 1H-NMR- und 31P-NMR- spektroskopischen Daten der neuen Verbindungen werden diskutiert.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 450 (1979), S. 57-60 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organoarsenic-bridged Stannio ComplexesThe new pentacarbonyl(di-tert-butylarsinochlorostannio)chromium(0) and wolfram(0) complexes (CO)5MSnClAsR2 (M = Cr, W; R = t-C4H9) have been obtained from the reactions of the corresponding thf-containing tin dichloride complexes with di-tert-butyl(trimethylsilyl)-arsine. Infrared, Raman, and 119mSn-Mössbauer data are discussed in terms of di-tert-butyl-arsinobridged stannio-complex-type structures.
    Notes: Die Pentacarbonyl(di-tert-butylarsinochlorstannio)-chrom(0)- und -wolfram(0)-Komplexe (CO)5MSnClAsR2 (M = Cr, W; R = t-C4H9) entstehen bei den Umsetzungen der entsprechenden Tetrahydrofuran enthaltenden Zinndichlorid-Komplexe mit Di-tert-butyl(trimethylsilyl)arsin. Die Bindungsverhältnisse der neuen arsenverbrückten Stannylenkomplexe werden anhand von Schwingungsspektren und 119mSn-Mößbauerspektren diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 436 (1977), S. 270-276 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organophosphine-substituted Halogenogermylenes and -stannylenesHalogeno(di-tert-butylphosphino)germanium(II) and -tin(II) [(CH3)3C]2PMX (M = Ge, Sn; X = Cl, Br) are obtained by the reactions of triphenylphosphinedichloro- and -dibromogermylene, tindichloride and tri-tert-butylphosphinedibromostannylene with equimolar amounts of di-tert-butyl(trimethylsilyl)phosphine with elimination of chloro- and bromotrimethylsilane. Vibrational spectra of the new stable phosphine-substituted halogenogermylenes and -stannylenes are discussed in terms of coordination polymeric structures with bridging phosphino groups.
    Notes: Die Halogen(di-tert-butylphosphino)germanium(II)- und -zinn(II)-Verbindungen [(CH3)3C]2PMX (M = Ge, Sn; X = Cl, Br) entstehen bei den Umsetzungen von Triphenyldichlor- und -dibromgermylen, Zinn(II)-chlorid und Tri-tert-butylphophindibromstannylen mit Di-tert-butyl(trimethylsilyl)phosphin unter Abspaltung von Chlor- bzw. Bromtrimethylsilan. Für die neuen stabilen phosphinsubstituierten Halogengermylen und Halogenstannylene werden auf Grund schwingungsspektroskopischer Daten koordinationspolymere Strukturen mit verbrückenden Phosphinogruppen vorgeschlagen.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1693-1698 
    ISSN: 0044-2313
    Keywords: Tris(trimethylsilyl)methaneselenenyl halides ; Tris(trimethylsilyl)methaneselenyl chalcogenides ; 1H, 13C, 77Se n.m.r. sprectra ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tris(trimethylsilyl)methaneselenenyl Halides and Chalcogenides.Ditrisyldiselenide (1) (trisyl = TSi = (Me3Si)3C) reacts with SOCl2, Br2 and I2 to provide trisylselenenyl halides TSiSeX (2: X = Cl; 3: X = Br, 4: X = I). Insertion of S and Se into the Se—Se bond of 1 to yield (TSiSe)2Sn (5: n = 1; 6: n = 2) and (TSiSe)2Sen (7: n = 1; 8: n = 2) was catalysed by iodine. 5 was isolated in pure state and examined by X-ray diffraction. Triselenide 7 can be cleaved by I2 in CS2 to give 4 and Se2I2 (9). From 2 with Me3SiCN and Me3SiNCS, the new selenenyl pseudohalides TSiSeCN (10) and TSiSeSCN (11) were prepared. The compounds were characterised by 1H, 13C- and 77Se n.m.r. spectra.
    Notes: Ditrisyldiselenid (1) (Trisyl  -  Tsi  -  (Me3Si)3C—) reagiert mit SOCl2, Br2 und I2 zu Trisylselenenylhalogeniden TSiSeX (2: X = Cl; 3: X = Br, 4: X = I). Die Einschiebung von Schwefel und Selen in die Se—Se-Bindung von 1 zu (TSiSe)2 Sn (5: n = 1; 6: n = 2) bzw. (TSiSe)2Sen (7: n = 1; 8: n = 2) läßt sich mit Iod katalysieren. 5 wurde in reiner Form isoliert und durch Röntgenstrukturanalyse untersucht. Das Triselenid 7 wird durch Iod in CS2 zu 4 und Se2I2 (9) gespalten. Aus 2 lassen sich mit Me3SiCN bzw. Me3SiNCS das Trisylselenocyanat TSiSeCN (10) bzw. Trisylselenenylthiocyanat TSiSeSCN (11) gewinnen. 1H, 13C- und 77Se-NMR Spektren von 1 - 11 sind im Einklang mit den Strukturvorschlägen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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