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  • 1
    ISSN: 1432-0630
    Keywords: 61.80.Ba ; 52.75.-d ; 81.60.Bn ; 76.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Armco iron samples were surface nitrided by irradiating them with pulses of an excimer laser in a nitrogen atmosphere. The resulting nitrogen depth profiles measured by Resonant Nuclear Reaction Analysis (RNRA) and the phase formation determined by Conversion Electron Mössbauer Spectroscopy (CEMS) were investigated as functions of energy density and the number of pulses. The nitrogen content of the samples was found to be independent of the number of pulses in a layer of 50 nm from the surface and to increase in depths exceeding 150 nm. The phase composition did not change with the number of pulses. The nitrogen content can be related to an enhanced nitrogen solubility based on high temperatures and high pressures due to the laser-induced plasma above the sample. With increasing pulse energy density, the phase composition changes towards phases with higher nitrogen contents. Nitrogen diffusion seems to be the limiting factor for the nitriding process.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0630
    Keywords: 61.80.Ba ; 52.75.-d ; 81.60.Bn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Laser nitriding of Armco iron in nitrogen was studied for KrF-excimer-laser irradiation. The influence of the energy density and number of pulses on the nitrogen take-up and the nitride phases formed was investigated using Resonant Nuclear Reaction Analysis (RNRA) and Mössbauer spectroscopy. Besides the original a-iron, austeniteγ-Fe(N), martensiteα′-Fe(N),ε-Fe2+χN, andα″-Fe16N2 were identified. The fraction of the e-phase was found to increase with the number of pulses and the energy density. A threshold energy density of 1.8(2) J/cm2 for the laser nitriding process was found.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 83 (1998), S. 2907-2914 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The surface topology and nitrogen concentration profiles of iron irradiated with pulses of an excimer laser in a nitrogen atmosphere were studied by means of optical and scanning electron microscopy, surface profilometry, energy-dispersive x-ray spectroscopy, and resonant nuclear reaction analysis. The observations are combined to distinguish several mechanisms contributing to the material transport: ablation, redeposition of nitride from the plasma and pressure-induced lateral flow of the molten iron towards the edges of the laser spot (piston mechanism). Numerical estimates of the time and spatial evolution of temperature and pressure at the surface led to average rates of the material transport in good agreement with the experiment. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-0630
    Keywords: PACS61.80.Ba; 52.75.-d; 81.60.Bn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract. Laser nitriding of Armco iron in nitrogen was studied for KrF-excimer-laser irradiation. The influence of the energy density and number of pulses on the nitrogen take-up and the nitride phases formed was investigated using Resonant Nuclear Reaction Analysis (RNRA) and Mössbauer spectroscopy. Besides the original $\alpha$ -iron, austenite $\gamma$ -Fe(N), martensite $\alpha'$ -Fe(N), $\varepsilon$ -Fe $_{2+x}$ N, and $\alpha''$ -Fe $_{16}$ N $_2$ , were identified. The fraction of the $\varepsilon$ -phase was found to increase with the number of pulses and the energy density. A threshold energy density of 1.8(2) J/cm $^2$ for the laser nitriding process was found.
    Type of Medium: Electronic Resource
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